• 제목/요약/키워드: chemical transportation

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The control of Interleaved Multi-phase Boost Converter for Application of a Fuelcell Railway Vehicle (연료전지 철도차량 적용을 위한 인터리브드 다상 승압형 컨버터 제어)

  • Kim, Jae-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.11
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    • pp.1925-1930
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    • 2016
  • Fuel cell power generation system, unlike conventional energy sources, converts chemical energy into electrical energy through electrochemical reaction of hydrogen and oxygen. This paper presents the control of interleaved multi-phase boost converter as the feasibility study on small-scale prototype electric railway vehicle application using fuel cell generation system. PSIM simulation program is to be used to implement the modeling of the electrical fuelcell as well as traction motor control with interleaved multi-phase boost converter. Comparing the input current ripple rate, two-phase interleaved boost converter is less than the boost converter. But the more multi-phase not less proportional to the ripple factor. we confirmed that the amplitude of the input current ripple rate of converter depend on duty ratio.

Concentration of Airborne Fungi in Public Transportation during Operation (운행 중 대중교통차량 내 부유진균 농도 분석)

  • Kim, Hong-Gi;Cho, Eun-Min;Jeon, Bo-Il;Lee, Jeong-Hun;Kim, Ho-Hyun;Kwon, Hyuk-ku
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.757-763
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    • 2020
  • Objectives: The objective of this study was to evaluate the concentrations of airborne fungi in public transportation from autumnl 2016 to summer 2017. Methods: This study measured the concentrations of airborne fungi on six subway lines and intercity buses in Seoul. Results: The concentration of fungi in the air in public transportation was found to be lower than the standard (500 CFU/㎥) for vulnerable group facilities among public use facities. In summer, the concentration of airborne fungi was relatively higher than in autumn. The concentrations of airborne fungi in subway (252.0 CFU/㎥) and train (45.1 CFU/㎥) were high tendency during non-rush hours in summer, while intercity bus was hightendency during rush hours in summer (111.9 CFU/㎥). The major types of airborne fungi in public transportation were Cladosporium, Penicillium, and Aspergillus. Conclusions: The harmful airborne fungus were detected though they did not exceed the standard in all public transportation. As a result, further studies on the analysis of the distribution of airborne fungi by ventilation and the characterization of indoor environments are needed to propose effective management of airborne fungi in public transportation.

Propyl Gallate Inhibits Adipogenesis by Stimulating Extracellular Signal-Related Kinases in Human Adipose Tissue-Derived Mesenchymal Stem Cells

  • Lee, Jeung-Eun;Kim, Jung-Min;Jang, Hyun-Jun;Lim, Se-Young;Choi, Seon-Jeong;Lee, Nan-Hee;Suh, Pann-Ghill;Choi, Ung-Kyu
    • Molecules and Cells
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    • v.38 no.4
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    • pp.336-342
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    • 2015
  • Propyl gallate (PG) used as an additive in various foods has antioxidant and anti-inflammatory effects. Although the functional roles of PG in various cell types are well characterized, it is unknown whether PG has effect on stem cell differentiation. In this study, we demonstrated that PG could inhibit adipogenic differentiation in human adipose tissue-derived mesenchymal stem cells (hAMSCs) by decreasing the accumulation of intracellular lipid droplets. In addition, PG significantly reduced the expression of adipocyte-specific markers including peroxisome proliferator-activated receptor-${\gamma}$ (PPAR-${\gamma}$), CCAAT enhancer binding protein-${\alpha}$ (C/EBP-${\alpha}$), lipoprotein lipase (LPL), and adipocyte fatty acid-binding protein 2 (aP2). PG inhibited adipogenesis in hAMSCs through extracellular regulated kinase (ERK) pathway. Decreased adipogenesis following PG treatment was recovered in response to ERK blocking. Taken together, these results suggest a novel effect of PG on adipocyte differentiation in hAMSCs, supporting a negative role of ERK1/2 pathway in adipogenic differentiation.

The Application of CMB Model for Particulate Source Apportionment (분진오염원 할당을 위한 CMB모형의 적용)

  • 정장표;정창용
    • Journal of Environmental Science International
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    • v.3 no.4
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    • pp.393-402
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    • 1994
  • It is necessary to examine the source contributions and the relationship between a receptor and sources for the resonable controlling of air pollution level of suspended particulate matters. Therefore, in this study, profiles of sources contributing to the concentration of suspended particulate matters, were developed and CMB model was applied to obtain information of source contributions and feasibility of CMB model application. According to the propose of this study, twenty-seven chemical species such as the elements, anions, and total carbon of thirty-six PMl0 and TSP data sets sampled at the Pomch'on receptor site in Pusan for a 24-hr period from May to Aug. 1992, were analyzed and three (transportation, soil, marine) different source profiles were developed through the field measurement. Applying CMB model to transportation, soil, marine, the results of source contribution by CMB model showed that the case with TSP was more suitable for CMB model than that with PMl0. And the average contribution of transportation source to TSP and PMlo concentration at Pomch'on receptor was calculated as 90.66 ㎍/m3(64%) and 23.27 ㎍/m3(39%), resfiectively, which showed that the contribution by transportation was dominant. The validation of CMB model was performed by means of the results of contributions from marine source for the wind direction sectors.

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Extraction Equilibria of Acrylic Acid with Amine Extractants (아민계 추출제에 의한 아크릴산의 추출 평형)

  • Lee, Yong Hwa;Lee, Jun;Hong, Yeon Ki
    • Clean Technology
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    • v.20 no.2
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    • pp.103-107
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    • 2014
  • Acrylic acid is a commodity chemical which is applicable for various industries such as polymer and textile industry. Currently, it has been produced by chemical synthesis from petroleum. However, due to the high price of petroleum and global $CO_2$ emission, renewable materials such as sugar are interesting alternative carbon sources for the biological production of acrylic acid. For an economic production of acrylic acid from renewable carbon sources, a cost effective separation process for acrylic acid should be needed. In this study, reactive extraction by TOA (tri-n-octylamine) was used for the recovery of acrylic acid from its aqueous solutions. The effects of polarity of diluents and concentration of TOA on extraction equilibrium were investigated. The extraction efficiency was proportional to concentration of TOA and polarity of diluents and its value was more than 95% in the case of sufficient concentration of TOA. From IR spectroscopy, it was concluded that the ratio of (1,1) acid-amine complex was increased and the ratio of acid dimer was decreased with concentration of TOA. Equilibrium model based on IR spectroscopy was well fitted with experimental data.

Fabrication of TiAl alloy by centrifugal casting and its microstructure (원심주조법에 의한 TiAl 합금의 제조 및 미세구조 분석)

  • Ryu, Jeong Ho;Lee, Ho Jun;Cho, Hyun Su;Paeng, Jong Min;Park, Jong Bum;Lee, Jung-Il
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.5
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    • pp.229-234
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    • 2017
  • In this study, TiAl alloy was fabricated by a centrifugal casting method for turbo charge of automotive. Optimum conditions for defectless morphology using various ceramic mold were investigated. The crystal structure, microstructure, and chemical composition of the TiAl prepared by centrifugal casting were studied by X-ray diffractometer (XRD), optical microscopy (OM), field emission scanning electron microscopy (FE-SEM) and energy dispersive spectroscopy (EDS), microvickers hardness analyzer (HV). Two kinds of dendrite structures were observed with 4-fold and 6-fold symmetries. The FE-SEM, EDS and HV examinations of the as-cast TiAl showed that the thickness of the oxide layer (${\alpha}$-case) was typically less than $50{\mu}m$.

Thermal and Electrochemical Stability of Morpholinium Ionic Liquids (모폴린계 이온성 액체의 열 및 전기화학적 안정성)

  • Kim, Hyun-Taek;Hong, Yeon Ki;Kang, Jeong Won;Lee, Young-Woo;Kim, Ki-Sub
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.702-707
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    • 2012
  • During the last few decades, toxic chemicals used in various industries have caused global pollution and the side products such as carbon dioxide and methane gas have contributed to global warming. Thus, it is desirable to develop new alternative solvents. It is well known that ionic liquids display a variety of environmentally friendly physical properties: nonvolatile, nonflammable, wide electrochemical windows, high inherent conductivities, wide thermal operating ranges, chemically inert, and limited miscibilities with organic solvents. Because of these characteristics, ionic liquids are promising candidates as solvents for synthetic chemistries, catalysis, and gas separations. In this study, we synthesized morpholiunium salts as N-ethyl-N-methylmorpholine Bromide, N-butyl-N-methylmorpholine Bromide, N-octyl-N-methylmorpholine Bromide, N-ethyl-N-methylmorpholine Tetrafluoroborate, N-butyl-N-methylmorpholine Tetrafluoroborate, N-octyl-N-methylmorpholine Tetrafluoroborate, N-ethyl-N-methylmorpholine Hexafluorophosphate, N-butyl-N-methylmorpholine Hexafluorophosphate, and N-octyl-N-methylmorpholine Hexafluorophosphate. The melting points, decomposition temperatures and electrochemical stabilities of the salts were measured by DSC, TGA, and CV, respectively. The salts with halide anion showed high melting points ($150{\sim}200^{\circ}C$), low decomposition temperatures ($200{\sim}230^{\circ}C$), narrow electrochemical stabilities (3.4~3.6 V). The synthesized salts with inorganic anions, on the other hand, presented low melting point ($50{\sim}110^{\circ}C$), high decomposition temperatures ($250{\sim}380^{\circ}C$), wide electrochemical stabilities (6.1~6.3 V). We also found that the properties depend on the length of the carbon chain.

Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.648-652
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    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.