• Title/Summary/Keyword: chemical process safety

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A Study on the Safety Enhancement of Chemical Plants Using Risk Based Inspection Method (Risk Based Inspection 기법을 이용한 화학공장의 안전성 향상에 관한 연구)

  • 노용해;유진환;서재민;임차순;고재욱
    • Journal of the Korean Society of Safety
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    • v.17 no.3
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    • pp.73-80
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    • 2002
  • The RBI technique proposed by API is composed of three steps. The qualitative RBI method can be used for the purpose of screening the components with high risk. And the quantitative RBI method employs complex risk evaluation model for predicting component risk in a quantitative manner. The inspection program can be optimized based on the results obtained by these RBI technique. The forementioned RBI technique has been applied to a common hydrodesulfurizer unit and the technique is critically evaluated for studying its benefits and limitations, which is the main issue of this thesis. It's conducted that the RBI method can provide a method for defining and measuring the component risk, and also provide a powerful tool for managing many of the important elements of a process plant.

Review for Retrospective Exposure Assessment Methods Used in Epidemiologic Cancer Risk Studies of Semiconductor Workers: Limitations and Recommendations

  • Park, Donguk
    • Safety and Health at Work
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    • v.9 no.3
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    • pp.249-256
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    • 2018
  • This article aims to provide a systematic review of the exposure assessment methods used to assign wafer fabrication (fab) workers in epidemiologic cohort studies of mortality from all causes and various cancers. Epidemiologic and exposure-assessment studies of silicon wafer fab operations in the semiconductor industry were collected through an extensive literature review of articles reported until 2017. The studies found various outcomes possibly linked to fab operations, but a clear association with the chemicals in the process was not found, possibly because of exposure assessment methodology. No study used a tiered assessment approach to identify similar exposure groups that incorporated manufacturing era, facility, fab environment, operation, job and level of exposure to individual hazardous agents. Further epidemiologic studies of fab workers are warranted with more refined exposure assessment methods incorporating both operation and job title and hazardous agents to examine the associations with cancer risk or mortality.

Analysis of Performance influencing Factor in Chemical Process Industry : A Practical Application (석유화학 산업에서의 수행영향인자 및 근본원인 분석 결과)

  • Kim Eun;Yu Kwang-Soo;Park Kyo-Shik
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2006.05a
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    • pp.294-299
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    • 2006
  • 한국에서는 석유화학 산업의 역사가 30년 이상이 되어 잠재적인 사고의 위험 가능성이 높아지고 있다. 지금까지의 석유화학 산업에서의 전통적인 위험성 평가와 시스템의 제어는 기계적인 결함에만 중점을 두었기 때문에 인간의 행동을 제어하는 것은 간과하여 왔다. 비록 자동화 기술가 제어기술의 발전이 필요함에도 불구하고 인간의 의사 결정 요소는 석유화학 산업에서 사고를 예방하는데 필수적이다. 대부분의 심각한 사고는 부적절한 인간의 행동과 안정장치의 기계적인 결함이 동시에 존재할 경우에 발생한다. A-HRA(Advanced Reliability Analyzer) 소프트 웨어는 석유화학 플랜트 내에서의 인적오류 확률을 분석하고 사고 데이터를 축적하기 위하여 개발되었다. A-HRA 프로그램을 이용하여 1960년대 이후부터 최근 까지 한국의 석유화학 산업에서 발생하여온 인적오류 사고 데이터를 입력하고 사고마다의 근본원인과 수행영향인자를 분석하였다. 이 본문에서는 Root cause Aanlysis을 통한 결과와 PIF(Performance Influencing Factor) 평가 결과를 보여준다. 이 분석 결과는 석유화학 산업의 안전을 극대화 시키면서도 인적오류 제어를 통하여 안전비용을 최저화 시킬 수 있는 대책을 제시할 것이다.

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The Study on the Quantitative Analysis in LPG Tank's Fire and Explosion (LPG 저장탱크에서의 화재$\cdot$폭발에 관한 정량적 영향 평가에 관한 연구)

  • Bae Sung-Jin;Kim Byung-Jick
    • Journal of the Korean Institute of Gas
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    • v.3 no.1
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    • pp.21-26
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    • 1999
  • Chemical plant's fire and explosion does not only damage to the chemical plants themselves but also damage to people in or near of the accident spot and the neighborhood of chemical plant. For that reason, Chemical process safety management has become important. One of safety management methods is called 'the quantitative analysis', which is used to reduce and prevent the accident. The results of the quantitative analysis could be used to arrange the equipments, evaluate the minimum safety distance, prepare the safety equipments. In this study we make the computer program to make easy to do Quantitative analysis of the accident. The output of the computer program is the magnitude of fire(pool fire and fireball) and explosion(UVCE and BLEVE) effects. We used the thermal radiation as a measure of fire magnitude and used the overpressure as a measure of explosion magnitude. In case of BLEVE, the fly distance of fragment can be evaluated. Also probit analysis was done in every case. As the case study, Buchun LPG explosion accident in Korea was analysed by the program developed. The simulation results showed that the permissible distance was 800m and probit analysis showed that 1st degree bum, 2nd degree burn, and death distances are 450, 280, 260m, respectively the simulation results showed the good agreement with the results from SAFER PROGRAM made by Dupont.

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A Direct Injection-mixing Total-flow-control Boom Sprayer System (주입식 총유량 자동제어방식 분관 방제기의 개발)

  • 구영모
    • Journal of Biosystems Engineering
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    • v.21 no.2
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    • pp.155-166
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    • 1996
  • A direct injection sprayer was designed using the concepts of injection mixing and total flow control, flowrate-based system compensating for the variation of forwarding speed. A metered rate, proportionally to the actual diluent flow rate, of a tracer chemical was injected directly into the diluent stream. The injection of chemical may improve the precision and safety of chemical application process. The control system was evaluated for the variables of the control interval, tolerances and sensitivities of flow regulation valve and injection pump. Performance of the system was assessed as that the response time of flow rate, response time of injection rate, absolute steady state error, and the coefficient of variance(C.V.) of concentration were 8.5 and -0.53 seconds, 0.067 lpm(0.8%) and 3.15%, respectively, at optimal parameters of control interval of 1.0 sec, fast sensitivity of flow regulation valve, medium sensitivity of injection pump and medium tolerance of flow rate. Performance of the system can be improved by increasing the sensitivity of flow regulating valve and employing a high resolution velocimeter, such as Doppler radar.

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Development and Selection of Accident Scenarios for Risk Assessment in HF Charging Process (HF 충진 공정의 위험성 평가를 위한 가상사고 시나리오 발굴 및 선정)

  • Jang, Chang-Bong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.26-32
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    • 2013
  • The best way to prevent major occupational accidents is prohibiting use of hazardous substances such as flammable gas, toxic gas whereas using alternative substances that ensured safety. but if there are no economic efficiency and substituting technologies of alternative substances, the best way is preparing to prevent accidents thoroughly. Therefore, this study has developed and selected release scenarios to use and apply for consequence analysis and emergency action plan for HF charging process of chemical plants that have HF release accidents and high probability of release accidents.

Evaluation of Lead Exposure Characteristics by Process Category and Activity (작업공정 및 활동에 따른 국내 작업장 납 노출특성 평가)

  • Dohee Lee;Naroo Lee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.33 no.1
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    • pp.19-33
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    • 2023
  • Objectives: The purpose of this study is to systematically identify situations where exposure levels are expected to be high by structuring domestic lead measurement data according to exposure processes and activities. Methods: Occupational exposure data on lead was collected from the results of the Evaluation of Reliability of Working Environment Measurement conducted by the government from 2019 to 2020. Lead exposure characteristics were analyzed by PROC (process category) and activity. The Risk Characterization Ratios (RCRs) of five PROCs according to ventilation type and lead content were evaluated using the MEASE (Metal's EASE) model. Results: The exposure data on lead (n=250) was classified into 12 PROCs and 12 activities, with an average concentration of 0.040 mg/m3 and about 14% exceeding the occupational exposure limit of 0.05 mg/m3. Processes with high exposure levels were PROC 7 (industrial spraying), 23 (open processing and transfer operations of molten metal), 24 (mechanical treatment), 25 (welding), and 26 (handling of powder containing lead). The results of evaluating RCR for the five PROCs were greater than 1 or close to 1 even if local exhaust ventilation was used. Conclusions: There is a possibility that the concentration of exposure is high in the casting and tapping of molten metal containing lead, mechanical treatment such as fracturing and abrasion, handling of powder, spraying, battery manufacturing, and waste battery recycling processes. It is necessary to implement chemical management policies for workplaces with such processes.

Surface Safety Characteristics of Polypropylene Surface Treatment by Variation of Rolling Speed and The Electric Power of Corona Discharge (코로나방전 표면 처리시 이동속도 및 공급전력 변화에 따른 폴리프로필렌 표면 안전성 특성)

  • Lee, Su Hwan;Lee, Dong Hoon
    • Journal of the Korean Society of Safety
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    • v.33 no.1
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    • pp.41-46
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    • 2018
  • Experiments were carried out the phenomenal observation on effect of corona treated hotmelt laminating film in process of manufacture by 2 kinds of rolling speed and electric power variatons. Surface treatment by corona which is exposure of film surface to electron of ion bombardment, rather than mere exposure to active species, like atomic oxygen or ozone, can enhance adhesion by removing contaminant, electret, roughening surface, and introducing reactive chemical group. Reactive neutrals, ions, electron and photons generated during the corona treatment interact simultaneously with polymers to alter surface chemical composition, wettability, and thus film adhesion. However, it is highly recommended that extensive chains scission is avoided because it can lead to side-effect by forming sticky matter, resulting in dropouts. This paper reviews principles of surface preparation of polypropylene substrate by corona discharging. In addition, the experimental section provides a description of parameter optimization on corona discharging treatment and its side-effect. Experimental results are discussed in terms of surface wetting as determined by contact angle and SEM measurements. When the rolling speed of the film decreased from 1.666 [m / sec] to 0.083 [m / sec], contact angle decreased from $80[^{\circ}]$ to $64[^{\circ}]$, and the wettability was greatly improved. As the supply power increased from 0.4 [kVA] to 2 [kVA] at the corona discharge surface treatment, the contact angle decreased from $77[^{\circ}]$ to $65[^{\circ}]$, and the wettability was greatly improved.

Effect of N2 Diluent on Soot Formation Characteristics in Ethylene Diffusion Flames (에틸렌 확산화염 내 질소 혼합이 매연 생성 특성에 미치는 영향)

  • Jun-Soo Kim
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.4
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    • pp.356-362
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    • 2023
  • The risk of climate change has been long acknowledged, and ongoing efforts to overcome this issue, within the shipping sector, with the international maritime organization playing a central role. Conducting research on characteristics of soot formation is crucial to control its occurrence within the combustion process. In this study, the laser extinction method and chemical reaction numerical analysis were employed to examine the alterations in the state of chemical species associated with flame temperature, flame visual, and soot formation by mixing nitrogen, an inert gas, in the counterflow diffusion flame based on ethylene gas. The findings of the study suggest that as the mixing ratio of nitrogen increased, both the flame temperature and soot volume fraction decreased. Additionally, the area in which soot particles were distributed also decreased, and the volume fraction decrease rate declined when the mixing ratio increased by more than 30%. The mole fraction of the chemical species involved in soot growth also decreased. the chemical species associated with the HACA reaction were affected by variations in the hydrocarbon fuel ratio, and the chemical species related to the odd carbon path were confirmed to be affected by the flame temperature as well as the hydrocarbon fuel ratio.

A Study on Effective Removal Method of Odorant Smell in Natural Gas using Sodium Hypochlorite (차아염소산나트륨을 이용한 천연가스 부취냄새 효과적 탈취방법 연구)

  • Lim, Hyung-Duk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.154-159
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    • 2018
  • Intentional releases occur frequently during maintenance in gas supplying companies, which may result in unpleasant odors, and the possible mistaken belief of a gas accident. Therefore, this study developed a chemical process for effective odorant removal in natural gas using an active chemical that is released intentionally during maintenance and inspection. To develop an effective treatment process for removing the odorant from released natural gas, the effluent concentrations of the odorant in the released gas were measured after a chemical oxidation reaction with a sodium hypochlorite solution in a compact gas scrubbing equipment newly devised in this study. The device was based on a mixed gas vent after the solution inject odorant in the gas through the energy of the venting gas. The cascade combination of a venturi pipe and mixing chamber was developed to remove the odorant effectively from the purposely-released natural gas using an oxidative reaction between the mercaptan compounds (odorant) and the sodium hypochlorite solution. On the other hand, the developed method could be applied limitedly to a relatively small gas release from a low-pressure source. Further studies will be needed to apply the developed process to a large-scale gas release from a high-pressure source.