• Title/Summary/Keyword: chemical recycling

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A Study on the Recycling of Radioactively Contaminated Metal Waste (방사성오염 금속폐기물의 재활용 연구)

  • 문제권;박상윤;정종헌;이정원;오원진
    • Resources Recycling
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    • v.6 no.3
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    • pp.22-27
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    • 1997
  • Recycling of radioactively contaminated metal wasles is very attractive to reduce thc final disposal volumc of the radioactive wastes, thereby maximizing the usage of nahrral rzsuunts and minimizmg the detrimental effects of thz rzdioaclive wastes on the environment. In the recycling process, many complicated processes arc involved. Among those processes the 'surface contamination removal techniques such as physical, chemical and electrochern~calm ethods are the most critical and Ircquently applied in accordance with the contamination characteristics and the chemical compositions of the metal wastes. In this sludy, the sulfuric acid-cerium method and electmchemical methods were applied lu removc the conatiminated suhce. The results showed the surface contaminalion could he lowered to the background levcl by lhasc mclhods.

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Current Status of Smelting and Recycling Technologies of Tungsten (텅스텐의 제련과 리사이클링 현황)

  • Sohn, Ho-Sang
    • Journal of Powder Materials
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    • v.28 no.4
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    • pp.342-351
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    • 2021
  • Because of its unique properties, tungsten is a strategic and rare metal used in various industrial applications. However, the world's annual production of tungsten is only 84000 t. Ammonium paratungstate (APT), which is used as the main intermediate in industrial tungsten production, is usually obtained from tungsten concentrates of wolframite and scheelite by hydrometallurgical treatment. Intermediates such as tungsten trioxide, tungsten blue oxide, tungstic acid, and ammonium metatungstate can be derived from APT by thermal decomposition or chemical attack. Tungsten metal powder is produced through the hydrogen reduction of high-purity tungsten oxides, and tungsten carbide powder is produced by the reaction of tungsten powder and carbon black powder at 1300-1700℃ in a hydrogen atmosphere. Tungsten scrap can be divided into hard and soft scrap based on shape (bulk or powder). It can also be divided into new scrap generated during the production of tungsten-bearing goods and old scrap collected at the end of life. Recycling technologies for tungsten can be divided into four main groups: direct, chemical, and semi-direct recycling, and melting metallurgy. In this review, the current status of tungsten smelting and recycling technologies is discussed.

Trend on the Recycling Technologies for Used Fat and Vegetable Oil as Monomers by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 동식물폐유지(動植物廢油脂) 모노머화 재활용(再活用) 기술(技術) 동향(動向))

  • Kim, Young-Wun;Yoon, Byung-Tae;Cho, Bong-Gyoo;Cho, Young-Ju
    • Resources Recycling
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    • v.22 no.1
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    • pp.72-79
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    • 2013
  • There is increasing interest to the development of environmental friendly products related global environment and health issue and it is very important technology for recycling contained hazardous substance that occur due to oxidation during used oils and fats of vegetable and animal to eco-friendly products. In this study, papers and patents for recycling technologies of used fat and vegetable oil as monomers were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1976 to 2012. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals were analyzed by the years, countries, companies, and technologies. Such pretreatment purification, polymerization for monomer, and polymer manufacturing technology were ahead of the United States.

Review of Recycling of the Plastic Waste (폐플라스틱의 처리·재자원화 최신동향)

  • Shin, Hee-Duck;Kim, Jong Heon
    • Resources Recycling
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    • v.23 no.4
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    • pp.3-11
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    • 2014
  • Large scale generation of plastic waste has generated considerable interest it seeking innovative solutions to waste recycling and reuse. Plastic solid waste(PSW) treatment and recycling processes could be allocated to four major categories, re-extrusion(primary), mechanical recycling(secondary), chemical recycling(tertiary) and energy recovery(quaternary). This review considers the various aspects of the PSW recycling such as recycling methods of PSW, special problems about some proposed process, separation techniques, and recycling of mixed PSW.

A Novel Method for Calcium Hardness Control of Closed OCC Recycling System

  • Ow, Say-Kyoun;Shin, Jong-Ho;Song, Bong-Keun;Ryu, Jeong-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.164-171
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    • 1999
  • A new technique for recycling process water was developed in order to reduce the calcium hardness of the closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by a reaction with sodium carbonate and the CaCO$_3$precipitates were easily removed from the system by a dissolved air flotation(DAF) method. After the DAF stage, CO$_2$-gas was purged into the water because the pH of Na$_2$CO$_3$-treated white water was reduced to neutral by CO$_2$gas. Since CaCO$_3$precipitate tends to stick onto the fine fiber surface and then is selectively removed from the water, a proper amount of suspended solid in the process water acts as an important factor in deciding the removal efficiency. By the application of Na$_2$CO$_3$addition - DAF - CO$_2$purging to the short circulated white water the calcium hardness was significantly reduced by 92% and more. The removal of calcium ions with fine fibers led to drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

Separation of Non-Metallic Components in Waste Printed Circuit Boards (WPCBs) using Organic Solvent and Potassium Phosphate Solution (유기용매와 인산칼륨 용액을 이용한 폐 인쇄회로기판에서 비금속성분의 분리)

  • Lee, Jae-Cheon;Jeong, Jin Ki;Kim, Jong Seok
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.367-371
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    • 2012
  • Waste printed circuit boards (WPCBs) contain valuable metals such as Cu, Ni, Au, Ag, and Pd. For an effective recycling of WPCBs, it is essential to recover the valuable metals. In recent years, recycling processes have come to be necessary for separating noble metals from WPCBs due to an increasing amount of electronic device wastes. However, it is well known that glass reinforced epoxy resins in the WPCBs are difficult materials to separate into elemental components, namely metals, glass fibers and epoxy resins in the chemical recycling process. $K_3PO_4$ as a catalyst in dimethylformamide (DMF) and N-Methyl-2-pyrrolidone (NMP) was used to depolymerize epoxy resins for recovering metallic and non-metallic components from WPCBs. Reactions of WPCBs were carried out at temperatures $160{\sim}200^{\circ}C$ for 2~12 h. The recycled glass fiber from WPCBs was analyzed by thermogravimetric analyzer (TGA) and evaluated the degree of solubility of the epoxy resin for separation efficiencies of the WPCBs.

Foaming Process of Waste LCD Glass for the Recovery of Valuable Materials from Waste LCD Pannel (폐 LCD판넬의 유가성분 회수를 위한 폐 LCD유리의 발포공정)

  • Lee, Chul-Tae;Park, Tae-Moon;Kim, Jung-Min
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.195-203
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    • 2012
  • Recycling method of waste LCD glass is the essential process for developing the total recycling process of LCD pannel. Pulverizing of LCD glass, determination of proper carbonacious foaming agent, the properties of residue from the recovery of valuable materials through an acid leaching process and the feasibility for the foaming of the residue obtained from leaching for indium and tin recovery were investigated for the developing of recycling method of waste LCD glass as industrial feed materials, such as heat insulation materials, sound absorbing materials, carrier of water treatment. Waste LCD glass could be pulverized finely for foaming process. Natural graphite was proper agent for foaming of the residue and the foaming technology of LCD glass would be effective recycling alternatives.