• Proceedings of the Korean Institute of Building Construction Conference
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• v.y2004m10
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• pp.71-76
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• 2004

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

• Journal of the Korea Concrete Institute
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• v.26 no.1
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• pp.71-78
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• 2014

The long term integrity of concrete cask is very important for spent nuclear fuel dry storage system. However, there are serious concerns about early deterioration of concrete cask from creaking and corrosion of reinforcing steel by chloride ion because the cask is usually located in seaside, expecially by combined deterioration such as chloride ion and heat, carbonation. This study is to investigate the relation between temperature and chloride ion diffusion of concrete. Immersion tests using 3.5% NaCl solution that were controlled in four level of temperature, i.e. 20, 40, 65, and $90^{\circ}C$, were conducted for four months. The chloride ion diffusion coefficient of concrete was predicted based on the results of profiles of Cl- ion concentration with the depth direction of concrete specimens using the method of potentiometric titration by $AgNO_3$. Test results indicate that the diffusion coefficient of chloride ion increases remarkably with increasing temperature, and there was a linear relation between the natural logarithm values of the diffusion coefficients and the reciprocal of the temperature from the Arrhenius plots. Activation energy of concrete in this study was about 46.6 (W/C = 40%), 41.7 (W/C = 50%), 30.7 (W/C = 60%) kJ/mol under a temperature of up to $90^{\circ}C$, and concrete with lower water-cement ratio has a tendency towards having higher temperature dependency.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.112-118
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• 2022

In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

• Journal of the Korea Concrete Institute
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• v.16 no.2 s.80
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• pp.261-268
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• 2004

Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing methods on the coefficients of chloride diffusion. Also, it is surveyed the relationship between total chloride and free chloride in concrete. According to this experiment results, W/C ratio and testing method affect chloride diffusion coefficient of concrete. As W/C ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different values, respectively. The model equation of diffusion coefficient with W/C ratio is proposed.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.15 no.2
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• pp.71-79
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• 2003

The estimation functions were proposed for calculating diffusion coefficient, chloride binding, and evaporable water. The program estimating chloride ion penetration was developed on the basis of these functions and the effects of humidity, curing temperature, water-cement ratio, and $C_3$A on chloride penetration were analyzed. The relative humidity increases the depth of chloride ion penetration and the trend becomes greater with aging. On the contrary, the influence of curing temperature on chloride ion penetration decreases with aging. By the way, the rise of $C_3$A in cement increases total chloride concentration on the surface as the bound chloride concentration increases but it decreases total chloride concentration on the inner part as the diffusion velocity of free chloride decreases. The fall of water-cement ratio decreases the chloride penetration depth rapidly. Therefore, the reduction of water-cement ratio may be the most effective method for reducing of the steel corrosion by chloride penetration.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.413-418
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• 2000

The test results on the deterioration process of concrete under single and combined action of chloride penetration have been obtained. Within the test period of 15 weeks, it is seen that the internally penetrated chloride ion contents are slightly less in the combined action of NaCI and $Na_2SO_4$ than the single action of NaCI. Also the theoretical prediction of chloride penetration based on measured diffusion coefficient agress well with the test data of single deterioration process but disagress with that of combined process. Therefore it should be needed that improved chloride diffusion model for the combined deterioration process.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.34-39
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• 2014

The purpose of this experimental research is to evaluate the resistance of reinforcement corrosion and chloride ion penetration of high volume fly ash (HVFA) concrete. For this purpose, concrete test specimens were made for various strength level and replacement ratio of fly ash, and then compressive strength and diffusion coefficient for chloride ion of them were measured for 28, 91 and 182 days, respectively. Also, corrosion monitoring by half cell potential method was carried out for the made lollypop concrete test specimens to detect the time of corrosion initiation for reinforcement in concrete. As a result, it was observed from the test results that compressive strength of HVFA concrete was decreased with increasing replacement ratio of fly ash but long-term resistance against reinforcement corrosion and chloride ion penetration of that was increased.

• Computers and Concrete
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• v.34 no.2
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• pp.169-178
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• 2024

To circumvent the constraints of time-consuming experimental methods, numerical simulation can be one of the most effective approaches to investigating chloride diffusion behaviors in concrete. However, except for the effect of the external environments, the transport direction of the chloride cannot be neglected when the concrete is exposed to the marine tidal zone, especially in certain areas of concrete members. In this study, based on Fick's second law, considering the effects of timevarying, chloride binding capacity, concrete stress state, ambient temperature, and relative humidity on chloride diffusion coefficient, the modified one-dimensional, two-dimensional, and three-dimensional novel modified chloride diffusion theoretical models were established through defining the current boundary conditions. The simulated results based on the novel modified multi-dimensional model were compared with the experimental results obtained from some previous pieces of literature. The comparing results showed that the modified multi-dimensional model was well-fitted with experimental data, confirming the high accuracy of the novel modified model. The experimental results in literature showed that the chloride diffusion in the corner area of the concrete structure cannot be simulated by a simple one-dimensional diffusion model, where it is necessary to select a suitable multi-dimensional chloride diffusion model for simulation calculation. Therefore, the novel modified multi-dimensional model established in this study has a stronger applicability for practical engineering.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.617-620
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• 2008

When the RC structure repaired by patching repair method, which method refilles with patching repair material after removes degraded area, It is necessary to determine chloride ion's permeation from outside of the RC structure repaired by patching repair material. Therefore, in this study, damage from sea environment of structure was predicted, moreover, diffusion coefficient of concrete also determined to figure out rebar's corrosion and concentration of chloride ion. RCPT(Rapid Chloride Permeability Test) was used for ditermination of patching repair material's diffusion coefficient, also connection between material thickness and effect of chloride ion's permeation was examined in analytically. Results which derived by experimental test was used in FEM(Finite Element Method) and equation suggested by JSCE to predict concentration of chloride ion in different distance from surface.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.4
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• pp.48-54
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• 2024

NPP (Nuclear power plant) structures have been constructed near to the sea shore line for cooling water and exposed to steel corrosion due to chloride attack. Regarding NPP structures built in the UAE, chloride transport may be more rapid than those in the other regions since the temperature near to the coast is high. In this study, concrete samples with 5,000psi (35MPa) design strength grade were manufactured with the materials and mix proportions, which were the same as used in the UAE NPP structures, then chloride diffusion coefficients were evaluated considering temperature and curing age. The compressive strength and the diffusion coefficient were evaluated and analyzed for the samples with 28 and 91 curing days. In addition, chloride diffusion tests for 91-day-cured condition were carried out in the range of 20℃ to 50℃. The activation energy was obtained through converting the temperature slope to a logarithmic function and it was compared with the previous studies. The proposed activation energy can be useful for a reasonable durability design by using actual temperature-dependent chloride diffusion coefficient.