• Title/Summary/Keyword: chemical leak

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A Study on Validation for Mapping of Gas Detectors at a BTX Plant (BTX 공정에서 Gas Detector Mapping 적정성 검토에 관한 연구)

  • Seo, Ji Hye;Han, Man Hyoeng;Kim, Il Kwon;Chon, Young Woo
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.168-178
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    • 2017
  • In order to prevent major and chemical accidents, some of the plants which would like to install and operate hazard chemicals handling facilities must submit Off-site Consequence Analysis due to recent arisen leak accidents since 2015. A lot of chemical industrials choose gas detectors as mitigation equipment to early detect gas vapor. The way of placement of gas detectors has two methods; Code-based Design(CBD) and Performance-based Design. The CBD has principles for gas detectors to be installed with consideration for the place that is expected to accumulate gas, and the leak locations according to legal standards and technical guidelines, and has a possibility to be unable to detect by these rules to locate gas detectors by vapor density information. The PBD has two methods; a Geographic Method and Scenario based Method. The Scenario-based Method has been suggested to make up for the Geographic Coverage Method. This Scenario-based Method draw the best optimum placement of gas detectors by considering leak locations, leak speed information, leak directions and etc. However, the domestic placement guidelines just refers to the CBD. Therefore, this study is to compare existing placement location of gas detectors by the domestic CBD with placement locations, coverages and the number of gas detectors in accordance with the Scenario-based Method. Also this study has measures for early detecting interest of Vapor Cloud and suitable placement of gas detectors to prevent chemical accidents. The Phast software was selected to simulate vapor cloud dispersion to predict the consequence. There are two cases; an accident hole size of leak(8 mm) from API which is the highst accident hole size less than 24.5 mm, and a normal leak hole size from KOSHA Guide (1.8 mm). Detect3D was also selected to locate gas detectors efficiently and compare CBD results and PBD results. Currently, domestic methods of gas detectors do not consider any risk, but just depend on domestic code methods which lead to placement of gas detectors not to make personnels recognize tolerable or intolerable risks. The results of the Scenario-based Method, however, analyze the leak estimated range by simulating leak dispersion, and then it is able to tell tolerable risks. Thus it is considered that individuals will be able to place gas detectors reasonably by making objectives and roles flexibly according to situations in a specific plant.

A Study on the Applicability of Acrylic Water Leak Repair Materials used to Repair Cracks in Conduits and Underground Structures (관거 및 지하구조물 균열 보수에 사용되는 아크릴 누수 보수재의 적용성에 대한 연구)

  • Eunmi Lee;Kyungik Gil
    • Journal of Wetlands Research
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    • v.26 no.2
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    • pp.139-146
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    • 2024
  • Various injection materials, such as asphalt-based injection materials, urethane-based injection materials, cement- based injection materials, and acrylic-based injection materials, are used for the repair of aged conduits and underground structures with cracks. In this study, research was conducted on an environmentally friendly acrylic- based leak repair material that exhibits good curing properties even in humid conditions and stability in temperature fluctuations. To compare the performance of the improved acrylic leak repair material with the existing acrylate injection material, experiments were conducted using KS standard methods, including underwater length change rate tests, underwater leakage resistance tests, and chemical performance tests. The comparative experiments revealed that the improved acrylic leak repair material showed no changes in shrinkage due to humidity, temperature variations, or chemical reactions compared to the existing acrylate injection material. In the underwater resistance test, the improved acrylic leak repair material did not show any leakage. Additionally, to assess the environmental impact of the improved acrylic leak repair material, acute fish toxicity tests and acute oral toxicity tests were conducted, and the results showed no mortality and no specific concerns with the test specimens. The experimental results led to the conclusion that the improved acrylic leak repair material is considered to be superior in performance, environmentally safe, and harmless to the human body. Based on various experimental results, it is inferred that the improved acrylic leak repair material is suitable for use as a repair material for cracks in manholes and underground structures compared to the existing acrylate repair material. This study aims to propose valuable data for future technological development by evaluating the applicability of acrylic leak repair materials.

Development Can Air Leak Detector System For Single Compression Head-Line Type Using Pressure Sensor (압력 센서를 이용한 씽글 헤드라인 타입의 캔 에어 리크 검출씨스템 개발)

  • Lee, Jong-Woon
    • Proceedings of the KIEE Conference
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    • 1992.07a
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    • pp.506-507
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    • 1992
  • When it comes to the 'Leak Detector System' generally, our country has a large income 'Rotary Type Leak Detector' of foreign goods. The completed development of the 'Line Type Leak-Detector' system was produced to check Whether the containers for small and large on the filling line are auto defective. This system is applied to the filling package Processing during the production and contributed to inproving competiveness of domestic containers manufactures of all society of Industry. Also, high precision and realiablity, very compact size, low cost and Easy set-up etc. by checking the experimental data directly plan, Design and making for '1 Compression Head Control Leak Detector System'. This flexcible system can be equipped with multiple Compression heads depending on the requested prodution test rate and test precision.

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Consideration on Design and Management of Flexible Hose through the Case Study of Chlorine Leak (염소 누출 사고사례연구를 통한 Flexible hose 설계 및 관리 방안 고찰)

  • Park, Suyoul;Yim, Ji-pyo
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.351-357
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    • 2019
  • This research was performed to propose domestic standard for design and management of flexible hose by analyzing chlorine leak caused by breakage of the hose in Ulsan, 2018. The leak had multiple causes but this paper focuses on analyzing the cause of breakage of flexible hose, the direct cause. According to the analysis, flexible hose that the company of the accident used for chlorine transfer was inappropriate in several aspects including material and wall thickness. And even pressure test had been conducted below operating pressure. Upon investigation on five companies that handle chlorine in Ulsan, four companies were using inappropriate flexible hose for chlorine transfer. Since there is no domestic standard for the design of flexible hose for chlorine transfer at present, it is hard to examine its design adequacy. Design standard of flexible hose used in chlorine transfer that is applicable domestically is proposed based on this research. It will contribute to the reduction in risk of breakage of the hose if the proposed standard could be applied in design and examination of flexible hose.

A Study on the Diffusion Behavior of Leak Gas from Underground Gas Pipeline (지하매설 가스배관의 가스 누출시 지하 확산거동에 관한 연구)

  • Choi S.C.;Jo Y.D.;Kim K.S.
    • Journal of the Korean Institute of Gas
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    • v.3 no.2 s.7
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    • pp.43-52
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    • 1999
  • An experimental chamber was fabricated to observe the gas diffusion behavior of leak gas from underground city-gas pipeline. It was made of acryl so that feeding of gas and the measuring points of the gas could be varied in each experiment. The MOS sensors were used to measure the concentrations of leak gas. The soil media such as the Jumunjin standard sand and the granite weathered soil were used to measure the gas diffusion and the change of leak gas concentrations was measured with time for various gas flow rate. As the distance between the leak point of gas and the measuring point of MOS sensor decreases, or the leak rate increases, the detection time of gas at a measuring points decreases and the gas concentration increases quickly and the concentration of the gas at steady state also increases. As the density of granite weathered soil is higher than that of Jumunjin standard sand for compaction, the detection time of leak gas in the granite weathered soil was longer than that in the Jumunjin standard soil. The leak gas concentrations in the granite weathered soil were lower than those in the Jumunjin standard sand at the beginning of gas leaking from a pipe, but inverse phenomenon was occured at steady state.

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Corrosion Characteristics of a 5Cr-1Mo Steel Specimen by Sodium-Water Reaction (나트륨-물 반응에 의한 5Cr-1Mo Steel 시편의 부식특성)

  • Jeong, Kyung-Chai;Jeong, Ji-Yeong;Park, Jin-Ho;Hwang, Sung-Tai;Kim, Eui-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1023-1029
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    • 1998
  • Small water leak experiment was carried out for the 5Cr-1Mo steel specimen in sodium atmosphere. Perfect re-open time for the leak path of a specimen, by micro leak, was 129 minutes, and its size observed about 2 mm diameter at sodium side. The halos phenomena appeared around of leak spot before the leak path has re-opened, and the size of halos observed was different from the real re-open size of a specimen. Also, the corrosion of a specimen initiated from sodium side, but it did not occur at steam side. In AES analysis, the segregation phenomena of Cr in the specimen was found much more than those of other elements. And also, the sodium compounds formed by sodium-water reaction and deposited onto the leak site of specimen were observed by EPMA analysis and SEM photograph. It is postulated that the corrosion products could be precipitated to form mixed Na Fe Cr compounds.

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A Study on Prevention of Accidents of Carbon Monoxide Leak from Gas Boilers (가스보일러 일산화탄소 누출사고 경감에 관한 연구)

  • Song, Jaechang;Kwon, Hweeung;Lee, Younghee;Moon, Il
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.277-281
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    • 2012
  • This work is concerned with a plan for preventing accidents of CO gas leak from gas boilers, involving the enforcement of installations of both CO alarm system and condensing boilers, and financial support of government grants. If amongst 1,460,000 beneficiaries of basic livelihood security, one million households in use of gas boilers receive 3-year support of 200,000 won, the difference of prices between common and condensing boilers, the government grants would be 2,000 billion won. If 3 million common householders are in 3-year support of 100,000 won, government grants would be 3,000 billion won. Therefore, 3-year grand total of government grants would be 5,000 billion won. Finance for government grants can be purveyed from energy saving; yearly 2,000 billion won of energy saving by enforcing to replace one million existing boilers with condensing boilers, leading to 2 trillion won of energy saving for 10 years. In this way, 6,000 billion won of 3-year grand total of government grants for CO alarm system and condensing boilers can be purveyed. The rest amount would be fundraised for energy savings. We claim that our proposal can make an achievement of more than 50% reduction of CO leak accidents during 10 years.

Prevention of Soil Contamination from Underground Storage Facilities of Petroleum Product and Hazardous Chemical Compounds (유류 및 유해화학물질 저장시설에서의 토양오염 방지대책)

  • 배우근;홍종철;정진욱;김종호
    • Journal of Soil and Groundwater Environment
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    • v.7 no.4
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    • pp.40-47
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    • 2002
  • The practices of the construction and management of the petroleum and hazardous chemical compound storage facilities in Korea were investigated extensively, and the problems were identified. The advanced technologies in the U.S.A were comparatively studied. Considering the effectiveness of leak prevention and applicability, the following measures were suggested. To prevent corrosion of a tank, a clad tank, an interior lining tank, or a double-wall tank were thought to be the most cost effective. For piping. use of non-metalic materials was suggested. A catchment basin seemed to be effective for preventing spills. For monitoring of leaks, constructions of more than one of detection systems, such as an automatic leak detection device. a vapor detection system, a groundwater monitoring system, or a double-wall monitoring system, were recommended.

A Study on the Improvement of Emergency Block and Diffusion Prevention System for Hazardous Chemicals Leakage (화학물질 누출에 따른 긴급 확산 방재시스템 개선 방안 연구)

  • Lee, Deok-Jae;Yun, Jeong Hyeon;Yoo, Byung-Tae
    • Journal of the Korean Institute of Gas
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    • v.22 no.5
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    • pp.89-99
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    • 2018
  • In the case of medium and small-sized businesses handling hazardous chemicals, emergency disaster prevention by workers, rather than a disaster prevention system using a safety device equipped with an automation system in case of a leak accident, is highly likely to occur. In order to solve these limitations, in this study investigated an emergency disaster prevention system that can be easily removed and adhered to the expected point of leakage according to the occurrence frequency of the leak during the chemical handling process.