• Title/Summary/Keyword: chemical process safety

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Development of Human Error Probability Program for Human Error Analysis of Chemical Plants (화학 산업 시설에서의 인적 오류 분석을 위한 HEP 프로그램 개발)

  • Ko Jae Wook;Im Cha Soon;Park Kyo-Shik
    • Journal of the Korean Institute of Gas
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    • v.6 no.4 s.18
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    • pp.1-7
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    • 2002
  • Human errors can take place in all levels that include the design, production, construction, operation and maintenance of plant facilities. It was found that the causes were concerned with the effects of human error. This study verified characteristics of the on-site operators and error mechanism, and used the classifying sheet to analyze human error that occurred in process. Also, by applying the ASEP(Accident Sequence Evaluation Program) HRA(Human Reliability Analysis) procedure, the algorithm to estimate the HEP and the ASEP HEP program to analyze human error in the plant were developed. If it is built in on-site, possible human error incident will be prevented and the systematic human error prevention strategy will be devised.

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A Study on Odor-Savor and Microbiological Changes of Mineral Water Depending on the Storage Period (생수의 저장기간에 따른 이·취미 및 미생물학적 변화에 관한 연구)

  • Lee, Woo-Sik;Seo, Kwang-Seok
    • Journal of the Korea Safety Management & Science
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    • v.16 no.4
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    • pp.441-449
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    • 2014
  • As people seek a healthy, wealthy, and quality life more than before, interests in mineral water are picking up and the consumption continues to increase accordingly. In an experiment to examine changes in the water quality after mineral water on the market was kept indoor and outdoor for four weeks, there seemed to be no problem in external appearance. Water kept in an outdoor storage contained more odor-savor than water kept in an indoor storage. Odor was not detected in 90% of the sample, and savor not in 80% of it. As for the mechanism of odor-savor generation, the elution of chemical substances from a container may be taken into consideration. In general, odor and savor have turned out to be in close correlation to each other. The average number of bacteria in the sample mineral water was $200{\pm}10CFU/mL$, and such factors as area of storage and ozone post-treatment did not cause significant effects on the reproduction of common microbes. Hence, it is thought that strict regulations on a production process and reduction of the period of circulation will contribute to customers consumption rates.

Analysis of a Fire Accident during a Batch Reactor Cleaning with AcciMap, STAMP and FRAM (AcciMap, STAMP, FRAM을 이용한 반응기 세척 작업 중 화재 사고 분석)

  • Seo, Dong-Hyun;Bae, Gye wan;Choi, Yi-Rac;Han, Ou-Sup
    • Journal of the Korean Society of Safety
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    • v.36 no.4
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    • pp.62-70
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    • 2021
  • Representative systematic accident analysis methods proposed so far include AcciMap, STAMP, and FRAM. This study used these three techniques to analyze a fire accident case that occurred during routine manufacturing work in a domestic chemical plant and compared the results. The methods used different approaches to identify the cause of the accident, but they all highlighted similar causal factors. In addition to technical issues, the three accident analysis methods identified factors related to safety education, risk assessment, and the operation of the process safety management system, as well as management philosophy and company culture as problems. The AcciMap and STAMP models play complementary roles because they use hierarchical structures, while FRAM is more effective in analyses centered on human and organizational functions than in technical analyses.

Safety Assessment on the Incineration Disposal of Regulation Exempt Waste by RESRAD Code (RESRAD 코드를 활용한 규제해제 폐기물 소각처분에 대한 안정성 평가)

  • Kim, Hui-Gyeong;Han, Sang-Wook;Park, Su-Ri;Kim, Byung-Jick
    • Journal of radiological science and technology
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    • v.41 no.1
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    • pp.67-73
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    • 2018
  • In this paper, risk assessment was conducted to verify self - disposal requirements by landfill for exempted incineration ash by using Resrad Ver.6.5 computer code. The result of risk assessment by landfill for the incineration by-product is that individual dose is $6.91{\times}10^{-2}{\mu}Sv\;y-1$ and collective dose is $3.475{\times}10^{-7}man-Sv\;y-1$. It proved that the result meets reference dose of individual dose $10{\mu}Sv\;y-1$ and collective dose 1 man-Sv y-1 for general public. According to the current 'Nuclear Safety Commission Notice [No. 2014-3]', it states that the exempted wastes can be disposed of by incineration, landfill and recycling. However, most of recently documents and papers related to exempted wastes are disposed of by landfill and recyling and it could not confirm the case of exempt by incineration. If the national consensus is derived and treating the waste by using process of incineration is activated, it could be considered to treat low level of radiation wastewater and activated carbon excluded from exempted waste because of nuclide $^3H$ and $^{14}C$.

Consequence Analysis for Fire and Explosion Accidents in Propylene Recovery Process (프로필렌 회수공정에서 화재 및 폭발 사고의 피해영향 해석)

  • Han, Seong-Hwan;Lee, Hern-Chang;Park, Kyoshik;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.52-60
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    • 2014
  • This study aims to suggest risk management plan including safety measures through hazard identification followed by consequence analysis in petrochemical plants. Consequence analysis was performed through practical release scenario by using PHAST RISK(ver. 6.7) software in the propylene recovery process(PRP). As results, consequences by fire or explosion accidents in the depropanizer zone, deethanizer zone and heat pump zone were relatively larger than other else zones among six process zones in the PRP. In the case of jet fire, it is recommendable not to install residence building within 200 m of the process zone. Additionally, process zones having large inventory or high pressure must be prevented from accidents and required to establish quick response against accidents.

A modularized numerical framework for the process-based total system performance assessment of geological disposal systems

  • Kim, Jung-Woo;Jang, Hong;Lee, Dong Hyuk;Cho, Hyun Ho;Lee, Jaewon;Kim, Minjeong;Ju, Heejae
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2828-2839
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    • 2022
  • This study developed a safety assessment tool for geological disposal systems called APro, a systemically integrated modeling system based on modularizing and coupling the processes which need to be considered in a geological disposal system. Thermal, hydraulic, chemical, canister failure, radionuclide release and transport processes were considered in the current version of APro. Each of the unit processes in APro consists of a single Default Module, and several Alternative Modules which can increase the flexibility of the model. As an initial stage of developing the modularization concept and modeling interface, the Default Modules of each unit process were described, with one Alternative Module of chemical process. The computation part of APro is mainly a MATLAB workspace controlling COMSOL and PHREEQC, which are coupled by an operator splitting scheme. The APro model domain is a stylized geological disposal system employing the Swedish disposal concept (KBS-3 type), but the repository layout can be freely adjusted. In order to show the applicability of APro to the total system performance assessment of geological disposal system, some sample simulations were conducted. From the results, it was confirmed that coupling of the thermal and hydraulic processes and coupling of the canister failure and the radionuclide release processes were well reflected in APro. In addition, the technical connectivity between COMSOL and PHREEQC was also confirmed.

Design and Simulation of Fluidized Bed System for Waste Propellant Treatment by Computational Fluid Dynamics (폐 추진제 소각을 위한 유동층 반응기 설계 및 CFD 공정 모사)

  • Lee, Jiheon;Lee, Inkyu;Kim, Hyunsoo;Park, Jungsoo;Oh, Min;Moon, Il
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.84-89
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    • 2018
  • Recently, many studies have focused on the explosive waste treatment in terms of the safety and environmental pollution. A combustion process using fluidized bed incinerator has several profits : continuous process, low pollutive gases such as NOx, and high process efficiency. This study focused on the design of the propellant combustion reactor by using computational fluid dynamics(CFD) simulation technique. As a result, the reactions are successfully simulated in cylindrical incinerator, and. The study will influence to the research about treatment of explosive wastes.

Measurement and Prediction of Fire and Explosion Properties of n-Ethylanilne (노말에틸아닐린의 화재 및 폭발 특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.474-478
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    • 2018
  • For process safety, fire and explosion characteristics of combustible materials handled at industrial fields must be available. The combustion properties for the prevention of the accidents in the work place are flash point, fire point, explosion limit, and autoignition temperature (AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. In the chemical industries, n-ethylaniline which is widely used as a raw material of intermediate products and rubber chemicals was selected. For safe handling of n-ethyl aniline, the flash point, the fire point and the AIT were measured. The lower explosion limit (LEL)of n-ethylaniline was calculated using the lower flash point obtained in the experiment. The flash points of n- ethylaniline by using the Setaflash and Pensky-Martens closed-cup testers measured $77^{\circ}C$ and $82^{\circ}C$, respectively. The flash points of n-ethylaniline using the Tag and Cleveland open cup testers are measured $85^{\circ}C$ and $92^{\circ}C$, respectively. The AIT of the measured n-ethyl aniline by the ASTM E659 apparatus was measured at $396^{\circ}C$. The LEL of n-ethylaniline measured by Setaflash closed-cup tester at $77^{\circ}C$ was calculated to be 1.02 vol%. In this study, it was possible to predict the LEL by using the lower flash point of n-ethylaniline measured by closed-cup tester. The relationship between the ignition temperature and the ignition delay time of the n-ethylaniline proposed in this study makes it possible to predict the ignition delay time at different ignition temperatures.

Preparation and Properties of Polymer Blends Type Humidity Sensor for Process Safety (공정안전용 Polymer Blend형 습도센서의 특성 연구)

  • Kang Young-Goo;Cho Myoung-Ho
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.51-56
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    • 2004
  • Conductive polymer blends and composites are widely used for different safety application such as electrostatic charge dissipation(ESD), electromagnetic interference(EMI) shielding, electrostatic prevention and safety chemical sensor. In order to prepare a impedance-type humidity sensor that is durable at high humidities and high temperature, electically conductive polymer blends based on diallyldimethylammonium chloride(DADMAC) and epoxy were prepared in this study. The polymer blends type conductive ionomer exhibits reaction each other DADMAC and epoxy in FT-IR and DSC analysis. The blends material was traced by new peak at 1600cm-1 and appeard improvement of thermal resistance by melting point shift. Alumina substrate was deposited a pair of gold electrodes by screen printing. The blend material were spin-coated with a thin film type on the surface of alumina substrate. The polymer bleld type sensor exhibits a linear impedance increasing better than DADMAC coated humidity sensor. Also it shows good sensitivity, low hysteresis and durability against high humidity.

Sodium Reduction in Traditional Fermented Foods (전통발효식품의 나트륨 저감화)

  • Park, Hyun-Joo;Lee, Mi-Young;Yoon, Eun-Kyong;Chung, Ha-Yull
    • Food Science and Industry
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    • v.49 no.2
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    • pp.34-44
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    • 2016
  • Given that fermented foods, such as kimchi and doenjang, are main food sources for high sodium intake in Korea, there have been needs to develop sodium-reduced kimchi and doenjang with the proper quality. However, small and medium sized business could not actively develop the sodium-reduced products due to lack of techniques and information as well as economical reasons. The most important aspects is to address food safety issues including microbial contaminations in sodium-reduced foods. Hurdle Technology, physical, biological, chemical control technique, would have to be preferentially considered to increase the hygiene safety standards in entire processing steps including raw materials, process water, manufacturing environments, and so on. Once the food hygiene level is stable, the next challenges are to improve the taste of the sodium reduced-products as well as to packaging and storage technologies. The development of a variety of sodium-reduced fermented foods would result in significant mitigation of sodium intake by Korean. This report provides the directions to develop sodium-reduced kimchi, doenjang or pickled food products for small and medium sized business, based on the technical consulting results of sodium reduction project supported by Ministry of Food and Drug Safety in 2015.