• Title/Summary/Keyword: chemical indicator

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Geochemical Investigations of Contaminated River Waters Part II-Chemical Oxygen Demand of River Water and Industrial Waste Water in Seoul (汚濁河川水의 地球化學的인 硏究 (第 II 報) 서울市內 河川水 및 工場排水의 化學的 酸素要求量)

  • Lee, Yong-Keun
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.5-12
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    • 1970
  • River water and industrial waste water in Seoul were studied by means of chemical oxygen demand(COD) as an indicator for water pollution, from August 1967 to July 1968. Rivers flowing through residential and industrial areas are badly contaminated and COD of water in Han River increases as it progresses to downstream. Seasonal variation of COD showed that higher value of COD was observed in spring and lower in autumn. It is clear that the seasonal variation of COD is influenced by the precipitation. Close relationship was found between COD and population density. The lowest COD curve obtained by plotting COD values against population density and show that the curve slopes upward. The discontinuation of the curve was shown at the population density of 14,000/km$^2$; an increase in COD was acute over the population density of 14,000/km$^2$.

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Fabrication of Chemical Sensors for the Detection of Acidic Gas using 1,3-bisdicyanovinylindane (1,3-bisdicyanovinylindane을 이용한 산성가스 감지용 화학 센서 제작)

  • Song, Hwan-Moon;Park, Young-Min;Son, Young-A;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.184-188
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    • 2008
  • This study presented simple and efficient fabrication of chemical sensors for the detection of acidic gas using 1,3-bisdicyanovinylindane as an indicator because it can be promising materials having property of the rapid color change according to the variation of pH. The dissociation of proton and dye in acidic condition as changing of ion pairs give rise to dramatically change the absorbance intensity of 1,3-bisdicyanovinylindane, which can be easily applied to the development of chemical sensors. In addition, indicator dyes having negatively charge in aqueous phase can be easily fabricated using layer-by-layer (LBL) methods by way of electrostatic interaction. For the proof of concept, we demonstrated the abrupt presentation of skeleton symbol on the chemical sensor, which could be resulted from the reaction of 1,3-bisdicyanovinylindane as background color with acidic gas. Thus, the rapid appearance of symbol will induce user's caution under the emergency condition. The presented chemical gas sensor using 1,3-bisdicyanovinylindane have strong advantages. First, the fabrication process of gas sensor was very simple and low-cost. Secondly, sensors reacted by acidic gas could be reused for several times. Finally, the chemical gas sensor would be environmentally friend, which can be a basic tool for the realization of eco-organic sensor device.

Evaluation of Influent Water Quality Using Indicator Microorganisms in Lake Shiwha (지표미생물을 이용한 시화호 유입수의 수질평가)

  • Lee, Hee-Tae;Kim, Hee-Yeon;Park, Hyun-Jin;Cho, Young-Eun;Ryu, So-Young;Lee, Kyung-Jin;Jung, Jong-Sun;Ko, Gwang-Pyo
    • Journal of Environmental Health Sciences
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    • v.34 no.1
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    • pp.86-94
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    • 2008
  • Lake Shiwha, an artificial lake located near metropolitan Seoul, offers a unique water environment and has been suspected to have high levels of chemical and microbiological contaminations. Lake Shiwha was originally connected to the sea but currently has four major surface water inputs from agricultural, municipal, industrial areas and in addition an occasional inflow from the sea. The objectives of this study are to investigate the relative contribution of microbial contaminants from each of the inflowing surface waters and to identify appropriate microbial indicator organisms in this unique water environment. We measured the levels of microbial contaminations in the four inflowing surface waters. A number of microbial indicator organisms including total coliform (TC), fecal coliform (FC), E. coli, Enterococci, somatic and male-specific coliphages were analyzed. Bacterial indicator microorganisms were detected and quantified by the $Colilert^{(R)},\;Enterolert^{(R)}$ kit. Surface water (50 l) was sampled by $ViroCap^{TM}\;5"$ cartridge filters and analyzed by the single agar layer method for detecting coliphages. The concentrations of TC, FC, E. coli, and Enterococci were 1543 CFU/100 ml${\sim}1.99{\times}10^6$ CFU/100 ml, 0 CFU/100 ml${\sim}202$ CFU/100ml, 0 CFU/100 ml${\sim}1.80{\sim}10^5$ CFU/100ml, 74 CFU/100 ml${\sim}3408$ CFU/100 ml, respectively. The male-specific and somatic coliphages were detected in three different inflowing surface waters. Isolated E. coli and Enterococci strains were further analyzed by 16s rDNA amplification and subsequent phylogenetic analysis from Jungwang-chun, Ansan-chun, Banwol-chun and penstock of inflowing surface water. Our results indicated that the concentrations of different fecal indicator microorganisms might not be highly correlated with each other. Multiple microbial indicator organisms should be used for monitoring microbial contamination and microbial source tracking methods.

Sustainability Indicator for the Korea Industrial Sectors and Decomposition Analysis of its Variations over Time (산업별 지속가능지표의 측정과 지속가능량의 변동요인 분해)

  • Rhee, Hea-Chun;Chung, Hyun-Sik
    • Environmental and Resource Economics Review
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    • v.12 no.1
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    • pp.91-120
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    • 2003
  • This paper is intended to measure sectoral sustainabilities and inter-industry linkage effects of natural capital depletion of the Korean industries, and to analyze sources of their change over time using the familiar input-output model. The sustainability indicator that we are measuring in this paper is based on the so-called genuine saving concept proposed by the World Bank(1997). We accommodated the concept in the extended analytical framework of Proops et al.(1999) to analyze sectoral sustainabilities of the Korean industries. We decomposed sectoral sustainabilities so measured into their composing factors based on the decomposition method devised by Chung & Rhee (2001). According to our analysis, overall sustainability of the Korean industries has been declined since 1995. In heavy and chemical, transportation, and electricity sectors, their sustainabilities has been gotten worse. Among four major factors influencing the sustainability, change in GDP was the most important followed by changes in savings, industrial structures, and demand patterns.

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Environmental Impact Assessment of Wastewater Treatment Plant Using Life Cycle Assessment (LCA기법을 이용한 하수처리장의 환경영향 평가)

  • Park, Kwang-Ho;Hwang, Yong-Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.6
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    • pp.809-818
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    • 2005
  • Comprehensive environmental impact of wastewater treatment plant (WWTP) was evaluated with life cycle assessment (LCA) methodology based on ISO 14040. As environmental impact assessment method, Eco-indicator 95 and Eco-indicator 99 were used. The studied WWTP had a capacity of $100,000m^3/d$, and its life span of civil structure and main machinery was designed to 40 years and 20 years, respectively. As the results, more than 95% of environmental impact was produced by using electricity and chemical use in operation stage. In construction stage, temporary shoring facility was the major reason of environmental load, however, its impact was much less than those by operation utilities.

Variation of Adenosine tri-Phosphate(ATP) in Fermentation-Extinction of Food Wastes with Wood Bio-Chip (목질바이오칩에 의한 음식물쓰레기 발효-소멸반응에서의 아데노신3인산의 변화)

  • Oh, Jeong-Ik
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.4
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    • pp.363-368
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    • 2010
  • The overall indicator of microbial activity in the fermentation-extinction reaction of food waste by using bio wood-chips were investigated by considering adenosine tri-phosphate(ATP). Degradation rate of organic compounds, which was represented by chemical oxygen demand(COD) and total nitrogen(TN), was increased with the concentration of adenosine tri-phosphate during fermentation-extinction reaction of food waste by using bio-wood chips. With this view, the ATP would be one of the overall evaluation indicator of organic degradation in the species of bio-wood chip for the fermentation-extinction of food waste.

GC-MS and GC-FID Analysis of Citronella Oil Products for Indicator Ingredient Identification

  • Sumin Kang;Wooil Kim;Jin Wuk Lee;Sangwon Cha
    • Mass Spectrometry Letters
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    • v.14 no.4
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    • pp.160-165
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    • 2023
  • Citronella oil, an essential oil extracted through steam distillation from the leaves and stems of Cymbopogon, is a natural complex substance (NCS) regulated by the Korean government for its use in insect repellents. The component ratios of NCSs like citronella oil vary due to differences in manufacturing processes and origins, presenting a challenge in identifying and quantifying these substances in consumer chemical products. This study analysed ten commercially available products of the most commonly used types of citronella oil, specifically Java and Ceylon types, using gas chromatography (GC)-mass spectrometry (MS) and GC with flame ionization detection (FID). Through chromatographic data, we aimed to determine the components that can qualitatively identify citronella oil and the indicator ingredients that can be used for content analysis.

A Study on the Proper Installation of Storage Tank Measuring Instruments through a Case Study of Corrosive Fluid Leak Accident (부식성 유체 누출 사고사례 연구를 통한 저장탱크 레벨게이지 적정설치에 관한 연구 )

  • Sang Ryung Kim;Gyu Sun Cho;Won Baek Yang
    • Journal of the Korean Institute of Gas
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    • v.27 no.2
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    • pp.32-38
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    • 2023
  • In a chemical plant, while supplying corrosive fluid to a storage tank with a pump, an accident occurred where the corrosive fluid leaked through the upper exhaust vent because the level indicator was not accurately determined. There are various causes of leakage accidents, but we focused on the sticking of the level indicator of the level gauge, which is the direct cause. As a result of the analysis, the level indicator used in the workplace where the accident occurred was randomly replaced, and in the summer when the accident occurred, the tubular type level gauge was found to be more likely to stick than other types because thermal expansion easily occurs. In addition, there were difficulties in reviewing the proper installation because the installation standards for measuring instruments installed in storage tanks were not clear in Korea. Therefore, in this study, based on accident cases and overseas standards, we are going to find out about precautions when installing storage tank instrumentation.

Measurement of Biological Activity in Pilot Scale Dyeing Wastewater Process by Using Respirometer (호흡률 측정기를 이용한 파일럿 스케일 염색폐수처리 장치에서의 생물학적 활성 측정)

  • Jeon Hyun Hee;Choi Kwang Keun;Yoon In Jun;Lee Jin Won
    • KSBB Journal
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    • v.19 no.5
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    • pp.390-393
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    • 2004
  • Oxygen uptake rate (OUR) was used as an indicator of microbial activity. In this study OUR at dyeing wastewater in the pilot plant was monitored to examine biological activity. Correlation between inlet COD concentration and maximum OUR showed that maximum OUR was proportional to inlet COD concentration. Changes in the OUR values reflected the changing waste load in the reactor. Consequently, OUR can be used to estimate biological activity of inlet COD concentration. This study showed that biodegradable COD at dyeing wastewater could be calculated from OUR and yield coefficient. Non-biodegradable COD was able to be calculated from a difference between initial COD concentration and biodegradable COD.

Effect of Chemical Amendments on Soil Biological Quality in Heavy Metal Contaminated Agricultural Field

  • Kim, Yoo Chul;Hong, Young Kyu;Oh, Se Jin;Oh, Seung Min;Ji, Won Hyun;Yang, Jae E.;Kim, Sung Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.2
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    • pp.146-152
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    • 2015
  • Heavy metal pollution has been a critical problem in agricultural field near at the abandoned metal mines and chemical amendments are applied for remediation purpose. However, biological activity can be changed depending on chemical amendments affecting crop productivity. Main purpose of this research was to evaluate biological parameters after applying chemical amendments in heavy metal polluted agricultural field. Result showed that soil respiration (SR) and microbial biomass carbon (MBC) were changed after chemical amendments were applied. Among three different amendments, lime stone (LS), steel slag (SS), and acid mine drainage sludge(AMDS), AMDS had an effect to increase SR in paddy soil. Comparing to control ($93.98-170.33mg\;kg^{-1}day^{-1}$), average of 30% increased SR was observed. In terms of MBC, SS had an increased effect in paddy soil. However, no significant difference of SR and MBC was observed in upland soil after chemical amendment application. Overall, SR can be used as an indicator of heavy metal remediation in paddy soil.