• Proceedings of the Materials Research Society of Korea Conference
• /
• 1998.08a
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• pp.90.2-90
• /
• 1998

• Bulletin of the Korean Chemical Society
• /
• v.32 no.3
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• pp.783-784
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• 2011

• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.11a
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• pp.230-232
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• 2004

• Proceedings of the Korean Magnestics Society Conference
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• 2003.12a
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• pp.257-257
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• 2003

• Proceedings of the Korean Vacuum Society Conference
• /
• 2009.08a
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• pp.216-216
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• 2009

• Proceedings of the Korean Vacuum Society Conference
• /
• 2003.02a
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• pp.143-143
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• 2003

• Bulletin of the Korean Chemical Society
• /
• v.29 no.10
• /
• pp.1993-1997
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• 2008

In the present work, Diels-Alder reaction of cyclopentadiene with ethylacrylate has been carried out by using two types of mesoporous solid acid catalysts (Al-MCM-41, Al-MCM-48) with different pore structures. The specific topology of Al-MCM-48 (cubic Ia3d structure composed of two independent 3-D channel systems) exhibit higher activity and stereo-control than those of Al-MCM-41 (hexagonal packing of 1-D channels). The physical properties of Al-MCM-48 catalyst, such as high accessibility of reactants to the acid sites, spatial confinement in the nanoscopic reactors, and 3-D channel network structure that are effective adsorption and diffusion of reactants, play a crucial role in the present study.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2008.02a
• /
• pp.91-91
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• 2008

• Proceedings of the Membrane Society of Korea Conference
• /
• 2003.11a
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• pp.219-222
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• 2003

• Polymer Science and Technology
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• v.8 no.5
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• pp.635-643
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• 1997