• Title/Summary/Keyword: chemical-recycled

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SEPARATION OF STRONTIUM AND CESIUM FROM TERNARY AND QUATERNARY LITHIUM CHLORIDE-POTASSIUM CHLORIDE SALTS VIA MELT CRYSTALLIZATION

  • WILLIAMS, AMMON N.;PACK, MICHAEL;PHONGIKAROON, SUPATHORN
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.867-874
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    • 2015
  • Separation of cesium chloride (CsCl) and strontium chloride ($SrCl_2$) from the lithium chloride-potassium chloride (LiCl-KCl) salt was studied using a melt crystallization process similar to the reverse vertical Bridgeman growth technique. A ternary $SrCl_2-LiCl-KCl$ salt was explored at similar growth rates (1.8-5 mm/h) and compared with CsCl ternary results to identify similarities. Quaternary experiments were also conducted and compared with the ternary cases to identify trends and possible limitations to the separations process. In the ternary case, as much as 68% of the total salt could be recycled per batch process. In the quaternary experiments, separation of Cs and Sr was nearly identical at the slower rates; however, as the growth rate increased, $SrCl_2$ separated more easily than CsCl. The quaternary results show less separation and rate dependence than in both ternary cases. As an estimated result, only 51% of the total salt could be recycled per batch. Furthermore, two models have been explored to further understand the growth process and separation. A comparison of the experimental and modeling results reveals that the nonmixed model fits reasonably well with the ternary and quaternary data sets. A dimensional analysis was performed and a correlation was identified to semipredict the segregation coefficient.

Development of Eco-Block for Grass Growth based on Expanded Vermiculite Absorbing Bacteria (박테리아 흡착 팽창질석 기반 친생태 잔디블록의 개발)

  • Yoon, Hyun-Sub;Jung, Seung-Bae;Yang, Keun-Hyeok;Lee, Sang-Seob;Lee, Jae-Yeung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.316-321
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    • 2016
  • This study developed an eco-block for grass growth using the expanded vermiculites that absorb bacteria selected considering for the high pH and dry environments and plant growth. For the developed eco-block, a fundamental properties including compressive strength gain and water absorption and ecology characteristics were tested. The selected bacteria was Bacillus alcalophilus a nd Rhodoblastus acidophilus and had high concentration of $10^9cell/mL$. The expanded vermiculite that was used for shelter of bacteria was added by 7.5% and 10% replacement of the natural aggregates by volume. The developed eco-block achieved the minimum requirements specified in SPS provision and significantly effective in reducing chemical Chemical Oxygen Demand(COD) concentration and enhancing the growth of fish and plant.

Effect of the Fineness of Fly Ash on the Compressive Strength (플라이애시 입도가 압축강도에 미치는 영향)

  • Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Ahn
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.313-319
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    • 2017
  • In general, various factors such as grain size, chemical composition, amorphous amount, amorphous Si and Al content of fly ash affect the reaction with cement. In this study, we investigate the effect of fly ash particle characteristics on compressive strength. The standard sand was pulverized to a particle size similar to that of fly ash and the compressive strength was measured by blending with the cement as in fly. Using the measured compressive strength results, strength enhancement by cement hydration reaction and strength enhancement by particle filling effect were confirmed. Strength increment by pozzolanic reaction of fly ash was calculated by using the compressive strength results of mortar substituted with standard powder. As a result of comparison between compressive strengths and the particle characteristics of fly ash, the blaine showed a weak correlation with the compressive strength and the PI(Pozzolanic Index) showed good correlation with the 10% penetration diameter(D10) and the 50% Respectively. Therefore, it is expected that PI will be a good means to evaluate the fly ash characteristics together with the chemical characteristics of fly ash.

Effect of the Organic Fertilizer Mixed with Various Recycled Coir Substrates on Chinese Cabbage(Brassica Campestris Ssp. Pekinensis) and Lettuce(Lactuca Sativa) (폐코이어를 재활용한 혼합 유기질 비료가 배추와 상추의 생육에 미치는 영향)

  • Lee, Gyu-Bin;Park, Eun-Ji;Park, Young-Hoon;Choi, Young-Whan;Suh, Jeong-Min;Kang, Jum-Soon
    • Journal of Environmental Science International
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    • v.24 no.9
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    • pp.1221-1231
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    • 2015
  • The present study was conducted to find a way to recycle the coir substrate by investigating changes in its physical and chemical properties based on the number of use year. Specific gravity of unused coir substrate was $0.212g/cm^3$, while it was higher for the substrate used for 2 years. Porosity was different depending on the number of use year. The porosity of unused substrate was 51.9%, but it increased to 68.6% after used for 2 years. In general, physical and chemical properties were better in the coir substrate used for 2 years than in unused one. The number of leaves, leaf area, flesh weight and dry weight of oriental cabbage and lettuce were higher in coir substrate used for 2 years than those in unused one. Whereas, no significant difference was observed between the substrates used for one year and 2 years, indicating that the one time-used wast substrate could be recycled for cultivating vegetables. Growth of the vegetables was improved when organic fertilizer composed of complex organics with different mixing ratios was provided to the coir substrate, compared to untreated plot. The optimum mixing ratio of the wast substrate and complex organics was 2:8(v/v) for fertilization using wast coir substrate. Therefore, coir substrate generally wasted after being used for one time was reuseable by supplying organic fertilizer.

Investigation for Utilization of Separator Bag Filter Cement (세퍼레이터 백필터 집진 미립자시멘트 (SBFC : Separator Bag Filter Cement)의 활용성 검토)

  • Kim, Kyoung-Min;Park, Sang-Joon;Yoo, Jea-Kang;Lee, Eui-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.78-83
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    • 2010
  • This paper presents the feasibility of incorporating ultrafine particles collected in the separator bag filter (separator bag filter cement, SBFC) during the cement manufacturing process as an substitution material for cement. SBFC does not require additional processes needed in the existing processes to manufacture high early strength cement such as modifying mineral components and adjusting the firing temperature. Moreover, it can also solve the issue of efficiency decrease resulted from the increase of the grinding time applied in the existing process of manufacturing microcement. Therefore, this research has examined the characteristics of SBFC and fresh properties and mechanical properties after making paste and mortar using SBFC in order to use SBFC as a material to gain early strength of concrete. For results, analyzing the chemical composition and physical properties of SBFC, its blaine value was $6,953cm^3/g$, about double than that of OPC, but its chemical composition showed no significant difference. According to the result of the paste and mortar examination, the paste and mortar mixed with SBFC showed a lower flowability, earlier setting time, and higher compressive strength than that with OPC. The result of microstructure analysis of paste, the paste mixed with SBFC indicated about 9% lower internal porosity at an early age than that of OPC. The compressive strength and flexural strength of mortar were higher in the order of SBFC ratio of 100, 50 and 0% SBFC.

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Availability Review of Tailings from the Sangdong Tungsten Mine as a Material for Construction (건설용 재료로서 상동광산광미의 활용성 검토)

  • Kim, Yong-Jic;Kim, Young-Jin;Choi, Yun-Wang;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.204-210
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    • 2013
  • This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine (TA) as admixture for concrete. TA has been accumulating for several decades in Sangdong, a region in Korea, and there is a growing demand for alternative uses for this hazardous substance. In particular, the use must be in accordance with the hazardous materials stipulations under the Korean waste control act. This study showed that TA presented pH of 8.0-9.3, 18.7-22.0% of water content, 2.7% of maximum ignition loss. The chemical composition of TA showed minute differences from each depth of sampling that represented approximately 50% of $SiO_2$ and 13% of both $Al_2O_3$ and $Fe_2O_3$. The chemical composition of Cd, Cu, Zn and Pb from mortar incorporating TA showed lower levels of hazardous materials which met the specifications of the waste control act in Korea. The TA mortar also appeared very effective for stabilizing/solidifying heavy metals particularly when used in conjunction with SG.

Development of moveable instrument for fuel of cement production and of clean process for cement production using waste plastics from agriculture (농업용 폐비닐을 이용한 이동식 시멘트 연료 제조 장치 및 이를 이용한 시멘트 제조 청정 공정 개발)

  • Seo, Hyung-Nam;Goo, Sang-Ser;Choi, Young-Ki;Min, Kyung-So;Kang, Seong-Gu;Oh, Hea-Kap
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.109-113
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    • 2004
  • In this study, we tried to develop the moveable instrument for fuel of cement production by using waste plastics from agriculture that was not recycled. First we investigated the burning character of recycled fuel and feasibility of second pollution. Then we made the instrument which can produce the solid fuel under 1cm size. In changing the inputting method from pre-heater to main burner, this reduces the NOx and O2 emission rate. and When we input it 0.5ton/hour, we obtain 0.2-0.3 ton/hour reduction of coal amount.

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Effect of Properties of Fly-ashes on the Characteristics of Fly-ash Mortars (플라이애시 종류에 따른 플라이애시 모르타르의 특성에 대한 연구)

  • Kim, Joo-Hyung;Park, Byoung-Sun;Jung, Sang-Hwa;Choi, Young-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.439-445
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    • 2016
  • Recently, a large number of researches about concrete containing high volume fly-ash(HVFA) have been carried to obtain carbon dioxide reduction, resource recycle and durable option in concrete industry. The quality of fly-ash such as chemical composition and fineness has high variability due to the differences of used fuels, operation condition in power plant. The aim of this study is to investigate the performances of fly-ash cement mortar containing different type of fly-ashes. The basic analysis of fly ash such as chemical composition, SEM image analysis were performed. Many mortar specimens were fabricated to evaluate the properties (compressive strength, drying shrinkage and carbonation) of mortar with various fly ash. From the test results, the quality of each fly ash must be considered and fully weighted in fly ash concrete.

A Study on the Recycling of Detoxified Waste Asbestos (무해화 처리 폐석면의 재활용에 관한 기초연구)

  • Kim, Tae-Hyoung;Song, Tae-Hyeb;Shin, Hyen-Gyoo;Jang, Kyung-Pil
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.161-166
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    • 2020
  • In accordance with the amendment of the Industrial Safety and Health Act of 2007, Korea completely prohibited the import, distribution and manufacture of asbestos like Europe and Japan. Accordingly, the current problem of asbestos is the safe maintenance and disposal of asbestos construction material, the disposal of asbestos, and the final disposal of asbestos building materials. If the asbestos building material is made harmless, it may be classified as general waste or as recyclable waste. Therefore, this study evaluated the physical and chemical characterization of detoxified asbestos powder and the applicability of secondary products. In this study, it was found that applying the appropriate temperature and pressure for catalysis during asbestos desalination through low temperature chemical treatment was the most important factor.

Influence of chemical and mechanical treatments of screened short fibers from OCC on paper forming and strength properties (골판지고지섬유의 단섬유분의 물리화학적처리에 관한 연구 - 골판지 고지의 물리화학적 처리에 의한 강도향상 제 4보 -)

  • Lee, Jong-Hoon;Seo, Yung B.;Choi, Chan-Ho;Jeon, Yang;Lee, Hak-Lae;Shin, Jong-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.04a
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    • pp.71-71
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    • 2000
  • Recycled fibers usually give slow drainage in the paper forming zone on papermachine, which limit the application of more refining to the fibers for improving paper strength and formation. To use recycled fibers, especially, OCC, more effectively, developing very efficient handling technique of short fibers and fines is inevitable. We tried to make hard flocs of fractionated short fibers and fines, which were the main cause of slow drainage, by adding excessive amount of retention aid on them. This technique was proved to increase drainage with no difference in strength properties, compared to the conventional technique of adding the same amount of polymers to the whole furnish in the lab test. The bonding capability of short fibers and fines in Korean OCC were very poor to be considered as ´fillers´in paper products. Various chemical treatment on the short fibers and fines of the Korean OCC did not improve their bonding and optical properties. One of the reasons of no improvement in their properties was thought to be their high amount of ashes (over 30% in the fractionated samples).

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