• Computers and Concrete
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• v.7 no.5
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• pp.421-435
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• 2010

This paper utilizes the modified Davis model and the mode coupling theory, as parts of the electrolyte solution theory, to investigate the diffusivity of the ion in concrete. Firstly, a computational model of the ion diffusion coefficient, which is associated with ion species, pore solution concentration, concrete mix parameters including water-cement ratio and cement volume fraction, and microstructure parameters such as the porosity and tortuosity, is proposed in the saturated concrete. Secondly, the experiments, on which the chloride diffusion coefficient is measured by the rapid chloride penetration test, have been carried out to investigate the validity of the proposed model. The results indicate that the chloride diffusion coefficient obtained by the proposed model is in agreement with the experimental result. Finally, numerical simulation has been completed to investigate the effects of the porosity, tortuosity, water-cement ratio, cement volume fraction and ion concentration in the pore solution on the ion diffusion coefficients. The results show that the ion diffusion coefficient in concrete increases with the porosity, water-cement ratio and cement volume fraction, while we see a decrease with the increasing of tortuosity. Meanwhile, the ion concentration produces more obvious effects on the diffusivity itself, but has almost no effects on the other ions.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.489-492
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• 2006

A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon and numerous methods have been proposed to determine the diffusion coefficient of chloride ion quickly. In this study, electrically accelerated experiments were carried out in order to evaluate diffusion coefficient of the chloride ion into concrete. The methods were diffusion cell test method in which the voltage of 15V(DC) was applied. The type of cement is blended cement in which the admixtures of blast-furnace slag and fly ash were used. In conclusion, the diffusion coefficient of chloride ion is much affected according to mineral admixtures and the diffusion coefficient of ternary blended cement showed very low values. it is presumably said that this result is due to highly densified pore structures by the aid of slag substitution and pozzolanic activity of fly ash.

• Computers and Concrete
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• v.15 no.2
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• pp.183-198
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• 2015

Chloride ingress implies a complex interaction between physical and chemical process, in which heat, moisture and chloride ions transport through concrete cover. Meanwhile, reinforced concrete structure itself undergoes evolution due to variation in temperature, relative humidity and creep effects, which can potentially change the deformation and trigger some micro-cracks in concrete. In addition, all of these process show time-dependent performance with complex interaction between structures and environments. In the present work, a time-dependent behavior of chloride transport in reinforced concrete beam subjected to flexural load is proposed based on the well-known section fiber model. The strain state varies because of stress redistribution caused by the interaction between environment and structure, mainly dominated by thermal stresses and shrinkage stress and creep. Finally, in order to clear the influence of strain state on the chloride diffusivity, experiment test were carried out and a power function used to describe this influence is proposed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.87-91
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• 2009

Recycling demolished concrete as an alternative source of coarse aggregates for the production of new concrete can help solve the growing waste disposal crisis and the problem of depleted natural aggregates. The purpose of this study is to investigate chloride migration of recycled aggregate concrete containing pozzolanic materials by chloride migration coefficient. The specimens were made with recycled coarse aggregate as various replacement ratio(10, 30, 50%) and metakaolin, blast furnace slag, fly ash is replaced for recycled concrete with mixing ratio 20%. The major results are as follows. 1) Compressive strength of recycled aggregate concrete containing pozzolanic materials increase as curing age and chloride migration decrease. 2) When the replacement ratio of recycled coarse aggregate is 30%, the chloride migration coefficient of recycled concrete containing blast furnace slag, metakaolin shows the similar or lower value than plain concrete at all ages.

• Computers and Concrete
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• v.10 no.3
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• pp.219-229
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• 2012

Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.56-61
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• 2012

The most common deterioration cause of concrete structures over the world is chloride ions attacks. Thus, service life modeling of concrete is a crucial issue in civil engineering society. Many studies on the durability of concrete have been accomplished, however, it is not easy to review literatures about environmental analysis. Since the durability of concrete depends on the properties of the surface concrete. micro-climatic condition which influences on surface concrete realistically should be considered. This study is devoted to analysis the micro-climatic condition of concrete structures, based on the in-situ monitoring of weather in marine environment. The effect of degree of saturation on chloride diffusivity of concrete is also examined. It is expected that the result of this work should be available for the prediction of chloride profile of marine concrete.

• Journal of the Korea Concrete Institute
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• v.17 no.6 s.90
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• pp.1045-1051
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• 2005

For critical structures and application, where a given reliability must be met, it is necessary to account for uncertainties and variability in material properties, structural parameters affecting the corrosion process, in addition to the statistical and decision uncertainties. This paper presents an approach to the fuzzy arithmetic based modeling of the chloride-induced corrosion of reinforcement in concrete structures that takes into account the uncertainties in the physical models of chloride penetration into concrete and corrosion of steel reinforcement, as well as the uncertainties in the governing parameters, including concrete diffusivity, concrete cover depth, surface chloride concentration and critical chloride level for corrosion initiation. The parameters of the models are regarded as fuzzy numbers with proper membership function adapted to statistical data of the governing parameters and the fuzziness of the corrosion time is determined by the fuzzy arithmetic of interval arithmetic and extension principle

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.694-699
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• 2000

Recently, the degradation of reinforced concrete structures due to physical and chemical attack has been a major issue in construction engineering. One of the main causes of degradation of concrete structures can be ascribed to chloride-induced corrosion, i.e., the rapid penetration of chloride ions into concrete. To estimate durability of reinforced concrete structures exposed to marine environment, many different kinds of accelerated tests to evaluate the concrete diffusivity were proposed. In this study, present test methods are reviewed and a proper test method for concrete is selected. The diffusion coefficients of concrete with corrosion inhibitor are measured using the proposed method, and then, measured values are compared to those of concrete without corrosion inhibitor. It is found from experimental results that diffusion coefficient re decreased with curing ages.

• Journal of the Korea Institute of Building Construction
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• v.18 no.6
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• pp.543-550
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• 2018

The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforcing steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is higher than 35MPa in the concrete/building construction standard specification. Even though it has been proved that the concrete mixed with mineral admixture such as blast furnace slag and fly ash etc. have high strength and durability in previous researches, the beneficial informations are not applied to the codes. Ready-mixed concretes which usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC. For economical and reliable durability design, chloride ion diffusivity should be measured before applying to new building construction.

• Journal of Pharmaceutical Investigation
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• v.16 no.1
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• pp.1-7
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• 1986

The influences of sodium chloride, polyethylene glycol 4000 and 20000 on 5-fluorouracil release from disk type silicone polymer devices were examined in isotonic phosphate buffer. These water soluble cosolvent and sodium chloride caused devices to swell in aqueous media. Sodium chloride exerted the greatest influence on drug release. The addition of water soluble cosolvent or sodium chloride to silicone polymeric devices permitted controlled release of 5-fluorouracil, presumably due to the change of the physical microstructure of silicone network, and the solubility and diffusivity of 5-fluorouracil. It seemed that the water soluble drug was released through the hydrophilic pores or pathways formed in the device by the incorporation of a water soluble cosolvent or sodium chloride.