• Title/Summary/Keyword: chloride content

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Effects of the Protection for Rebars by Embeded Sacrificial Anode in Concrete (희생양극재의 매입에 의한 콘크리트 중의 전기방식 효과)

  • 김성수;김홍삼;김종필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.1207-1212
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    • 2001
  • Reinforced concrete has defects in durability due to carbonation, freezing and thawing, and penetration of chloride ions with elapse of time in spite of super structure. Especially steel corrosion in concrete due to penetration of chloride ions has result in a severe decline in service life. The principal purpose of this study is to estimate effects of sacrificial anode cathodic system, one of the electrochemical methods in order to control of steel corrosion in concrete. There are chloride content in concrete in cracked and non cracked specimen with cathodic protection. To investigate the effect of sacrificial anode cathodic protection, potential-decay with current density, corrosion ratio, etc. are measured. We have the excellent effect for control steel corrosion adaption sacrificial anode cathodic system.

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Field Application of the Corrosion Protection Method for Marine Concrete with Nano-Silica (Nano-Sillica를 이용한 해양콘크리트 방식공법 현장 적용)

  • Kim, Kyoung-Min;Ryu, Dong-Woo;Park, Sang-Joon;Kim, Jong-Baek;Jo, Sung-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.399-400
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    • 2009
  • This study arranged the result corrosion inhibition using Nano-silica for efficient prevention to diffusion of chloride ion. For the results, significant difference was not found on slump and air content, and there were superior effect to preventing diffusion of chloride ion on hardened concrete. It seemed to be Nano-silica prevented diffusion of chloride ion.

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Effect of Tracer Composition on Spectrum and Intensity of Burning Flame (예광제 조성이 연소 불꽃의 스펙트럼 및 광도에 미치는 영향)

  • Kwon, Soon-Kil;Hwang, Jun-Sik;Lee, Sang-Mu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.9 no.4
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    • pp.90-96
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    • 2006
  • Computer simulation was carried out to develop the tracer composition of a high performance to be able to be observed by not only the naked eye but also the thermal imaging system attached to the weapon system. The results of computer simulation show that the optimum Mg content among the trace compositions is about 40% and the formulation consisted of Viton A has a higher flame temperature compared with that of chloride compound. But the only use of Viton A radiates a yellow light and the composition adding a chloride compound radiates the red light. The light intensity of the tracer composition involving Viton A is higher than that of chloride compound. The tracer composition involving Viton A shows more clear images in case of all tests.

A Study on the anti-Corrosion Properties of Inhibitor in Aqueous Solution (수용액내에서의 방청제 부식성능 평가연구)

  • Ryu, Hwa-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.221-223
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    • 2011
  • In this study, in order to comprehend performance of corrosion inhibitor, the experiment study was conducted about corrosion characteristic of 3 steps(0.0, norm 1/2, norm) compared to organic corrosion inhibitor standard use of liquid and molar 3 steps(0.0, 0.3, 0.6%) of Chloride by added amount of inorganic corrosion inhibitor by the corrosion inhibitor types about 2.4kg/㎥, 4.8kg/㎥ based on Chloride ion content 1.2kg/㎥ for service life prediction of concrete structure by using Poteniostat.

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Effects of C3A Content on Chloride Concentration in Pore Solution (C3A함유량이 세공용액 Cl 농도에 미치는 영향)

  • 소승영;박홍신;소양섭
    • Magazine of the Korea Concrete Institute
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    • v.7 no.1
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    • pp.89-96
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    • 1995
  • 본 연구는 시멘트 경화체 중의 Cl 고정화 메카니즘을 규명하는 연구의 일환으로 시멘트의 C3A 함유량에 따른 Cl 고정화 효과를 세공용액 분석방법에 의해 조사한 것으로 C3A함유량 0.46 9.65%의 4가지 시멘트와 C3A를 함유하지 않은 초속경 시멘트 페이스트를 밀봉용기내에서 양생시켜 재령 28일에 세공용액을 추출하여 세공용액 중의 Cl 과 OH 농도를 측정, C3A함유량이 Cl 고정화에 미치는 영향을 검토한 것이다. 연구결과 세공용액 중의 Cl 농도는 NaCl 혼입량에 관계없이 시멘트 중의 C3A량이 증가함에 따라 낮아져 시멘트 경화체 내에서 Cl 의 고정화에 C3A가 매우 효과적임을 알 수 있었다. 세공용액의 Cl /OH 는 Cl 혼입량이 시멘트 중량의 0.3%인 경우 강재부동태막을 파괴하는 0.3보다 낮았으며 X선회절분석에 의해 C3A에 의한 고정화 메카니즘은 프리델씨염(Friedel's salt)의 생성에 의함을 확인하였다.

Corrosion resistant self-compacting concrete using micro and nano silica admixtures

  • Jalal, Mostafa
    • Structural Engineering and Mechanics
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    • v.51 no.3
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    • pp.403-412
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    • 2014
  • In this paper, enhancement of corrosion and chloride resistance of high performance self compacting concrete (SCC) through incorporating nanosilica into the binder has been investigated. For this purpose, different mixtures were designed with different amounts of silica fume and nano silica admixtures. Different binder contents were also investigated to observe the binder content effect on the concrete properties. Corrosion behavior was evaluated by chloride penetration and resitivity tests. Water absorption and capillary absorption were also measured as other durability-related properties. The results showed that water absorption, capillary absorption and Cl ion percentage decreased rather significantly in the mixtures containing admixtures especially blend of silica fume and nano silica. By addition of the admixtures, resistivity of the SCC mixtures increased which can lead to reduction of corrosion probability.

Effect of Ultrasonic Wave on the Nickel-Zine Alloy Deposition whit the Variation of Ammonium Chloride Concertration (Ni-Zn 함금도금에서 염화암몬 농도에 따른 초음파의 영향)

  • 양학희;고광진;김재원
    • Journal of the Korean institute of surface engineering
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    • v.21 no.4
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    • pp.168-175
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    • 1988
  • The nickel0zinc allot depositions have been studjen in ammonium chloridw added chloride baths to fine out the effects of ultrasonic irradiation for the electrodeposition processes. The compositions of deposited alloys, the current efficiencies, corrosion resistance and brightness in various conditions of electrodeposition were investigated, in the range of ultrasonic irradiation of 50,500 and 1,000kc/s respectively. The results obtained are as follows; 1. the ratio of nikel to zinc in the deposit increased according 시 the ammonium chloride concentration in irradiated baths. 2. The current efficiencies became also higer in the irradiated bath. 3. Ammonium ions in solution seem to retard formation of zinc hydroxide. 4. The corrsion resistance and brightness of the deposits are dependent upon nickel content of deposits which ranges 10-18%(wt)nickel in the irradiated baths and 11-15%(wt)in ninirradisted baths. 5. The corrosion resistance and brightnes of the deposited are appreciably better in the irradiated baths than in non-irradiated bath with the mole ratio of 3.4(NH+4/Ni+++Zn++).

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Durability of VA/E/MMA-Modified Mortars with Nitrite-Type Hydrocalumite (VA/E/MMA 터폴리머 분말수지와 아질산형 hydrocalumite를 병용한 폴리머 시멘트 모르타르의 내구성)

  • Hong, Sun-Hee;Lee, Jae-Hwa;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.41-42
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    • 2011
  • In this study, VA/E/MMA-modified mortars with nitrite-type hydrocalumite were prepared with various calumite contents and polymer binder-ratios, and tested for chloride ion penetration, carbonation and drying shrinkage. As a result, the chloride ion penetration and carbonation depths were somewhat increased with calumite contents, but those were remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage showed a tendency to increase with polymer-binder ratios and calumite contents. VA/E/MMA-Modified mortars with a calumite of 10 % were dissatisfied with KS requirements. Accordingly, a calumite content of 5 % for the VA/E/MMA-modified mortars with calumite is recommended.

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Preparation and Swelling Characteristics of Hydrogel from Microbial Poly(${\gamma}-glutamic acid$) by ${\gamma}$-Irradiation

  • Choi, Seong-Hyun;Whang, Kyung-Sook;Park, Jong-Soo;Choi, Woo-Young;Yoon, Min-Ho
    • Macromolecular Research
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    • v.13 no.4
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    • pp.339-343
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    • 2005
  • Microbial hydrogel was prepared by ${\gamma}-irradiation$ of poly(${\gamma}-glutamic acid$) (PGA) which was produced from Bacillus subtilis BS 62 and it's physico-chemical characteristic was examined. The hydrogel, prepared from 10% PGA with the dose of 48 kGy, was swollen up to 1,370 times of specific water content as dry weight basis. The hydrogels obtained above the dose of 48 kGy appeared to have higher compressive strength but lower specific water content. The period to reach a swelling equilibrium for the hydrogel in deionized water at the temperature range of 4 to $45^{\circ}C$ was about 10 h. The swollen hydrogel was shrunk in ionic solutions with the increase of ionic strength, and the rate of shrinkage was greater in calcium chloride solution than in sodium chloride. Specific water content of the hydrogel was quickly decreased at $80^{\circ}C$, showing a thennally hydrodegradable property.

Fundamental Study on High Strength and High Durability Cement Concrete Pavement: Part II Strength and Durability Evaluations (시멘트콘크리트 포장의 고강도 고내구성을 위한 기초 연구 : Part II 최적배합콘크리트의 강도 및 내구특성 분석)

  • Yun, Kyong-Ku;Park, Cheol-Woo;Hong, Seung-Ho
    • International Journal of Highway Engineering
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    • v.11 no.3
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    • pp.51-60
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    • 2009
  • This study investigates the fresh state characteristics, strength, chloride ion penetration resistance and freeze-thaw resistance of the suggested high strength-high durability cement concrete pavement. The required workability and air content could be achieved by using an appropriate admixtures. However its dosage should be carefully determined through field trial batches. Compressive strength increased with the increased cement content and, in particular, high cement volume concrete continuously developed strength up to 90 days. No clear relationship, however, existed between flexural strength and cement content. Chloride penetration resistance seemed as a function of curing age rather than the cement content. Freeze-thaw resistance test was conducted using two different coolants, tap water and 4% NaCl solution. When the tap water was used no severe damage was observed up to 300 cycles regardless the air content. Under 4% NaCl solution, specimens of 326kg/$m^3$ cement content showed severe damage with surface scaling. Based on the experimental investigations herein, it is highly recommended that the cement content be greater than 400kg/$m^3$ for strength-high durability cement concrete pavement structures.

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