• Journal of Industrial and Engineering Chemistry
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• 제67권
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• pp.448-460
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• 2018

Copper nanoparticle-doped and graphitic carbon nanofibers-covered porous carbon beads were used as an efficient catalyst for treating synthetic phenolic water by catalytic wet air oxidation (CWAO) in a packed bed reactor over 10-30 bar and $180-230^{\circ}C$, with air and water flowing co-currently. A mathematical model based on reaction kinetics assuming degradation in both heterogeneous and homogeneous phases was developed to predict reduction in chemical oxygen demand (COD) under a continuous operation with recycle. The catalyst and process also showed complete COD reduction (>99%) without leaching of Cu against a high COD (~120,000 mg/L) containing industrial wastewater.

• Korean Chemical Engineering Research
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• 제53권4호
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• pp.440-444
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• 2015

Effects of operating variables on the solid circulation rate were investigated in a three-phase circulating fluidized bed, of which inside diameter was 0.102m and height was 3.5m, respectively. Gas velocity, primary and secondary liquid velocities, particle size and height of solid particles piled up in the solid recycle device were chosen as operating variables. The solid circulation rate increased with increasing primary and secondary liquid velocities and height of solid particles piled up in the solid recycle device, but decreased with increasing particle size. The value of solid circulation rate decreased only slightly with increasing gas velocity in the riser. The values of solid circulation rate were well correlated in terms of dimensionless groups within the experimental conditions.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1988년도 한국자동제어학술회의논문집(국내학술편); 한국전력공사연수원, 서울; 21-22 Oct. 1988
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• pp.482-487
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• 1988

A sequential-clustered integrator based on GEAR method is developed for the purpose of dynamic simulation of chemical processes. And a single simulator structure capable of employing various integration approaches is designed and its efficiency and flexiblity is evaluated. Sequential integration method is superior to simultaneous method for the process without recycle, but simultaneous method is very powerful for the coupled process with recycle.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2001년도 추계 기술심포지움
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• pp.235-239
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• 2001

In recent years, as Chemical Mechanical Planarization(CMP) has been routinely utilized in integrated circuit(IC) fabrication, the consumption of slurry, main consumable in a CMP process, is greatly increased. Thus the reprocess of CMP slurries has been actively considered in the industry to reduce cost-of-consumable (COC). The main purpose of this study was to recycle the used oxide slurry using filters as a new method. As a result, Ultra Fine(UF) Filter could distinguish silica from the used oxide slurry and Reverse Osmosis(RO) Filter could distinguish Deionized(DI) Water and chemistry from chemistry solution. The tetraethylorthosilicate removal rate was almost the same as the number of recycle polishing was increased, when it was modified by slightly adding new SS-12 slurry. The microscratch didnt found as the number of recycle polishing was increased.

• 한국막학회:학술대회논문집
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• 한국막학회 1999년도 Energy Saving Membrane Separtion Systems 에너지 절약형 막분리 시스템
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• pp.39-39
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• 1999

Membrane separation technology has become a more attractive technology on waste water treatment and water recycle in recent years. On this application, membrane does not take main part of treatment, such as decomposition or handling of organic matter in the waste water, but it is very important supporting method in the total system. Activated sludge is most popular method as main part. In the system , membrane works as a separator to obtain clear water after biological treatment, by which the permeate could be released, recycled or applied to further additional treatment, instead of conventional sedimentation, coagulation and sand filtration. We would like to introduce our system cases for waste water treatment and water recycle, in which membrane separation technology works. In most of cases, membranes are applied to solid- liquid separation of activated sludge. Our experiences will be introduced as following items.

• Korean Chemical Engineering Research
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• 제48권2호
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• pp.198-204
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• 2010

가압순환유동층 적용을 위해 루프씰(loop-seal: 내경 0.10 m)을 갖는 고체재순환부(직경 0.10 m, 높이 2.25 m)에서 층 물질로 silica sand 입자($d_p=240{\mu}m$, ${\rho}_s=2582kg/m^3$)를 사용하여 시스템 압력 변화(0.10~0.71 MPa)에 따른 고체흐름 특성을 연구하였다. 루프씰을 통한 고체질량플럭스는 공기주입량이 증가할수록 선형적으로 증가하였고, 동일한 공기주입속도에 대해 시스템 압력이 증가할수록 증가하였다. downcomer 내 압력변이는 시스템 압력이 증가할수록 동일한 공기주입속도에 대해 증가하였고, 흐름 내 고체속도 및 기체 속도 또한 증가하였다. 고체질량플럭스로부터 downcomer 에서의 압력변이를 예측할 수 있는 상관관계식을 Transportation number와 Pressure drop number를 이용하여 제안하였다. 루프씰에서의 압력강하는 시스템 압력에 관계없이 고체질량플럭스가 증가할수록 증가하였다. 각각의 시스템 압력에서 공기주입속도 변화에 따른 고체질량플럭스 및 Transportation number를 예측할 수 있는 상관관계식을 제안하였다.

• 한국미생물·생명공학회지
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• 제13권1호
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• pp.33-39
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• 1985

The effects of initial concentration, flow rate, and recycle ratio on the removal efficiency of phenol were studied in a tapered fluidized bed reactor packed with activated carbon which was attached with Candida tropicalis. The optimum conditions of Candida tropicalis were showed that pH was 7.0 and temperature was $30^{\circ}C$, and the specific growth rate of Candida tropicalis was satisfied with the Monod equation up to 500 mg/L of phenol, and beyond it the inhibition of substrate was found. According to the increases of initial concentration and flow rate, the removal efficiency was decreased, as the recycle ratio was increased, the removal efficiency was increased. In the case of flow rate of 10mL/sec and the recycle ratio of 2, the removal efficiency was 90% above for the all of initial concentration. The removal rate of phenol was the first order reaction in this system, and the rate equation of reaction was as follows.

• 플랜트 저널
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• 제13권3호
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• pp.26-29
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• 2017

본 연구에서는 메탄올-아세톤 압력 변환 증류 공정에서 유입 흐름의 조성 최적화를 진행하였다. 압력 변환 증류 공정에서 유입 흐름의 조성은 혼합물 분리가능성에 지대한 영향을 주는 것이 잘 알려져 있다. 분리된 순수한 물질의 환류흐름을 이용하여 유입 흐름의 조성을 조절하여 정해진 압력에서 보다 나은 분리효율을 보이는 것을 이번 연구의 목적으로 한다. 환류 흐름이 없는 압력 변환 증류 공정을 기본 공정으로 하여, 메탄올의 환류 흐름이 있는 경우와 아세톤의 환류 흐름이 있는 경우 두 가지 공정이 설계되었다. 각 공정은 Total annual cost로 비교되었으며, 그 결과 환류 흐름이 없는 기본 공정이 가장 유리한 것으로 나타났다.

• Membrane and Water Treatment
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• 제2권2호
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• pp.75-89
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• 2011

The predicting equations for mass transfer rate in cross-flow rectangular dialyzers with double flow and recycle, have been derived by mass balances. The recycling operation has two conflicting effects. One is the desirable effect of the increase in fluid velocity, resulting in an increased mass transfer coefficient. The other is the undesirable effect of the reduction in concentration difference due to remixing, resulting in decreased mass-transfer driving force. In contrast a single-pass device without recycling, considerable improvement in mass transfer is achieved if the cross-flow rectangular dialyzer of same size is operated with double pass and external recycling. It is concluded that recycle can enhance mass transfer, especially for larger reflux ratio.

• Elastomers and Composites
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• 제32권5호
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• pp.325-329
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• 1997

Microbial treatment of the powdered waste tire was studied to recycle the waste tires. Chemoautotrophic acidophilic, iron-oxidizing bacterium was employed to unvulcanize the powdered tires. Biotreated rubber powder was compared to a untreated and a chemically treated powder. The results showed sulfur content of rubber powder(1.33%) were decreased to 1.22% by chemical treatment and 1.12% by microbial treatment for 20 days, 0.88%, for 30 days. One of the problems of the powdered utilization of the waste tires is that rubber powder leads to decrease mechanical properties when it is compounded with other virgin polymers. When tee biotreated powder was compounded with natural rubber, the mechanical properties were less decreased when untreated or chemically treated powder. Therefore, the microbial treatment can be one of useful methods to recycle the waste tire.