• 제목/요약/키워드: chemistry-fiber

검색결과 583건 처리시간 0.025초

Synthesis and Characterization of Poly(trimethylene terephthalate) via TPA Process Using Titanium Catalyst

  • Kim, Kap-Jin;Park, Jung-Il;Pio Sifuentes;Lee, Jong-Soon
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.92-92
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    • 2003
  • poly(trimethylene terephthalate) (PTT) was synthesized via condensation polymerization using different molar ratios of 1,3-propane diol (PDO)/terephthalic acid (TPA) in the presence of tetraisopropyl titanate (TiPT) as a polyesterifi-cation catalyst. The effect of reaction conditions on the characteristics of as-polymerized PTT was investigated.

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유기섬유 강화 열가소성 복합재료의 유변학적 특성 (Rheological Properties of Organic Fiber-Reinforced Thermoplastics)

  • 이용무;차윤종;김성현;윤여성;윤주호;최형기
    • 한국재료학회지
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    • 제6권8호
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    • pp.786-795
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    • 1996
  • 열가소성 고분자 복합재료 개발을 위하여 매트릭스 수지로는 폴리프로필렌섬유(PP)를 사용하고 유기계 강화소재로 폴리비닐알코올(비닐론, VF), 아라미드(케블라-49, KF) 및 폴리아미드섬유(PAF)등을 사용하였다. 복합매트제조장치로서 복합매트를 제조하고 가열.압축하여 고분자 복합재료를 성형하였다. 제조한 고분자 복합재료의 형태학, 유변학적 및 기계적특성 등을 측정하였다. 형태학에서 미트릭스와 강화섬유 간의 젖음성은 강화섬유의 함량이 증가함에 따라 감소하는 경향을 보였다. PAF/PP와 VF/PP 복합재료에 대한 점성도는 낮은 주파수 영역에서 강화섬유의 함량이 증가됨에 따라 증가하였으나, 높은 주파주 영역에서 5-20wt%로 강화된 복합재료는 매트릭스인 PP에 근접하게 감소된 점성도를 나타냈다. 기계적 특성은 강화 섬유의 함량에 따라 변하였으며, VF/PP 및 KF/PP 복합재료가 PAF/PP 계에 비해 우수한 현상을 보였다.

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in situ중합을 통한 나일론 6-PEG 랜덤공중합체/점토 나노복합체의 합성 및 물성 (Synthesis and Properties of Nylon 6/PEG Random Block Copolymer/Clay Nanocomposite via in situ Polymerization)

  • Angelica S. Lopez;Pio Sifuentes;Kim, Kap-Jin
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 봄 학술발표회 논문집
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    • pp.72-74
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    • 2003
  • There has been extensive interest in the development of new nanocomposites. One kind of these systems is the hybrid based on organic polymers and inorganic minerals consisting of layered silicates. Some properties like stiffness, strength, barrier properties, thermal, and oxidative stability can be improved by the presence of the filler in the polymeric matrix[1]. It is reported that, in the nylon 6/clay nanocomposites, the modulus is increased, but impact strength and elongation at break are drastically decreased. (omitted)

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Preparation of Carbon Fiber from Heavy Oil Residue through Bromination

  • Park, Young-Ok;Yang, Kap-Seung
    • Fibers and Polymers
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    • 제2권4호
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    • pp.178-183
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    • 2001
  • A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

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The Effect of an External Electric Field on Phase Separation, Phase Dissolution, and Isothermal Crystallization Behavior of Poly(vinylidene fluoride)/Poly(1,4-butylene adipate) Blends

  • Kim, Kap-Jin;Lee, Jong-Soon
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.7-8
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    • 2003
  • Since PVDF/poly(1,4-butylene adipate) blend shows much lower LCST curve compared with PVDF/PMMA blend, the PVDF/PBA blend can be a good candidate for investigating the effect of the electric field on the phase separation and dissolution behavior of an electro-active polymer and electro-inactive polymer blend. (omitted)

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Hydrophobic modification of PVDF hollow fiber membranes using polydimethylsiloxane for VMD process

  • Cui, Zhaoliang;Tong, Daqing;Li, Xue;Wang, Xiaozu;Wang, Zhaohui
    • Membrane and Water Treatment
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    • 제10권4호
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    • pp.251-257
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    • 2019
  • Fabricating hydrophobic porous membrane is important for exploring the applications of membrane distillation (MD). In the present paper, poly(vinylidene fluoride) (PVDF) hollow fiber membrane was modified by coating polydimethylsiloxane (PDMS) on its surface. The effects of PDMS concentration, cross-linking temperature and cross-linking time on the performance of the composite membranes in a vacuum membrane distillation (VMD) process were investigated. It was found that the hydrophobicity and the VMD performance of the PVDF hollow fiber membrane were obviously improved by coating PDMS. The optimal PDMS concentration, cross-linking temperature and cross-linking time were 0.5 wt%, $80^{\circ}C$, and 9 hr, respectively.

Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • 제5권2호
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.