• Title/Summary/Keyword: chemistry-fiber

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Synthesis and Characterization of Poly(trimethylene terephthalate) via TPA Process Using Titanium Catalyst

  • Kim, Kap-Jin;Park, Jung-Il;Pio Sifuentes;Lee, Jong-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.92-92
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    • 2003
  • poly(trimethylene terephthalate) (PTT) was synthesized via condensation polymerization using different molar ratios of 1,3-propane diol (PDO)/terephthalic acid (TPA) in the presence of tetraisopropyl titanate (TiPT) as a polyesterifi-cation catalyst. The effect of reaction conditions on the characteristics of as-polymerized PTT was investigated.

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Rheological Properties of Organic Fiber-Reinforced Thermoplastics (유기섬유 강화 열가소성 복합재료의 유변학적 특성)

  • Lee, Yong-Mu;Cha, Yun-Jong;Kim, Seong-Hyeon;Yun, Yeo-Seong;Yun, Ju-Ho;Choe, Hyeong-Gi
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.786-795
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    • 1996
  • The fiber reinforced thermoplastics(FRTP) were prepared with polypropylene fiber(PP) as matrix and polyvinyl alchol(VF), aramid(KF) or polyamide fiber(PAF) as the reinforcing materials using the integrated fiber mixing apparatus. The reinforced thermoplastic sheets were prepared by com¬pression molding and their morphology, rheological and mechanical properties were characterized. In the morphological properties of composites, the wettability of the reinforced thermoplastics were decreased in proportion to the content of fibers. At low angular frequency, the viscosity of PAF /PP and VF/PP composite was increased with the content of reinforced fiber. However at high frequency the viscosity of composite reinforced with 5~20wt% fiber, was shown the reduced values which approaches that of the neat matrix. The mechanical properties of the composite were changed with the content of reinforecd fiber, and VF/PP and KF/PP composite had better properties than PAF/PP system.

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Synthesis and Properties of Nylon 6/PEG Random Block Copolymer/Clay Nanocomposite via in situ Polymerization (in situ중합을 통한 나일론 6-PEG 랜덤공중합체/점토 나노복합체의 합성 및 물성)

  • Angelica S. Lopez;Pio Sifuentes;Kim, Kap-Jin
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.72-74
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    • 2003
  • There has been extensive interest in the development of new nanocomposites. One kind of these systems is the hybrid based on organic polymers and inorganic minerals consisting of layered silicates. Some properties like stiffness, strength, barrier properties, thermal, and oxidative stability can be improved by the presence of the filler in the polymeric matrix[1]. It is reported that, in the nylon 6/clay nanocomposites, the modulus is increased, but impact strength and elongation at break are drastically decreased. (omitted)

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Preparation of Carbon Fiber from Heavy Oil Residue through Bromination

  • Park, Young-Ok;Yang, Kap-Seung
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.178-183
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    • 2001
  • A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

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The Effect of an External Electric Field on Phase Separation, Phase Dissolution, and Isothermal Crystallization Behavior of Poly(vinylidene fluoride)/Poly(1,4-butylene adipate) Blends

  • Kim, Kap-Jin;Lee, Jong-Soon
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.7-8
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    • 2003
  • Since PVDF/poly(1,4-butylene adipate) blend shows much lower LCST curve compared with PVDF/PMMA blend, the PVDF/PBA blend can be a good candidate for investigating the effect of the electric field on the phase separation and dissolution behavior of an electro-active polymer and electro-inactive polymer blend. (omitted)

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Hydrophobic modification of PVDF hollow fiber membranes using polydimethylsiloxane for VMD process

  • Cui, Zhaoliang;Tong, Daqing;Li, Xue;Wang, Xiaozu;Wang, Zhaohui
    • Membrane and Water Treatment
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    • v.10 no.4
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    • pp.251-257
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    • 2019
  • Fabricating hydrophobic porous membrane is important for exploring the applications of membrane distillation (MD). In the present paper, poly(vinylidene fluoride) (PVDF) hollow fiber membrane was modified by coating polydimethylsiloxane (PDMS) on its surface. The effects of PDMS concentration, cross-linking temperature and cross-linking time on the performance of the composite membranes in a vacuum membrane distillation (VMD) process were investigated. It was found that the hydrophobicity and the VMD performance of the PVDF hollow fiber membrane were obviously improved by coating PDMS. The optimal PDMS concentration, cross-linking temperature and cross-linking time were 0.5 wt%, $80^{\circ}C$, and 9 hr, respectively.

Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.