• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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• pp.463-469
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• 2012

Solar thermochemical syngas and hydrogen production process bv redox system of metal oxide was performed under direct irradiation of the metal oxide on the SiC ceramic foam device using solar simulator. $CeO_2/ZrO_2$ nanotube has been synthesized by anodic oxidation method. Syngas and hydrogen production process is one of the promising chemical pathway for storage and transportation of solar heat by converting solar energy to chemical energy. The produced syngas had the $H_2/CO$ ratio of 2, which was suitable for methanol synthesis or Fischer-Tropsch synthesis process. After ten cycles of redox reaction, $CeO_2$ was analyzed using XRD pattern and SEM image in order to characterize the physical and chemical change of metal oxide at the high temperature.

• 한국결정성장학회지
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• 제25권1호
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• pp.39-43
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• 2015

최근 콘크리트의 품질을 향상시키기 위하여 플라이애쉬, 고로슬래그, 실리카퓸과 같은 각종 시멘트 혼화재에 대한 많은 연구가 진행되고 있다. 이에 본 연구에서는 동합금 제련시 발생되는 슬래그의 시멘트 대체재로서의 활용성을 확인하기 위해 동합금 슬래그를 미분쇄하여 상용 포틀란트 시멘트에 첨가하고, 첨가량 변화에 따른 시멘트 모르타르의 유동성, 흡수율, 단위용적중량, 압축강도 및 휨강도 변화를 조사하였다. 또한 5 % 황산용액에서의 동슬래그 함유 시멘트 모르타르의 무게변화를 28일 동안 측정하여 화학적 저항성을 평가하였다.

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.51-61
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• 2022

Gas separation via hollow fibre membrane modules (HFMM) is deemed to be a promising technology for natural gas sweetening, particularly for lowering the level of carbon dioxide (CO₂) in natural gas, which can cause various problems during transportation and process operation. Separation performance via HFMM is affected by membrane properties, module specifications and operating conditions. In this study, a mathematical model for HFMM is developed, which can be used to assess the effects of the aforementioned variables on separation performance. Appropriate boundary conditions are imposed to resolve steady-state values of permeate variables and incorporated in the model equations via an iterative numerical procedure. The developed model is proven to be reliable via model validation against experimental data in the literature. Also, the model is capable of capturing axial variations of process variables as well as predicting key performance indicators. It can be extended to simulate a large-scale plant and identify an optimal process design and operating conditions for improved separation efficiency and reduced cost.

• Korean Chemical Engineering Research
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• 제52권5호
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• pp.564-573
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• 2014

이 연구는 벤젠과 프로필렌의 기상반응을 통해 쿠멘을 생산하는 쿠멘 생산 공정의 경제성 최적화에 대한 것이다. 최적화의 목적함수는 제품 판매 이득에서 자본비용, 유틸리티 비용, 원료 비용을 뺀 연간 조업이득이고, 설계변수는 6개이다. 설계변수의 변화에 따른 조업이득의 계산을 위해 Unisim Design과 Matlab을 연동하였다. 최적화는 3단계로 수행되었다. 설계변수를 샘플링한 후 조업이득 데이터를 얻고, 이 데이터로부터 설계변수와 조업이득의 관계를 추정 모델로 표현하고, 이 모델을 이용하여 최적화하였다. 추정모델로는 반응표면법에서 사용되는 2차 회귀 다항식과 비선형 모델인 support vector regression을 비교하였다. 설계변수의 샘플링 방법으로는 중심합성계획과 Hammersley 순차 추출법을 비교하였다. 각각 얻어진 모델을 이용한 최적화 결과, 추정방법으로는 SVR이, 샘플링 방법은 Hammersley 순차추출법이 더 정확하였다. 최적화된 조업이득은 연간 17.96 MM$로, 기준 조건에서의 연간 16.04 MM$에 비해 12% 증가하였다.

• 청정기술
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• 제21권2호
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• pp.124-129
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• 2015

본 연구에서는 5~30 bar의 이산화탄소에 대한 DMPEG250 (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), 그리고 TAT (triacetin)의 용해도를 측정하기 위해 일정 부피법에 따른 용해도 측정 장치를 사용하였다. 이들에 대한 이산화탄소 용해도는 측정된 부피와 압력을 Peng-Robinson 방정식에 대입하여 얻은 이산화탄소의 몰수로부터 얻어졌다. 이산화탄소에 대한 물리 흡수제의 용해도는 같은 온도에 대해 DMPEG250 > TAT > DEC > DMC 순으로 나타났다. DMPEG250에 DEC를 혼합한 물리 흡수제를 사용할 경우 이산화탄소에 대한 용해도는 DMPEG250 단독에 의한 경우보다 높은 값을 가지는 것으로 확인되었다. 그러므로 DEC가 혼합된 DMPEG250/DEC 혼합 물리 흡수제는 기존의 DMPEG250이 가지는 높은 비용을 절감할 수 있을 뿐 아니라 용해도 향상까지 거둘 수 있어 향후 연소 후 이산화탄소 포집 공정에 효과적인 적용을 기대할 수 있다.

• 한국안전학회지
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• 제33권1호
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• pp.66-72
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• 2018

This study analyses the types, related operations, facilities, and causes of chemical accidents in Korea based on the RISCAD classification taxonomy. In addition, human error analysis was carried out employing different human error classification criteria. Explosion and fire were major accident types, and nearly half of the accidents occurred during maintenance operation. In terms of related facility, storage devices and separators were the two most frequently involved ones. Results of the human error-based analysis showed that latent human errors in management level are involved in many accidents as well as active errors in the field level. Action errors related to unsafe behavior leads to accidents more often compared with the checking behavior. In particular, actions missed and inappropriate actions were major problems among the unsafe behaviors, which implicates that the compliance with the work procedure should be emphasized through education/training for the workers and the establishment of safety culture. According to the analysis of the causes of the human error, the frequency of skill-based mistakes leading to accidents were significantly lower than that of rule-based and knowledge based mistakes. However, there was limitation in the analysis of the root causes due to limited information in the accident investigation report. To solve this, it is suggested to adopt advanced accident investigation system including the establishment of independent organization and improvement in regulation.

• Industrial Engineering and Management Systems
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• 제11권2호
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• pp.148-154
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• 2012

Micro Electric Vehicles are considered as a solution for reducing $CO_2$ emissions, however, it is difficult to evaluate its impact in a local community when it has been introduced. In this study, we evaluated how to spread the Micro EV within the community, using the utility derived from a multinomial logit model, and analyze the effect on $CO_2$ emissions. The householder's utility model is based on an investigation about Kiryu citizen's activities of shopping, transportation methods, etc. Using the geographic information system, we get the distances of each householder and the stores, and estimate a multinomial logit model about the combination choices of shopping stores and transportation method.

• 한국유기농업학회지
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• 제12권1호
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• pp.1-21
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• 2004

If it does not underestimata the livestock feces, it is analyzed that thc potential energy of consumption is sufficient. If consequently economic value evaluation of the livestock feces, environmentally use, the use of opportune and proper quantity, the logistics system development which connected the transportation and scattering, environmentally plan of public control facilities for livestock feces as a precondition of livestock feces consuming is been sufficient, the livestock feces problem of both farmhouse and the area which occurs excessively will be solve more economically and will be the possibility resources more efficiently as chemical fertilizer transfer.

• Transactions on Electrical and Electronic Materials
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• 제16권4호
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• pp.198-200
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• 2015

The microwave plasma enhanced chemical vapor deposition (PECVD) system was used to grow a carbon nanowall (CNW) on a silicon (Si) substrate with hydrogen (H₂) and methane (CH₄) gases. To find the growth mechanism of CNW, we increased the growth time of CNW from 5 to 30 min. The vertical and surficial conditions of the grown CNWs according to growth time were characterized by field emission scanning electron microscopy (FE-SEM). Energy dispersive spectroscopy (EDS) measurements showed that the CNWs consisted solely of carbon.

• 한국환경과학회지
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• 제6권5호
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• pp.461-472
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• 1997

This study was carried out to investigate the characteristics of chemical components and precipitation at Kimhae area from March, 1992 to June, 1994. The pH values, concentration of soluble ions($Cl^-$, $NO_2^-}$ $NO_3^-}$, $NO_4^{2-}$-, $PO_4^{3-}$. $F^-$, $Mg^{2+}$, $Ca^{2+}$, $Mn^{2+}$, $K^+) and non-soluble metals(Cr.Si. Zn, Pb, Cu, Fe, Mn, Mg, Ad. V. Cal were measured by pH meter, IC (ion Chromatography) and ICP(Inductively Coupled Plasma). The data were analyzed by the dally. hourly distribution characteristics of acidity and chemical components, as well as the correlation between them. The results are as follows. 1. The pH range of precipitation was from 3.45 to 6.80 in Kimhae area. and average value was pH 4.62 and main chemical components were $SO_4^{2-}$, $Cl^-$, $NO_3^-$. The highest pH value and concentration appeared in initial rain, which might result from urbanlzation and industrialization in this area and long term transportation from China. 2. The hourly correction distribution of main anions related to pH value In the rainwater showed $SO_4^{2-}$ > $NO_3^-$ > $Cl^-$. Hourly concentration of heavy metal and each ion was highly correlated with pH in the precipitation.