• Title/Summary/Keyword: chemical states

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Current status on global sweetpotato cultivation and its prior tasks of mass production (세계 고구마 재배현황 및 대량생산의 선결과제)

  • Kim, Ho Soo;Lee, Chan-Ju;Kim, So-Eun;Ji, Chang Yoon;Kim, Sung-Tai;Kim, Jin-Seog;Kim, Sangyong;Kwak, Sang-Soo
    • Journal of Plant Biotechnology
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    • v.45 no.3
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    • pp.190-195
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    • 2018
  • Sweetpotato [Ipomoea batatas (L.) Lam] represents an attractive starch crop that can be used to facilitate solving global food and environmental problems in the $21^{st}$ century. It can be used as industrial bioreactors to produce various high value-added materials, including bio-ethanol, functional feed, antioxidants, as well as food resources. The non-profit Center for Science in the Public Interest (CSPI) announced sweetpotato as one of the ten 'super foods' for better health, since it contains high levels of low molecular weight antioxidants such as vitamin-C, vitamin-E and carotenoids, as well as dietary fiber and potassium. The United States Department of Agriculture (USDA) also reported that sweetpotato is the best bioenergy crop among starch crops on marginal lands, that does not affect food security. The Food and Agriculture Organization (FAO) estimated that world population in 2050 will be 9.7 billion, and require approximately 1.7 times more food than today. In this respect, sweetpotato will be a solution to solving problems such as food, energy, health, and environment facing the globe in the $21^{st}$ century. In this paper, the current status of resources, and cultivation of sweetpotato in the world was first described. Development of a new northern route of the sweetpotato and its prior tasks of large scale cultivation of sweetpotato, were also described in terms of global food security, and production of high-value added biomaterials.

Partial Oxidation of Methane to Syngas over M(10)-Ni(5)/SBA-15(M=Ce, Nd, Sm) Catalysts (M(10)-Ni(5)/SBA-15(M=Ce, Nd, Sm) 촉매상에서 합성가스 제조를 위한 메탄의 부분산화반응)

  • Seo, Ho Joon;Kim, Yong Sung
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.720-725
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    • 2017
  • M(10)-Ni(5)/SBA-15(M=Ce, Nd, Sm) catalysts were prepared for the partial oxidation of methane (POM) to syngas. The catalysts were characterized by BET, TEM, and XPS. The BET-specific surface area and average pore size for M(10)-Ni(5)/SBA-15(M=Ce, Nd, Sm) were 538.8, 504.3, and $447.3m^2/g$ and 6.4, 6.8, and 7.1 nm, respectively. TEM results showed that the mesoporous hexagonol structure was formed for SBA-15, while the homogeneous dispersion of Ni and Ce particles on the surface was formed for Ce(10)-Ni(5)/SBA-15 caused by the confinment effect of SBA-15. XPS data confirmed that $Ce^{4+}$ and $Ce^{3+}$ on the surface catalyst have two oxidation states due to the lattice oxygen species ($O^{2-}$, $O^-$). The yields of POM to syngas over Ce(10)-Ni(5)/SBA-15 were 52.9% $H_2$ and 21.7% CO at 1 atm, 973 K, $CH_4/O_2=2$, $GHSV=1.08{\times}10^5mL/g_{cat.}{\cdot}h$, and these values were kept constant even after 75 h on streams. The same tendency of syngas yields was observed for M(10)-Ni(5)/SBA-15(M=Ce, Nd, Sm). These results confirm that the redox reaction of promoters including Ce, Nd, and Sm enhanced the stability and yield of catalysts.

Calculation of the Correction Factors related to the Diameter and Density of the Concrete Core Samples using a Monte Carlo Simulation (몬테카를로 전산해석을 이용한 콘크리트 코어시료의 직경과 밀도에 따른 보정인자 계산)

  • Lee, Kyu-Young;Kang, Bo Sun
    • Journal of the Korean Society of Radiology
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    • v.14 no.5
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    • pp.503-510
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    • 2020
  • Concrete is one of the most widely used materials as the shielding structures of a nuclear facilities. It is also the most generated radioactive waste in quantity while dismantling facilities. Since the concrete captures neutrons and generates various radionuclides, radiation measurement and analysis of the sample was fulfilled prior to dismantle facilities. An HPGe detector is used in general for the radiation measurement, and effective correction factors such as geometrical correction factor, self-absorption correction, and absolute detector efficiency have to be applied to the measured data to decide exact radioactivity of the sample. Correction factors are obtained by measuring data using a standard source with the same geometry and chemical states as the sample under the same measurement conditions. However, it is very difficult to prepare standard concrete sources because concrete is limited in pretreatment due to various constituent materials and high density. In addition, the concrete sample obtained by core drill is a volumetric source, which requires geometric correction for sample diameter and self absorption correction for sample density. Therefore in recent years, many researchers are working on the calculation of effective correction factors using Monte carlo simulation instead of measuring them using a standard source. In this study we calculated, using Geant4, one of the Monte carlo codes, the correction factors for the various diameter and density of the concrete core sample at the gamma ray energy emitted from the nuclides 152Eu and 60Co, which are the most generated in radioactive concrete.

Microstructure and Electrical Properties of the Pt/Pb1.1Zr0.53Ti0.47O3/PbO/Si (MFIS) Using the PbO Buffer Layer (PbO 완충층을 이용한 Pt/Pb1.1Zr0.53Ti0.47O3/PbO/Si (MFIS)의 미세구조와 전기적 특성)

  • Park, Chul-Ho;Song, Kyoung-Hwan;Son, Young-Guk
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.104-109
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    • 2005
  • To study the role of PbO as the buffer layer, Pt/PZT/PbO/Si with the MFIS structure was deposited on the p-type (100) Si substrate by the r.f. magnetron sputtering with $Pb_{1.1}Zr_{0.53}Ti_{0.47}O_3$ and PbO targets. When PbO buffer layer was inserted between the PZT thin film and the Si substrate, the crystallization of the PZT thin films was considerably improved and the processing temperature was lowered. From the result of an X-ray Photoelectron Spectroscopy (XPS) depth profile result, we could confirm that the substrate temperature for the layer of PbO affects the chemical states of the interface between the PbO buffer layer and the Si substrate, which results in the inter-diffusion of Pb. The MFIS with the PbO buffer layer show the improved electric properties including the high memory window and low leakage current density. In particular, the maximum value of the memory window is 2.0V under the applied voltage of 9V for the Pt/PZT(200 nm, $400^{\circ}C)/PbO(80 nm)/Si$ structures with the PbO buffer layer deposited at the substrate temperature of $300^{\circ}C$.

SiO2 Behavior of MoSi2 Powders Containing SiO2 Synthesized by SHS Method (자전연소합성법으로 제조된 SiO2 첨가된 MoSi2 분말 내에서의 SiO2의 거동 연구)

  • Rha, Sa-Kyun;Jeon, Min-Seok;Song, Jun-Kwang;Han, Dong-Bin;Jeong, Cheol-Weon;Kim, Sung-Soo;Lee, Youn-Seoung
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.559-564
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    • 2011
  • In order to investigate the behavior of $SiO_2$ in the molybdenum silicide powders, crystal structure of these powders was measured by XRD, in addition, surface composition and surface phase (or chemical states) and microstructure were analysed by XPS and TEM, respectively. Mo-silicide powders containing $SiO_2$ were synthesized by SHS (Self-Propagating High-Temperature Synthesis) technique. In XRD result, according to increase of $SiO_2$ contents, the crystal structure for synthesized $MoSi_2$ powders was still typical $MoSi_2$ bct without any other phases. By XPS analysis, the surface of Mo and Si source powders was covered with $MoO_3$ and $SiO_2$, respectively, and the surface of synthesized $MoSi_2$ powder was also covered with $MoO_3$ and $SiO_2$, which were stable oxides at room temperature. However, according to increase of $SiO_2$ addition, $MoSi_2$ phase in XPS spectra decreased and $SiO_2$ phase increased relatively in synthesized $MoSi_2$ powders. From the results by XPS and XRD, we found that the existent $SiO_2$ has amorphous structure. In the microstructure, the small particulates of the synthesized products added $SiO_2$ agglomerated together to form larger clusters (from ~10 nm to ~1 ${\mu}m$). From TEM, XPS, and XRD results, we found that the out layer of agglomeration of synthesized $MoSi_2$ powder is surrounded by amorphous $SiO_2$.

Issues of Natech Risk Management (Natech위험의 개념 및 주요 쟁점)

  • Oh, Yoon-Kyung
    • Journal of Environmental Policy
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    • v.13 no.4
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    • pp.79-105
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    • 2014
  • Natech risk is a type of complex disasters that natural hazards trigger technological disaster or industrial accidents. Research on Natech risk has been started from the mid-1990s in European countries and the Unites States, and drawn much more attention after the Fukushima nuclear accident caused by the 2011 East Japan earthquake. While early studies on Natech risk have focused on the causal natural hazards and possibility to occur, and the resulting spill of hazardous materials from the perspective of science and engineering, the recent research interests lie on effective Natech risk management. Especially, emphasizing the difference of Natech risk management from traditional disaster management, issues of uncertainty management, integration between natural disaster and technological disaster, and responsibility, has been drawn attention. In Korea, Natech risk has not been introduced as a research topic. Although some regulatory improvements have been made in nuclear safety and chemical Substance management after the Fukushima disaster, the potential impact of natural hazards in these areas has not been considered yet. It is necessary to raise the issues of Natech risk management in research and policy areas through active discussion and interdisciplinary approaches.

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AN EXPERIMENTAL STUDY OF THE EFFECTS OF ION BEAM HIKING ON CERAMO-METAL BONDING (이온선 혼합법이 도재와 금속의 결합에 미치는 영향에 관한 실험적 연구)

  • Hong, Joon-Pow;Woo, Yi-Hyung;Choi, Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.29 no.2
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    • pp.245-265
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    • 1991
  • The purpose of this study was to observe the changes of the elemental transmission and bond strength between the metal and porcelain according to various kinds of ion beam mixing method. ion beam mixing of $meta1/SiO_2$ (silica), $meta1/Al_2O_3$(alumina) interfaces causes reactions when the $Ar^+$ was implanted into bilayer thin films using a 100KeV accelerator which was designed and constructed for this study. A vacuum evaporator used in the $10^{-5}-10^{-6}$ Torr vacuum states for the evaporation. For this study, three kinds of porcelain metal selected, -precious, semiprecious, and non-precious. Silica and alumina were deposited to the metal by the vacuum evaporator, separately. One group was treated by two kinds of dose of the ion beam mixing $(1\times10^{16}ions/cm^2,\;5\times10^{15}ions/cm^2)$, and the other group was not mixed, and analyzed the effects of ion beam mixing. The analyses of bond strength, elemental transmissions were performed by the electron spectroscopy of chemical analysis (ESCA), light and scanning electron microscope, scratch test, and micro Vickers hardness tests. The finding led to the following conclusions. 1. In the scanning electron and light microscopic views, ion beam mixed specimens showed the ion beam mixed indentation. 2. In the micro Vickers hardness and scratch tests, ion beam mixed specimens showed higher strength than that of non mixed specimens, however, nonprecious metal showed a little change in the bond strength between mixed and non mixed specimens. 3. In the scratch test, ion beam mixed specimens showed higher shear strength than that of non treated specimens at the precious and semiprecious groups. 4. In the ESCA analysis, Au-O and Au-Si compounds were formed and transmission of the Au peak was found ion beam mixed $SiO_2/Au$ specimen, simultaneously, in the higher and lower bonded areas, and ion beam mixed $SiO_2/Ni-Cr$ specimen, oxygen, that was transmitted from $SiO_2\;to\;SiO_2/Ni-Cr$ interface combined with 12% of Ni at the interface.

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BIOASSAY STUDY OF EARLY DEVELOPMENT OF MACTRA CHINENSIS PHILIPPI FOR THE WATER QUALITY EVALUATION OF THE COASTAL WATERS OF BUSAN (개량조개, Mactra chinensis Philippi 발생에 의한 부산연안 해수의 수질오탁 조사)

  • LEE Taek Yuil;SON Young Won
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.2
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    • pp.115-121
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    • 1978
  • Early developmental stages of Mactra chinensis were bioassayied to determin the water quality of the costal waters of Busan. The water samples were obtained at 12 stations from July 12 to July 17, 1977. Water quality evaluation was made in terms of the rates of normal development to abnormal development in three indicatory states, i. e. fertilization membrane formation, morula and trochophore larvae. The pollution degree of the waters brought from five swimming beaches was found to be highest at Haewundae followed by Songdo, Kwang-anri, Songjeong and Dadaepo with decreasing order. The highest value of the water at Haewundae was mainly due to the accidental oil spill from an oil tanker which happened on July 7, 1977. At Dongsamdong the rate of total abnormal development was $47.17\%$. This result is apparently attributable to fish byproducts discarded from a number of restaurants. At Chungmudong where a large fish-market is located, the rate of total abnormal development was $61.14\%$. At Suyeng Bay and Yongho Bay the rates of total abnormal development were $73.82\%$ and $72.90\%$ respectively. At these bays the drainage presumably contains a large amount of chemical pollutants from the industrial areas. This result shows that no organisms can normally breed in these regions.

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Geochemical Characteristics of Intertidal Surface Sediments along the Southwestern Coast of Korea (한국 서해남부 조간대 표층 퇴적물의 지화학적 특성)

  • Hwang, Dong-Woon;Ryu, Sang-Ok;Kim, Seong-Gil;Choi, Ok-In;Kim, Seong-Soo;Koh, Byoung-Seol
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.43 no.2
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    • pp.146-158
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    • 2010
  • In order to evaluate the characteristics of sediments and pollution by organic matter and metallic elements in intertidal sediments along the southwestern coast of Korea, we measured various geochemical parameters, including the mean grain size (Mz), water content (WC), ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and metallic elements (Al, Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, As), in intertidal surface sediments. The Mz of the surface sediments ranged from 2.1 to 8.3$\phi$, indicating that the surface sediments consist of various sedimentary facies, such as sand, slightly gravelly mud, sandy mud, and silt. The IL and COD in surface sediment ranged from 0.8 to 5.5% (mean $2.9\pm1.2%$) and from 3.9 to $13.8\;mgO_2/g{\cdot}dry$ (mean $8.5\pm2.6\;mgO_2/g{\cdot}dry$), respectively, which were lower than the values for surface sediment in areas near fish and shellfish farms or industrial complexes. No AVS was detected at any sampling station, despite various sedimentary facies. Most of metallic elements in surface sediments showed relatively good positive correlations with Mz and IL, which imply that the concentrations of metallic elements are mainly controlled by grain size and the organic matter content. The concentrations of metallic elements, except As, at some stations were considerably lower than those in the Sediment Quality Guideline (Effect Range Low, ERL) proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Similarly, the geoaccumulation index (Igeo) class indicated that pollution by metallic elements in intertidal surface sediment, except As, was moderate or non-existent. Our results imply that the intertidal surface sediments along the southwestern coast of Korea are not polluted by organic matter and metallic elements and are healthy for benthic organisms.

COMPARISON OF SHEAR BOND STRENGTH AND MARGINAL LEAKAGE OF RESIN MODIFIED GLASS IONOMER CEMENTS (강화형 글라스 아이오노머 합착용 시멘트의 접합강도 및 변연누출에 대한 연구)

  • Park, Hye-Yang;Oh, Nam-Sik;Lee, Keun-Woo;Lee, Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.4
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    • pp.647-661
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    • 1997
  • The resin modified glass ionomer cements(RMGICs) have been used for years since 1989. Recently it has been developed for luting of fixed restorations. To evaluate the bond strength and marginal leakage of RMGICs for luting usage, the 80 extracted human molars which had uniform area of exposed dentin were cemented with 3 types of RMGICs(Fuji Duet, Advance, Vitremer), a conventional Glass Ionomer Cement(GIC-Fuji I), and a resin cement (Panavia 21) to base metal alloy(Ni-Cr-Be). After thermocycling the specimens were immersed in basic fuschin dye for measuring marginal leakage. The shear bond strength was measured with Instron and the maximum dye penetration was measured to 0.1mm. The types of fractured patterns were determined with stereoscope(${\times}7.5$). The results are as follows. 1. The difference between 3 RMGICs and a conventional GIC in shear bond strength was not statistically significant. It seemed that RMGICs had lower shear bond strength than resin cement. (p<0.01) 2. The mean scores of marginal leakage had no significant difference between the resin cement and 3 RMGICs but it was much higher in conventional GIC than the RMGICs (p<0.05) 3. It was determined that the manufacturer and the methods of dentin pretreatment determined the pattern of fracture surfaces and the frequency of adhesive failure between teeth and 3 RMGICs standed as in following order - Vitremer, Advance, Fuji Duet. (p<0. 01) When the fracture pattern was analyzed, it could be said that the materials and the method of dentin pretreatment have much effect on bonding states. This means that the dentin bonding agents should be improved. But the limited products in this experiment can not evaluate the physical properties of the entire RMGICs. Therefore a further study which can evaluate various RMGICs should be in progress to develope better cements.

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