• Title/Summary/Keyword: chloride cell

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Estimation of Critical Chloride Content for Corrosion of Reinforcing Steel in Concrete by Field Exposure Experiment (현장 폭로실험에 의한 콘크리트 중 철근의 부식 임계 염화물량 평가)

  • Yu, Kyung-Geun;Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Kim, Jee-Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.585-588
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    • 2008
  • To predict the service life of reinforced concrete structures exposed to chloride environment, quantitative measures of material properties such as the critical chloride content for corrosion in concrete and the diffusion coefficient of chloride ions of concrete and the surface chloride content of the concrete are essential. However, it should be noted that they are influenced by several factors such as concrete mix proportions, cement type, and environmental conditions, etc. Thus, the purpose of this research is to estimate more actually the critical chloride content for corrosion of the reinforcing steel in concrete by field exposure experiment. For this purpose, the prism concrete test specimens were made for water-cement(W/C) ratios of 31%, 42%, 50%, and 70%, and then the field exposure experiment for them were conducted at Youngduk of the east coast for about 3 years. During the test, corrosion monitoring by half cell potential method was carried out to detect the time to initiation of corrosion for test specimens and its chloride content was evaluated by breaking the concrete test specimens when corrosion of the reinforcing steel in concrete was perceived. It was observed from the test results that the critical chloride content for corrosion of reinforcing steel in concrete would be dependent on W/C ratio and almost irrespective of concrete cover.

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Effect of Ginseng petroleum Ether Fraction on the Immunotoxicity of Cadmium in Mice (II) (마우스에 있어서 카드뮴의 면역독성에 미치는 인삼 석유 Ether분획의 영향(II))

  • 안영근;김정훈;이상근;황갑수
    • Environmental Analysis Health and Toxicology
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    • v.3 no.3_4
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    • pp.1-8
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    • 1988
  • Experiment was performed to investigate the immunotoxicity of cadmium administered orally and the effect of ginseng petroleum ether fraction on it. Mice were given 3, 30, or 300 ppm cadmium as cadmium chloride orally in the drinking water and injection of ginseng petroleum ether fraction intraperitoneally for 4 weeks. Mice were sensitized and challenged u'ith sheep red blood cells (5-HBC). Immune response was evaluated by delayed type hypersensitivity (DTH), Rosette forming cell (RFC), phagocyte activity, and natural killer cell activity (NK cell activity). In the present study, cadmium suppressed the cellular immunity, It also depressed phagocyte activity very significantly in all cadmium-administered groups, NK cell activity in the cadmium-300 ppm administered group. Ginseng petroleum ether fraction showed restoring effect on the decrease in RFC by cadmium-administration. Remarkably, it showed very significant restoring effect on the depression of phagocyte activity induced by cadmium-administration. From this result, we suppose that the anti-tumor effect of ginseng ether or petroleum ether extract, which has been reported by some other researchers, is mainly due to the increase of phagocyte activity by it's administration.

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Poly(vinylbenzyl chloride-glycidyl methacrylate)/Polyethylene Composite Anion Exchange Membranes for Vanadium Redox Battery Application

  • Park, Min-A;Shim, Joonmok;Park, Se-Kook;Jeon, Jae-Deok;Jin, Chang-Soo;Lee, Ki Bong;Shin, Kyoung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1651-1655
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    • 2013
  • Anion exchange membranes for a vanadium redox flow battery (VRB) were prepared by pore-filling on a PE substrate with the copolymerization of vinylbenzyl chloride (VBC) and glycidyl methacrylate (GMA). The ion exchange capacity, water uptake and weight gain ratio were increased with a similar tendency up to 65% of GMA content, indicating that the monomer improved the pore-filling degree and membrane properties. The vanadium ion permeability and open-circuit voltage were also investigated. The permeability of the VG65 membrane was only $1.23{\times}10^{-7}\;cm^2\;min^{-1}$ compared to $17.9{\times}10^{-7}\;cm^2\;min^{-1}$ for Nafion 117 and $1.8{\times}10^{-7}\;cm^2\;min^{-1}$ for AMV. Consequently, a VRB single cell using the prepared membrane showed higher energy efficiency (over 80%) of up to 100 cycles compared to the commercial membranes, Nafion 117 (ca. 58%) and AMV (ca. 70%).

Combination Effects of Potassium Sorbate and Sodium Benzoate with Sodium Chloride on the Growth of Bacillus subtilis (Bacillus subtilis의 생육에 미치는 식염과 Potassium Sorbate, Sodium Benzoate의 병용효과)

  • Yang, Yeo-Young;Youn, Jung-Hae;Cho, Nam-Sook;Choi, Eon-Ho
    • Korean Journal of Food Science and Technology
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    • v.20 no.1
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    • pp.23-27
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    • 1988
  • In order to investigate the combined effect of potassium sorbate and sodium benzoate and the synergistic effect of sodium chloride on bacterial cell growth inhibition, Bacillus subtilis was cultured with or without shaking in tryptone-glucose-yeast extract broth containing 0.1% potassium sorbate and/or 0.03% sodium benzoat, which are equivalent to half of the maximum permissible levels, respectively. The combined treatment of the two preservatives did not show any synergistic effect of tne growth inhibition of B. subtilis. Addition of 2% sodium chloride, however, showed remarkable synergistic effect on the growth inhibition of the bacterium by potassium sorbate.

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Effects of Addition of Electrolyte and Ascorbic Acid in Feed during Heat Stress in Buffaloes

  • Kumar, B.V. Sunil;Singh, G.;Meur, S.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.7
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    • pp.880-888
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    • 2010
  • The ameliorative effect of salts and ascorbic acid polyphosphate supplementation on heat stress was studied in buffaloes. Adult buffaloes of either sex were randomly divided into 2 groups of 4 animals each. Group I served as control and Group II was supplemented with sodium bicarbonate, potassium carbonate and ascorbic acid polyphosphate. All the animals were exposed to two conditions of temperature and humidity: hot-dry and hot-humid in a psychrometric chamber for 4 h daily for 10 days. Blood was collected on day 1, 5 and 10 of treatment. The activities of catalase and superoxide dismutase (SOD), concentrations of serum glutathione (GSH), cortisol, sodium, potassium, and chloride and lipid peroxidation were estimated in serum. Lymphocyte proliferation was assessed in blood. The activities of catalase and SOD, serum concentration of GSH, sodium, potassium and chloride decreased while lipid peroxidation and serum cortisol increased in both groups when subjected to heat stress. Dietary supplementation resulted in further decreasing of the enzyme activities but increasing of the serum concentrations of GSH, sodium, potassium and chloride. Lipid peroxidation and serum cortisol increased in the supplemented group in both types of stress. Dietary supplementation caused an increase in lymphoproliferative response to con A. Thus, supplementation of ascorbate in addition to electrolytes relieves the animals of oxidative stress and boosts cell mediated immunity.

A Case of Secondary FSGS due to Chronic Chloride Diarrhea

  • Kim, Byung Kwan;Lee, Hyun Soon;Yim, Hyung Eun;Cheong, Hae Il;Yoo, Kee Hwan
    • Childhood Kidney Diseases
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    • v.20 no.2
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    • pp.83-87
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    • 2016
  • Congenital chloride diarrhea (CLD) is a rare autosomal recessive disease that is difficult to diagnose. CLD requires early treatment to correct electrolyte imbalance and alkalosis and to prevent severe dehydration. Renal injury is clearly associated with defective electrolyte balance induced by CLD, particularly during the first months or years of life. A 7-year-old boy was diagnosed with CLD following detection of a homozygous mutation (c.2063-1G>T) in SLC26A3 at 6 months of age. During treatment with electrolyte supplements, mild proteinuria was detected at 8 months of age, and is still present. Renal biopsy showed the presence of focal renal dysplasia, with metaplastic cartilage and mononuclear cell infiltration, calcification, and fibrosis in the interstitium. Up to two-thirds of the glomeruli exhibited global obsolescence, mostly aggregated in the dysplastic area. In nondysplastic areas, the glomeruli were markedly increased in size and severely hypercellular, with increased mesangial matrix, and displayed segmental sclerosis. The marked glomerular hypertrophy with focal segmental glomerulosclerosis suggested a compensatory reaction to the severe nephron loss or glomerular obsolescence associated with renal dysplasia, with superimposed by CLD aggravating the tubulointerstitial damage.

In Vitro Mammalian Chromosomal Aberration Test of Allyl Chloride for Workers' Health (근로자의 건강보호를 위한 알릴 염화물의 포유류 배양세포 염색체이상시험)

  • Rim, Kyung-Taek;Kim, Soo-Jin
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.2
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    • pp.160-168
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    • 2014
  • Objectives: Chemical hazard evaluations are important for workers' health and working environments. Allyl chloride (CAS No. 107-05-1) is used in many industries, leading to concerns about the possibility of threats to the health of workers. Since only insufficient or controversial information is available about potential related hazards, an in vitro mammalian chromosomal aberration (CA) assay was conducted in order to gain additional information concerning any such hazards. Moreover, toxicological information from this study could be applied for workers' rights to know, and to prepare or update the Materials Safety Data Sheet (MSDS) for a number of industries. Methods and Results: The assay was performed using the Chinese hamster lung fibroblast cell (ATCC, CRL-1935), by the direct method (-S9) and by the metabolic activated method (+S9 mix). Using the direct method, the seven dosages in the 48-hour treatment group did not show that the frequency of CA is proportionate to the dosage. The frequency of CA is not proportionate to the dosage addition for a six-hour treatment using the metabolic activated method. Conclusions: From these findings, it was decided that this chemical does not induce chromosomal aberrations under the tested conditions.

Isolation and Identificatioh~ of a Phthalate Ester Degrading Bacterium and the Optimal Culture Conditions for Production of One Degrading Enzyme (프탈레이트 에스터 분해세균의 분리 및 분해효소의 최적 생성조건)

  • Kim, Byung-O;Kim, Ran-Sug;Jin, Ing-Nyol;Park, Wan
    • Microbiology and Biotechnology Letters
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    • v.18 no.6
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    • pp.553-559
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    • 1990
  • A strain degrading phthalate ester was isolated from a sludge of Taegu area and identified as a strain of Klebsiella. The optimum culture conditions for the protocatechuate dioxygenase production were also investigated. This strain produced the enzyme in question under the shaking cultivation at $30^{\circ}C$for the 48 hrs in the medium containing 0.1% protocatechuate as the sole carbon source, 0.1% ammonium sulfate and 0.1% yeast extract as the nitrogen source and mineral salt mixture of magnesium sulfate, sodium chloride, calcium chloride, ferric chloride, manganese sulfate, zinc sulfate and cupric sulfate. This enzyme was intracellularl j localized and probably linked to cell membrane, and induced by protocatechuate.

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Estimation of Critical Chloride Threshold Value in Concrete by the Accelerated Corrosion Test

  • Vicho, Victor C.;Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.201-204
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    • 2006
  • It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mix proportions, cement type and constituents, presence of admixtures, environmental factors, reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and cyclic wet and dry seawater method, respectively and during the test, corrosion monitoring by half-cell potential method was carried out to detect the time to initiation of corrosion for individual test specimen. For this purpose, lollypop and right hexahedron test specimens were made for 31%, 42%, and 50% of W/C, respectively, and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with the water-cement ratio and accelerated corrosion test method, respectively and the critical chloride threshold values were found to range from 0.91 to $1.47kg/m^3$.

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Study on the Effect of Radix polygoni Multiflori on Cultured Mouse Cerebral Neurons Damaged by Organic Mercury (하수오가 유기수은으로 손상된 생쥐의 배양대뇌신경세포에 미치는 영향에 관한 연구)

  • Yoo Kyo Sang;Lee Yong Suk;Son Young Woo;Hong Gi Youn
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.6
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    • pp.1134-1137
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    • 2002
  • To investigate the neurotoxic effect of organic chloride on cultured mouse cerebral neurons, cytotoxic effect was measured by MTT assay after cultured cerebral neurons were incubated with various concentrations of methyl mercuric chloride(MMC) for 24 hours. The protective effect of Radix Polygoni Multiflori(RPM) on MMC-induced neurotoxicity was also examined in these cultures. MMC decreased cell viability of cultured mouse cerebral neurons remarkably in a dose- and time-dependent manners. In protective effect of RPM it was remarkably effective in blocking the neuroxicity induced by MMC. From aboved the results, it is suggested that MMC induce neurotoxicity, and the herba extract, RPM is very effective in preventing MMC-induced cytotoxicity on cultured mouse cerebral neurons.