• Title/Summary/Keyword: chemical pulp

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Evaluation of the properties and the papermaking applicability of the residue originated from the anaerobic digestion of livestock manure (축산분뇨 혐기소화 잔재물의 특성 및 초지 적용성 평가)

  • Kim, Seung Min;Jung, Woong-Gi;Sung, Yong Joo;Ahn, Hee-Kwon;Kim, Dong Sung;Yoon, Do-Hyun;Kim, Dong-Seop;Jung, Hwa Gwang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.58-64
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    • 2014
  • Management of organic waste such as livestock manure has been considered as very important issue in terms of the environment. The anaerobic digestion of livestock manure become more attractive treatment method and has been widely applied. In this work, the properties of the residue after the anaerobic digestion of livestock manure was evaluated for providing the basic data to develop new application. The lignin and the ash contents of the residue were much higher than those of other biomass such as wood. The components of the residue were also analyzed with SEM-EDS and Elemental Analyzer. The addition of the residue into the handsheet paper resulted in the higher bulk and he higher air permeability with the loss of the strength properties. The water holding capacity of the handsheet were increased until the 40 % addition of the residue.

Study of the Annals of Joseon Dynasty for Developing Systematic Conservation Scheme (조선왕조실록의 체계적 보존을 위한 기초 연구)

  • Jung, Sun-Young;Lee, Min-Woo;Jang, Hyeon-Joo;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.2
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    • pp.1-12
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    • 2013
  • The annals of Joseon Dynasty designated as a national treasure No. 151 and a UNESCO World Memory are among the greatest archives that should be preserved permanently and inherited to future generations through the proven scientific conservation method. The annals of Joseon Dynasty in the custody of the National Archives of Korea as the sole original archive, has been restricted from the direct physical and chemical approaches. In this study, it is to develop a systematic conservation management scheme, based on the conservation state of the annals. Four books from the annals were selected out of 848 books and their moisture contents and optical property profiles were measured through the books. All the defects previously and newly found were pictured in 10~100 magnifications. The wire marks left on the Hanji's of the annals were analyzed. It was found that water damages and paper molds were prevalent in all four annals selected, and it was recommended to conduct more research for the conservation of those damaged areas. It turned out that various qualities of Hanji's were used for the time of publishing the annals because moisture content, optical properties, and wire mark intervals were quite different between papers even within one book.

Evaluation of the physical properties of organic fillers made from agricultural byproducts (농업부산물로 제조된 유기충전제의 물리적 특성 평가)

  • Lee, Ji-Young;Lim, Gi-Baek;Kim, Young-Hoon;Lee, Se-Ran;Kim, Man-Young;Kim, Chul-Hwan;Kim, Sun-Young;Kim, Jun-Sik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.34-41
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    • 2013
  • In this study, we investigated the physical properties of powders made from agricultural byproducts, including rice straw, peanut husks, and garlic stems, to manufacture a new organic filler used for making paperboard. These materials were collected individually, and then we measured their chemical compositions. The byproducts were ground with a laboratory grinder and fractionated with 60-, 100-, and 200-mesh sieves to make many grades of organic fillers. After the grinding and fractionation, the yield, mean particle size, and particle size distribution of each grade were measured. Particle shapes were also investigated using a scanning electron microscope. The organic filler made from rice straw had the highest yield of the largest particle size group and higher contents of cellulose and hemicellulose than those made from peanut husks and garlic stems. The rice straw also showed more regular particle shapes and a lower aspect ratio than the other agricultural byproducts.

Immunopathology of Spleen following 7,12-Dimethylbenz[a]anthracene Treatment in BALB/C Mice (마우스의 비장에 미치는 7,12-Dimethylbenz[a]anthracene의 면역병리학적 연구)

  • Lee, Duck-Yoon;Han, Sang-Seop;Lee, Sang-Mog
    • Toxicological Research
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    • v.8 no.2
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    • pp.179-189
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    • 1992
  • This study was carried out to investigate the immunopathological effects of 7,12-Dimethylbenz[a]anthracene(DMBA) on spleen in mice. DMBA was administered subcutaneously to BALB/C mice by interscapular single injection of 50 or 100${\mu}g/g$ of body weight. Each DMBA treatment group and additional corn oil control group of mice were studied on day 1,3,7,14 and 21 following the injection of DMBA. DMBA treatment resulted in marked decrease in weights and cellularity of spleen. Spleen weights showed the greatest decrease at 14days after 50${\mu}g/g$ DMBA treatment, and at 21days after 100${\mu}g/g$ DMBA treatment. Spleen cellularity was similarly deceased in comparison with spleen weights. Spleen showed morphologically no typical changes throughout the experiment after 50${\mu}g/g$ DMBA treatment. Following the treatment of 100${\mu}g/g$ DMBA the spleen showed severe fibrosis, hemosiderin precipitation, and megakaryocytes decrease in red pulp at 14 days, while hemopoietic function was partly restored in addition to the appearance of a few megakaryocytes at 21 days. In spleen sections treated with antibodies to IgM or Thy1.2, lymphocytes strongly stained with IgM antibody were infiltrated around the central artery within the white pulp, and T-lymphocytes of periarterial lymphatic sheath (PALS) were diminished and destructed in sections treated with Thy1.2 antibody, at 14 days after the treatment of 100${\mu}g/g$ DMBA. By the electron microscopy phagocytic epithelial cells or macrophages were remarkably increased in spleen at 14and 21days following the treatment of 100${\mu}g/g$ DMBA.

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Mass Balance on the Pulping Extracts of Maple Hardwood using High Performance Liquid Chromatography (HPLC 분석기를 이용한 펄프용 단풍나무의 펄핑 추출액에 관한 물질수지)

  • Um, Byung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.102-108
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    • 2008
  • At the University of Maine, a hemicellulose pre-extraction technology is now being investigated to improve pulp yields, reduce the organic and inorganic load for liquor recovery, and create a feed stream for the generation of new biomaterials. It is important to understand the composition of unextracted wood, extracted wood, and pulping extracts in the design of an economically viable pilot-scale ethanol plant. For analysis of wood pulp composition, the total analytical mass balance closure was 100.6, 100.3, and 81.6% for unextracted chips, extracted chips, and pulping extracts from HPLC-H column analysis. Meanwhile, the total analytical mass balance from the HPLC-P column was 97.8, 86.3, and 80.7%, respectively. This slight variability between H- and P-column results for analytical mass balance may be within the experimental error of the measurement. The data generated by this analysis are important to further design work in commercializing this process.

Purification of extracellular Cerrena unicolor laccase by means of affinity chromatography (친화크로마토그래프법을 이용한 Cerrena unicolor laccase의 정제특성)

  • A. Leonowicz;L. Gianfreda;J. Rogalski;M. Jaszek;M.W. Wasilewska;E. Malarczyk;A. Dawidowicz;M. Fink-Boots;G. Ginalska;Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.7-17
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    • 1997
  • 균체가 생산하는 laccase 효소가 다방면으로 이용되면서, 이 효소를 균체로부터 대량으로 생산하고 분리.정제하여야 할 필요성이 대두되고 있다. 아울러 이 효소의 활성을 유도하기 위한 inducer 로서 2,5-xylidine 이 주로 사용되고 있는바, 이 xylidine 의 유독성이 인정되면서 사람에게 독성을 주지 않는 환경친화적 inducer의 검색이 필요하게 되었다. 본 연구에서는 백색부후균 Cerrena unicolor가 분비하는 laccase 효소의 유도를 위한 inducer로서 ferulic acid를 사용하였으며, 균체로부터 생산 및 분리된 laccase 효소의 정제특성을 구명코자 하였다. 본효소(constitutive enzyme)로서 I 및 II를, ferulic acid를 inducer로 사용한 경우 inducing 효소 III을 분리.정제하였다. 본 효소 I 및 II의 Michaelis 정수는 각각 737 M, 716 M 이었고, inducing효소 III은 167 M 로서, 기질에 대한 높은 친화성을 보여주고 있다. 분자량도 각각 65 kD, 63 kD 였으며, inducing효소 III은 59 kD 였다. 두효소 모두 15-19%의 당 및 단백질분자당 4M의 동(Cu)을 함유하고 있었다. 정제효율은 효소 I 및 II가 10.1%, 9.4% 였으며, III은 3.2% 였다. 모든 효소의 최적 pH 는 5.5였으며, 최적온도는 비교적 높은 $40^{\circ}C$였다.

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Influence of the Surface Energetics on flotation Process - Importance of the Surface Energy and Polarity of Solid Particles in Flotation Efficiency - (부유부상 공정에 있어서 표면 에너지의 역할 - 부유부상 효율에 있어 고형 입자의 표면 에너지 및 극성성분의 중요성 -)

  • Lee, Hak-Rae;Park, Il;Lee, Yong-Min;Lee, Jin-Hee;Cho, Joong-Yeon;Han, Sin-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.3
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    • pp.1-8
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    • 2002
  • The object of this study was to determine the surface energy of hydrophobically modified micro-crystalline cellulose (MCC) with AKD and evaluate the effect of surface energy of the solid particles dispersed in aqueous medium on flotation efficiency. Especially to eliminate the complication derives from the diverse parameters of solid particles including particle size, type, etc. MCC's modified with AKD have been used. The surface energy Parameters were calculated from advancing contact angles of apolar and polar liquids on MCC pellets using the Lifshitz-van der Waals acid-base (LW:AB) approach. Total surface energy of hydrophobic MCC ranged from 46.19 mN/m to 48.60 mN/m. The contribution of the acid-base components to the total surface energy ranged form 13% to 17% for hydrophobic MCC's. The effect of surface characteristics on the flotation efficiency was evaluated. It was shown that there exist critical values of surface energies to increase flotation efficiency. Total surface energy and polar component of solid particles should be lower than 47 mN/m and 7 mN/m, respectively, for effective removal in the flotation process.

THE EFFECT OF FILLERS ON THE DEINKING OF PHOTOCOPIED PAPER

  • Chen, Qing-min;Chang, Hou-min;Ethan K. Andrews;Heinz G. Olf
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.159-163
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    • 1999
  • Model experiments were conducted to investigate the effect of different fillers on the removal of toner ink. Combinations of different papers (commercial photocopy paper and filler-free paper), fillers (calcium carbonate, kaolin clay, and talc), and chemicals(1-octadecanol, stearic acid, oleic acid, and TOFA) and stearic acid were found to be effective in detachment and agglomeration of toner ink. Furthermore, pH had little effect on toner detachment and agglomeration, indicating both protonated fatty acids and their anions are equally effective. In the presence of either kaolin clay or talc, all these agglomerating agents are equally effective, although a slightly higher dosage(1% for clay and 2% for talc as compared with control) is required, presumably due to the adsorption of chemical by the filler. Calcium carbonate filler, on the other hand, has a significant and adverse effect on the fatty acids used but has little effect on 1-octadecanol with the exception of possible adsorption. While stearic acid is not effective, a much higher level of oleic acid or TOFA is needed when calcium carbonate fillers are present as compared to the filler-free case. Fatty acids react with calcium carbonate to form calcium salts. The availability of fatty acid anion for toner detachment and agglomeration is determined by the solubility of calcium salt of a given fatty acid. Calcium oleate is 10 times more soluble in water than calcium stearate.

Permanent Characteristics of the Handsheet Mixed with Hemp Bast Fiber (삼 인피섬유 혼합율이 종이의 보존 특성에 미치는 영향)

  • Kim, Jun-Kyu;Choi, Kyoung-Hwa;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.71-77
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    • 2014
  • Despite the ubiquity of electronic media, paper is still the most generally readable carrier of information. Because paper materials are deteriorated by chemical, biological and physical factors over time, there have been major concerns about the decay of large collections of books, publications, old maps, historical artifacts, and written records. Therefore, manufacture of permanent paper has been a highly debated issue in paper conservation research. Through the use of permanent paper, our new records, journals, library books, art works, and all culturally and historically important documents can be preserved. In this study, handsheets were made of mixture of hemp bast fiber produced by soda pulping and HwBKP varying the amount of hemp. Physical, mechanical and optical properties of each handsheet were examined. As the ratio of hemp bast fiber increased, mechanical properties were improved significantly, but opacity decreased. After aging, the optical properties of the handsheets mixed with the hemp bast fiber more decreased than those of the non-mixed handsheet. The more mixture ratio of hemp bast fiber increased, the more decreasing rate of optical properties increased. As a result, it was confirmed that hemp bast fiber is a very promising resource for the manufacturing of permanent paper.

Effects of Micro-Electrical Stimulation on Regulation of Behavior of Electro-Active Stem Cells

  • Im, Ae-Lee;Kim, Jangho;Lim, KiTaek;Seonwoo, Hoon;Cho, Woojae;Choung, Pill-Hoon;Chung, Jong Hoon
    • Journal of Biosystems Engineering
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    • v.38 no.2
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    • pp.113-120
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    • 2013
  • Purpose: Stem cells provide new opportunities in the regenerative medicine for human or animal tissue regeneration. In this study, we report an efficient method for the modulating behaviors of electro-active stem cells by micro-electric current stimulation (mES) without using chemical agents, such as serum or induction chemicals. Methods: Dental pulp stem cells (DPSCs) were cultured on the tissue culture dish in the mES system. To find a suitable mES condition to promote the DPSC functions, the response surface analysis was used. Results: We found that a working micro-current of 38 ${\mu}A$ showed higher DPSC proliferation compared with other working conditions. The mES altered the expressions of intracellular and extracellular proteins compared to those in unstimulated cells. The mES with 38 ${\mu}A$ significantly increased osteogenesis of DPSCs compared with ones without mES. Conclusions: Our findings indicate that mES may induce DPSC proliferation and differentiation, resulting in applying to DPSCs-based human or animal tissue regeneration.