• Journal of the Korean Society of Hazard Mitigation
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• v.2 no.1 s.4
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• pp.143-152
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• 2002

The objectives of this paper were to obtain the fundamental data to analyze the causes of deterioration of 39 freeway concrete viaducts in Seoul metropolitan area. To investigate the degree of concrete deterioration, carbonation depth, soluble chloride concentration in hardened concrete and half-cell potentials of reinforcement were measured. The number of structures which carbonation depth penetrates to reinforcement was 25% of total. The model of carbonation .ate was induced to 3.92 $\sqrt{t}$, which was 5% faster than 3.727 $\sqrt{t}$ assumed 60% water-cement ratio, R=1 in that of kishitani. After measuring chloride concentration in concrete, it was concluded that about 24% of all readings on samples from concrete exceed the critical content to minimize the risk of chloride-induced corrosion. About 31% of the freeway viaducts structures had a value lower than -350mV(vs. CSE), so it could conclude that the excessive chloride concentration was the major cause of reinforcement corrosion. Among the structures which measured half-cell potentials less than -350mV, about 50% exceeds the maximum acceptable limit of chloride concentration.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.842-845
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• 2004

When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of the distance from seashore at 33 spots, 6 areas in East, West, South coast for 1 year. Results indicated that airborne sea salt is decreased by $y=a{\cdot}x^{-b}$ equation to the distance from seashore.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.261-264
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• 2005

For concrete structures immersed in seawater, the concentration of chloride used to estimate the chloride diffusion coefficient can be defined as the seawater chloride concentration. However, for seashore concrete structures which are not coming into direct contact with seawater, establishing the interface concentration of chloride becomes delicate. In addition, concrete structures are greatly affected by salt attack primarily due to airborne sea salt like it can be seen through the corrosion of rebar. This study intends to investigate characteristics on the salinity of airborne sea salt by height. Salinity measurement devices were installed at height of 2, 10 and 19m on the seashore water tower located in the area of Samchuk in the Eastern coast. Analysis results of the decrease of salinity with respect to the height above the ground at a distance of 30m from the seashore showed that the reduction reached about 40$\%$ at a height of 10m and 60$\%$ at 20m.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.237-240
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• 2004

When the concrete structures are in contact with seawater, concentration of chloride for estimating chloride diffusion coefficient can be defined as the chloride concentration of sea water. However, in case the concrete structures, constructed in the seashore, aren't directly in contact with seawater, it is difficult to establish the interface concentration of chloride. In addition, marine concrete structures are greatly affected by salt attack such as rebar corrosion, among the cause of salt attack, airborne sea salt is primary factor. Therefore, in this study, salt attack environment by airborne sea salt was investigated in terms of a seasonal distribution at 33 spots, 6 areas in the East, West, South coast for 1 year. Results indicated that in the South coast, the amount of the airborne sea salt is comparatively higher in summer. in the West coast. higher in winter. On the other hand, in the East coast, the amount of the airborne sea salt is rarely affected by a season.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.23 no.1
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• pp.11-17
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• 2011

A major source of durability problems in concrete structures is the corrosion of steel by the damage of passivity layer around steel bars. As chloride ion penetration is major cause of the destruction of passivity layer, evaluation of depth and concentration profile of chloride ion is the essential factor for the service-life estimation of concrete structure. To estimate chloride ion penetration characteristics, this paper on the basis of in-situ experimental data investigated the depth and concentration profile of chloride ion penetration. The core specimens are obtained at air-zone, splash zone, and tidal zone in Wando, Masan, Incheon, Gwangyang, and donghae harbors. Colorimentric method measured the chloride ion penetration depth and ASTM C 114 evaluated the concentration profile of chloride ion. Based on experimental data, the influence of harbor location and exposure condition on chloride ion penetration is evaluated.

• Journal of the Korean Chemical Society
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• v.10 no.2
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• pp.103-108
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• 1966

The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.739-742
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• 1999

A reinforcement corrosion prediction model was proposed using the results from accelerated testing and mathematical equation from the Fick's 2nd law for chloride-induced corrosion of reinforcement in concrete. The input data included the chloride concentration, mix characteristics of concrete, and environmental conditions. This model can be used to predict the chloride concentration pertaining to corrosion time and loading age for marine concrete structures. This model can also be used to predict the service life.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.631-634
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• 1999

A series of in-situ inspection and measurements have been conducted to estimate rebar corrosion incidence of freeway concrete bridges in Seoul metropolitan area. The results of this study have been analysed to identify the extent of chloride concentration and incidence of steel corrosion in various ages and in the different members of the structures. About 34% of the freeway structures had a value lower than - 350mV(vs CSE), so it could conclude that the excessive chloride concentration was a major cause of rebar corrosion.

• Journal of the Korean Chemical Society
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• v.19 no.6
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• pp.398-402
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• 1975

The light scattering studies of the aqueous solution of dodecyl pyridinium chloride (DPC) and tetradecyl pyridinium chloride (TPC) over the concentration range of 0~70 mM revealed that there exists a so-called 2nd critical micelle concentration (cmc) at about 43 mM and 8 mM respectively in addition to their 1st cmc at 17 mM and 3.5 mM. The 2nd cmc was greatly influenced by additives KCl, which lowered the 2nd cmc. The micelle molecular weight of DPC and TPC solutions at 1st cmc were 20800 and 15600 and the degree of ionization of their micelles at 1st cmc were 0.092 and 0.226 respectively.

• Computers and Concrete
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• v.15 no.1
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• pp.127-140
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• 2015

The process of chloride ingress in saturated concrete was presented by a previous study that used a mathematical model for the same as that concrete. This model is to be studied chloride ion diffusion which is considered as a chemical phenomenon and is to be represented the chloride diffusion process to be a nonlinear partial differential equation (PDE). In this paper, this nonlinear PDE is solved by the Kirchhoff transformation to render into a linear PDE. This linear PDE associated with initial and boundary conditions is also solved by the Laplace transformation to obtain an analytical solution. To verify the serviceability and reliability of this proposed method, the practical application should be supplied. The input parameters were cited from the previous study. The free chloride concentration profiles obtained by the analytical solution of mathematical model for saturated concretes after 24 and 120 hrs of exposure were compared with the previous study. The predicted results obtained from proposed method have a tendency with experimental results obtained by the previous study and trend toward numerical results approximated by finite difference technique.