• Title/Summary/Keyword: chemical-recycled

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A Study on the Quality Improvement of Recycled Fine Aggregate by Microwave Heating Technology, Friction and Abrasion Action (마이크로파 가열기술 및 마찰.마쇄 작용에 의한 순환잔골재 품질향상에 관한 연구)

  • Choi, Hyeong-Gil;Lee, Eui-Ba;Kwon, Soo-Kil;Lee, Do-Heun;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.337-338
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    • 2009
  • Use of the recycled fine aggregate as a material of structural concrete is not easy currently because there are some problems, such as of quality control and the uncertainty of chemical and physical property. Thus, the results indicate that it is possible to produce high quality recycled fine aggregate for structure by microwave heating technology, friction and abrasion action.

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Application of Paper and Paperboard Packaging for the Environmental Issues in U.S.A and E.U (환경을 고려한 선진국의 지.판지 포장재 적용 추세)

  • Kim, Jae-Neung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.3 no.2
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    • pp.33-42
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    • 1996
  • The portion of the recycled paper and paper board packaging material has been the highest in recycled municipal solid waste since 1960 but still the portion of the discarded paper and paper board packaging material is the highest (32.3%) in whole discarded municipal solid waste in USA. In order to reduce more the discarded paper and paper board, the common municipal solid waste treatments were compared and recycling treatment was still recommended for the the discarded paper and paper board rather than of the waste treatments, landfill, incineration, and source reduction. In this paper, the obstacled of recycling treatment of the paper and paper board in municipal solid waste and new application of recycled paper and paper board packaging material are discussed.

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Synthesis of nano Cerium(IV) oxide from recycled Ce precusor (재생 세륨 전구체로부터 나노산화세륨(IV)합성)

  • Kang, Tae-Hee;Koo, Sang-Man;Jung, Choong-Ho;Hwang, Kwang-Taek;Kang, Woo-Kyu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.2
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    • pp.101-107
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    • 2013
  • Cerium compounds such as Cerium hydroxide ($Ce(OH)_3$), Cerium chloride ($CeCl_3{\cdot}nH_2O$), Cerium carbonate hydrate ($Ce_2(CO_3)_3{\cdot}8H_2O$), Cerium oxide ($CeO_2$) were synthesized using recycled Ce precursor. Cerium(IV) oxide of nanoparticles were obtained by Ultra-sonication. Cerium-sodium- sulfate compound was synthesized through acid-leaching and addition of sodium sulfate from 99 wt% purity of Ce precursor as a starting material that was recycled from the waste polishing slurry. Moreover Cerium hydroxide was obtained from Cerium-sodium-sulfate compound by adding to sodium hydroxide solution. Then Cerium chloride was synthesized by adding of hydrochloric acid to Cerium hydroxide. Needle-shaped Cerium carbonate hydrate was synthesized in the continuous process and Cerium(IV) oxide with 30~40 nm size was subsequently obtained by the calcinations and dispersion.

A Study on Hydration Properties of Recycled Cement Mortar using Admixture Materials (혼화재료를 혼입한 재생시멘트 모르터의 수화특성에 관한 연구)

  • Park, Cha-Won;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.4
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    • pp.79-86
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    • 2004
  • The purpose of this study was the development of a recycling process to recover the hydraulic properties of hydration products which account for a large proportion of cementitious powder from concrete waste. This process was performed to recycle cementitious powder as recycle cement. Therefore, after the theoretical consideration of the properties of recycle process of recycled aggregates and cementitious powder, we investigated the hydraulic properties of cementitious powder under various temperature conditions in hardened mortar which was modeled on concrete waste. And we analyzed properties of chemical reactions of recycled cement with admixture materials such as Fly-Ash, Blast Furnace Slag As a result of the experiment, the most effective method to recover hydraulic properties of the cementitious powder from concrete waste was condition of burning at 700℃ for 120 minute. And it is shown that the fluidity of mortar was decreased rapidly when the burning temperature of recycle cement was increased. However, the compressive strength and fluidity were improved significantly when admixture materials such as Fly-Ash or Blast Furnace Slag was added.

Characterization of Carboxylated Cellulose Nanocrystals from Recycled Fiberboard Fibers Using Ammonium Persulfate Oxidation

  • KHANJANZADEH, Hossein;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.231-244
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    • 2020
  • As a way of finding value-added materials from waste medium density fiberboard (MDF), this study characterized cellulose nanocrystals (CNCs) isolated by ammonium persulfate (APS) oxidation using recycled MDF fibers. Chemical composition of the recycled MDF fibers was done to quantify α-cellulose, hemicellulose, lignin, nitrogen, ash and extractives. The APS oxidation was performed at 60 ℃ for 16 h, followed by ultrasonication, which resulted in a CNC yield of 11%. Transmission electron microscope images showed that rod-like CNCs had an average length and diameter of 167±47 nm and 8.24±2.28 nm, respectively, which gave an aspect ratio of about 20. The conductometric titration of aqueous CNCs suspension resulted in a carboxyl content of 0.24 mmol/g and the degree of oxidation was 0.04. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy clearly showed the presence of carboxyl group on the CNCs prepared by the APS oxidation. The change of pH of the aqueous CNC suspension from 4 to 7 converted the carboxyl group to sodium carboxylate group. These results showed that the APS oxidation was facile and CNCs had a one-step preparation method, and thus suggested an optimization of the oxidation condition in future.

CHARACTERISTICS AND STRENGTH EVALUATION OF THE MIXED MATERIAL OF FLY ASH FROM MUNICIPAL SOLID WASTE INCINERATOR AND THE RECYCLED POLYPROPYLENE

  • Park, Sang-Min;Kim, Hwan-Gi
    • Environmental Engineering Research
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    • v.11 no.5
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    • pp.257-265
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    • 2006
  • The purpose of research is to mix the fly ash from municipal solid waste incinerator in the recycled Polypropylene and to recycle. The specimen was produced by mixing 20 wt.% of MSWI fly ash at maximum in the recycled Polypropylene and the particle size analyzer, DSC, TGA, SEM and UTM instruments were used to analyze the physical chemical properties of the specimen. As a result of measurement, the average particle size of MSWI fly ash was $18.08\;{\mu}m$. In TGA analysis, the temperature of specimen S-5 at 50% of weight decrease was risen by $7^{\circ}C$ higher than specimen S-1. In UTM measurement, specimen S-2 showed the maximum strength for tensile strength and specimen S-3 showed the maximum strength for flexural strength. But, impact strength was decreased according to the increasing proportion of MSWI fly ash. In conclusion, when the proper amount of MSWI fly ash was added to the recycled Polypropylene, thermal endurance, tensile strength and flexural strength could be increased, but impact strength was decreased.

A STUDY OF BONDING STRENGTH AND CHANGE OF BRACKET SLOT WIDTH OF CHEMICALLY RECYCLED METAL BRACKETS (화학적(化學的)으로 재생(再生)된 금속(金屬) bracket의 접착(接着) 강도(强度)와 slot폭경(幅徑) 변화(變化)에 관(關)한 연구(硏究))

  • Ko, Young-Sam;Lee, Dong-Joo
    • The korean journal of orthodontics
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    • v.20 no.2
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    • pp.283-291
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    • 1990
  • The purpose of this study was to measure and compare tensile and shear strength for 4 types of new direct-bonding brackets and same brackets after recycling and to evaluate the change of bracket slot width after recycling. Four types of new direct-bond brackets were bonded to recently extracted human premolar teeth and the tensile and shear strength was measured by Universal Testing Machine. The brackets were recycled by chemical process and the tensile and shear test was repeated. To evaluate the change of the bracket slot width, slot width was measured by the Topcon Universal Measuring Microscope before and after recycling. Following results were obtained: 1. There was no satistically significant difference between the tensile and shear strength of recycled brackets and those of new brackets. 2. In both new and recycled brackets, the tensile and shear strength of perforated base bracket was lower than those of photoetched, foilmesh and contou-lok mesh base brackets. (P<0.01) 3. There was no statistically significant difference in bonding strengths of control group bonded only once and two times. 4. There was no statistically significant difference in the change of the bracket slow width after recycling process. 5. Of the failure, the combination type (58%) in the tensile strength and the tooth adhesive interface (65%) in the shear strength was the most common type.

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Image and Phase Analysis of Low Carbon Type Recycled Cement Using Waste Concrete Powder (폐콘크리트 미분말을 사용한 저탄소형 시멘트의 조직 및 상분석)

  • Song, Hun;Shin, Hyeon-Uk;Lee, Jong-Kyu;Chu, Yong-Sik;Park, Dong-Chan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.314-320
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    • 2014
  • Although the cement industry serves as the cornerstone of the construction industry by supplying one of its fundamental materials, it confronts new environmental challenges due to the problem of the $CO_2$ generated from raw materials and fuel used in the cement manufacturing process. Also, concrete structures can be decomposed and reused as construction materials. Simply in terms of the cyclic processing of $CO_2$, recycling waste concrete to manufacture recycled aggregate or recycling waste concrete powder, which is the material for cement can be considered optimally environment-friendly practices. This study contributes to the aim of manufacturing high value added materials that exploits the chemical properties of the waste concrete powder. From the research results, waste concrete powder is feasible to use to produce low carbon type recycled cement.

Deamination of MDA in the Recycled Polyol Obtained from the Glycolysis of Waste MDI Based Polyurethane Foam

  • Kim, Min-Gyu;Kim, Sang-Hern;Chun, Jong-Han;Soon, Lee-Young
    • International Journal of Safety
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    • v.4 no.1
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    • pp.14-17
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    • 2005
  • Recycled polyol was obtained by glycolysis of MDI-based Polyurethane(PU) rigid foam. The chemical structure of the recycled pclyol was confirmed by GC(gas chromatography) and 1H-NMR. The recycled polyol throughout the glycolysis contained liquid polyol and methylenedianiline(MDA). MDA which could cause liver cancer is carcinogenic material. TWA(Time Weighted Average.) amount for MDA in MSDS(Material Safety Data Sheets) was confined less than 0.1 ppm. The melting temperature of MDA is $92^{\circ}C$, and boiling temperature is $398^{\circ}C$. During the gylcolysis most of MDA was dissolved in liquid polyol. The probability that MDA diffuses into the atmosphere is low but there could be an absorption of MDA into skin. Furthermore because MDA is amine compound, recycled polyol which contained MDA had a difficulty in reaction control of polyurethane. Therefore reduction of MDA amount was needed strongly. In this study the elimination of MDA were performed through deamination of the recycled polyol by glycidyl ether compounds. As glycolysis was proceeded, the amount of MDA was 9.8 wt % at early stage and increased up to 14.0 wt % after 8 hours reaction. It was found that 2-Ethylhexyl glycidyl ether which contains aliphatic moiety was very effective compound for eliminating the primary aromatic amine compound :md the optimal mole ratio of 2-ethylhexyl glycidyl ether to MAD was 3. The final polyol after deamination by 2-ethylhexyl glycidyl ether has an appropriate viscosity(less than 500 centi poise) for polyurethane reaction.