• Title/Summary/Keyword: chemical stress

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KR-32158 protects heart-derived H9c2 cells from oxidative stress-induced cell death

  • Kim, Mi-Jeong;Jung, Yi-Sook;Kim, Sun-Ok;Lee, Dong-Ha;Lim, Hong;Yi, Kyu-Yang;Yoo, Sung-Eun;Lee, Soo-Hwan;Baik, Eun-Joo
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.131-131
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    • 2003
  • A benzopyranyl derivative, KR32158, synthesized as a plausible KATP opener, has been shown to exert cardioprotective effect in vivo myocardial infarction model. Myocardial ischemia, induced by oxidative stress, mental stress and fever, result in artheroscleosis, myocardial infarction and hypertrophy. In this study, we investigated in vitro effect of KR32158 by determining whether KR32158 produce cardioprotective effect against oxidative stress-induced death in heart-derived H9c2 cells. (omitted)

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Static measurement of yield stress using a cylindrical penetrometer

  • Uhlherr, P.H.T.;Guo, J.;Fang, T.N.;Tiu, C.
    • Korea-Australia Rheology Journal
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    • v.14 no.1
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    • pp.17-23
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    • 2002
  • A novel and simple method using a cylindrical penetrometer is being developed for the measurement of yield stress. The principle of this technique is based on the measurement of the static equilibrium of a falling penetrometer in a yield stress fluid. The yield stress is simply determined by a balance of forces acting on the penetrometer. The yield stress of Carbopol gels and $TiO_2$ suspensions has been measured using this method. The results are in reasonable agreement with the values from conventional methods. The effects of the dimensions and weight of the penetrometer have been examined. The long-term behaviour was also observed. No measurable creep was seen and equilibrium was found to be very quickly established. The cylindrical penetrometer technique promises to be a simple, quick and reliable static method for the measurement of yield stress.

Influence of Drought Stress on Chemical Composition of Sesame Seed

  • Kim, Kwan-Su;Ryu, Su-Noh;Chung, Hae-Gon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.1
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    • pp.73-80
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    • 2006
  • Sesame (Sesamum indicum L.) seeds contain abundant oil and antioxidative lignans related to the seed quality. To evaluate the potential effects of drought stress on the chemical composition of sesame seeds, eighteen cultivars were imposed water-deficit condition by withholding irrigation during 15 days at podding and maturing stage, compared with well-watered plants as control in seed yield and chemical composition. Drought treatments showed great decrease of seed yield with not affecting seed weight. The contents of sesamin and sesamolin decreased while lignan glycosides inversely increased in response to drought stress. Oil content was not significantly changed by drought treatment in spite of its slight decrease. In case of fatty acid composition, there were significant differences in increase of oleic acid while inverse decrease of linoleic acid under drought stress condition. These results demonstrate that the chemical composition of sesame seed may be modified with drought stress. In particular, the increase of sesaminol glucosides with strong antioxidative activity was observed.

Yield stress measurements in suspensions: an inter-laboratory study

  • Nguyen, Q. Dzuy;Akroyd, Timothy;Kee, Daniel C. De;Zhu, Lixuan
    • Korea-Australia Rheology Journal
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    • v.18 no.1
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    • pp.15-24
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    • 2006
  • The first international inter-laboratory study, involving six laboratories, has been conducted to examine issues associated with yield stress measurements in suspensions. The initial focus of the project was to evaluate the reliability and reproducibility of several common yield stress measuring techniques employed in different laboratories and with different instruments. Aqueous suspensions of colloidal $TiO_2$ at concentrations of 40-70 wt% solids were used as the test fluids. A wide range of instruments and techniques employing both direct and indirect methods were used to determine the yield stress of the samples prepared according to a prescribed procedure. The results obtained indicated that although variations of results existed among different techniques, direct yield stress measurements using static methods produced more reliable and repeatable results than other methods. Variability of the yield stress measured using different techniques within any laboratory however was less significant than variability of the results among different laboratories. The nature and condition of the test suspensions was identified as the most likely factor responsible for the poor reproducibility of yield stress measurements from different laboratories.

Stress jump: experimental work and theoretical modeling

  • Ning Sun;Kee, Daniel-De
    • Korea-Australia Rheology Journal
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    • v.13 no.3
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    • pp.109-123
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    • 2001
  • A stress jump, defined as the instantaneous gain or loss of stress on startup or cessation of a deformation, has been predicted by various models and has relatively recently been experimentally observed. In 1993, Liang and Mackay measured shear stress jump data of xanthan gum solutions, and in 1996, Orr and Sridhar reported extensional stress jump data of Boger fluids. Shear stress jumps of suspensions and liquid crystal polymers have also been observed. In this contribution, experimental work as well as a variety of theoretical models, which are able to predict a stress jump, are reviewed.

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Yielding behaviour of organically treated anatase $TiO_2$ suspension

  • Guo, J.;Tiu, C.;Uhlherr, P.H.T.;Fang, T.N.
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.9-17
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    • 2003
  • The rheological behaviour of anatase $TiO_2$ with organic coating has been investigated extensively in this study. The yield stress was measured over a wide range of solids concentration and pH using stress-controlled and speed-controlled rheometers. The organic treatment leads to a shift of the isoelectric point (IEP) from around pH 5.5 to pH 2.4. A maximum yield stress occurs in the vicinity of the isoelectric point determined by electrokinetic measurements. The transition of rheological behaviour between elastic solid and viscous liquid is represented by a stress plateau in a plot of stress against strain. It is hypothesised that the slope of the stress plateau reflects the uniformity of the structure, and hence the distribution of bond strength. Altering the concentration and the surface chemistry can vary the bond strength and its distribution. therefore, resulting in different type of failure: "ductile-type" or "brittle-type". pH and volume fraction dependence of yield stress could be described quantitatively using existing models with reasonable agreement.easonable agreement.

Investigation into a Chemical Cracking and the Measurement of Stress in a Polycarbonate Specimen through Deformation Jig (변형지그를 이용한 폴리카보네이트 시편의 케미컬 크랙킹 및 응력측정에 관한 연구)

  • Yoo, Seo Jeong;Hong, Hyoung Sik;Lyu, Min-Young
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.645-649
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    • 2014
  • The causes of residual stress in an injection molded part are high temperature variation and shear stress during molding process. Chemical cracking test is one of the methods of measuring residual stress and cracks are developed according to the degree of residual stress. In this study, the relationship between chemical cracking and exerted stress have been investigated. Deformation jig was designed and used to give a stress through deformation in a specimen. Specimens were molded by a hot press using polycarbonate (PC) and annealed to remove residual stresses in the specimens. Specimens were fixed in the deformation jig and immersed into the solvent to create cracks in the specimens. Solvents were prepared by using tetrahydrofuran and methyl alcohol. As stress accordance with the deformation in the specimen increased, the frequency and density of cracks in the specimen also increased. The results of this study can be used for the measurement of residual stress quantitatively in an injection molded PC product using a chemical cracking method.

Stress-Strain Relationship of Alkali-Activated Hwangtoh Concrete under Chemical Attack (화학적 침해를 받은 알칼리활성 황토콘크리트의 응력-변형률 관계)

  • Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.2
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    • pp.170-176
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    • 2014
  • This study examined the effect of chemical attack on the stress-strain relationship of alkali-activated Hwangtoh concrete. Water-to-binder ratio and air content were selected as mixture parameters. The stress-strain relationship of concrete was measured at chemical immersion times of 0, 7, 28, 56, and 91 days from an age of 28 days. Based on the test results, the reduction in compressive strength of alkali-activated hwangtoh concrete owing to chemical attack was formulated. In sddition the present study demonstrated that the stress-strain behavior of concrete under chemical attack is significantly dependent on the air content and chemical immersion time, indicating the rate of decrease of modulus of elasticity was greater than that of compressive strength at the same immersion time. As a result, the stress-strain behavior of concrete under chemical attack was significantly inconsistent with the conventional models specified in the CEB-FIP provision.

Finite Element Analysis of Residual Stress Evolution during Cure Process of Silicone Resin for High-power LED Encapsulant (고출력 LED 인캡슐런트용 실리콘 레진의 경화공정중 잔류응력 발달에 대한 유한요소해석)

  • Song, Min-Jae;Kim, Heung-Kyu;Kang, Jeong-Jin;Kim, Kwon-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.2
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    • pp.219-225
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    • 2011
  • Silicone resin is recently used as encapsulant for high-power LED module due to its excellent thermal and optical properties. In the present investigation, finite element analysis of cure process was attempted to examine residual stress evolution behavior during silicone resin cure process which is composed of chemical curing and post-cooling. To model chemical curing of silicone, a cure kinetics equation was evaluated based on the measurement by differential scanning calorimeter. The evolutions of elastic modulus and chemical shrinkage during cure process were assumed as a function of the degree of cure to examine their effect on residual stress evolution. Finite element predictions showed how residual stress in cured silicone resin can be affected by elastic modulus and chemical shrinkage behavior. Finite element analysis is supposed to be utilized to select appropriate silicone resin or to design optimum cure process which brings about a minimum residual stress in encapsulant silicone resin.

Effect of Stress on Current-Voltage Characteristics of ZnO Based Ceramics

  • Jung Ju-Yong;Kim Yeong-Cheol;Seo Hwa-Il;Chung Dong-Teak;Kim Young-Jung;Min Joon-Won
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.4 s.13
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    • pp.1-4
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    • 2005
  • The chemical composition and uniaxial compressive stress are varied to observe their effect on the current-voltage characteristics of ZnO based ceramics. The variation of chemical composition produces two kinds of ceramics showing ohmic and nonohmic current-voltage characteristics. The current at a fixed voltage increased with the increase of the compressive stress for both ohmic and nonohmic ceramics. Ceramics showing nonohmic behavior exhibit better reversible return of current-voltage curve when the applied compressive stress is removed from the ceramics than those showing ohmic behavior do. We found an appropriate chemical composition showing linear relation between current and stress at a fixed voltage. The ceramic materials with an appropriate chemical composition can be used as a potential sensing material in pressure sensors.

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