• 제목/요약/키워드: chemical indicator

검색결과 330건 처리시간 0.025초

유기인계 살충제 (다이아지논)에 대한 물벼룩, Daphnia magna (Cladocera: Daphniidae) 개체군의 공간분산 변이 (Change in Spatial Dispersion of Daphnia magna(Cladocera: Daphniidae) Populations Exposed to Organophosphorus Insecticide, Diazinon)

  • 이상희;지창우;전태수
    • Environmental Analysis Health and Toxicology
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    • 제24권3호
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    • pp.231-240
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    • 2009
  • We explored collective behaviors of indicator species to elucidate the effect of the chemical stress. After the treatments of an insecticide, diazinon, at low concentrations (1.0 and 10.0 ${\mu}g/L$), spatial dispersion patterns of Daphnia magna were checked in a test chamber. The I-index was used to characterize the movement data before (0~1 h) and after (1~2 h) the treatments in laboratory conditions. The slopes of the frequency distribution of I-index in semi-log scale decreased significantly, and the test populations appeared to be more dispersed with a lower degree of aggregation after the treatments. The index was feasible in indicating decrease in the ability of the specimens to keep desirable distances with neighbor individuals under chemical stress and showed a possibility of monitoring presence of toxic chemicals in environment through group behavior measurement.

학술지 영향력지수와 전자 학술지 이용의 상관관계 분석 (Analysis of the Relationship between Journal Impact Factor and Scholarly e-Journal Usage)

  • 김환민;김재훈;정도헌
    • 한국콘텐츠학회:학술대회논문집
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    • 한국콘텐츠학회 2007년도 추계 종합학술대회 논문집
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    • pp.40-44
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    • 2007
  • 국내에서 해외 학술 전자저널 이용과 학술지 영향력 지수의 관계를 알아보기 위하여 이 연구에서는 컨소시엄 기반으로 사이트 라이선스 형식으로 유통중인 American Chemical Society, Science, Elsevier, Wiley 등 4개 출판사 전자학술지의 2006년 이용량과 ISI의 JCR 2006에 등재된 영향력지수간의 상관관계를 중심으로 분석하였다. 이용량 분석 대상은 국내에서 상대적으로 이용량이 많으면서 이들 4개 출판사의 전자저널을 모두 라이선싱하고 있는 4개 대학과 5개 연구소를 택하였으며, JCR 영향력지수 부여 여부와 출판사, 주제 및 기관유형별로 학술지 영향력지수와 전자학술지 이용의 상관관계를 분석하였다.

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요오드화은막전극 (AgI / PVC${\cdot}$THF) 에 관한 연구 (제2보). 할로겐화 이온혼합물의 전위차법 적정오차에 관한 연구 (A Study on the Silver Iodide Membrane Electrode (AgI / PVC${\cdot}$THF) (Ⅱ). Potentiometric Titration Error of Halide Mixture)

  • 박기채;권영순
    • 대한화학회지
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    • 제25권4호
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    • pp.253-262
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    • 1981
  • AgI/PVC${\cdot}$THF막전극은 단일할로겐화이온과 할로겐화이온 혼합물을 질산은표준용액으로 전위차법적정할 때 지시전극으로 사용될 수 있다. 그러나 할로겐화이온혼합물을 단계적정할 때 오차가 매우 큼을 알 수 있었다. 그러나 적정용액에 $NaNO_3$$Ba(NO_3)_2$같은 뭉침제를 가하면 오차가 매우 감소한다. 또한 젤라틴과 거름종이의 효과 그리고 온도의 영향도 조사하였다.

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전남 고흥군 우각산 일대의 습윤지수와 암석의 풍화정도와의 상관관계 (Relationship between Wetness Index and Weathering degree of Rocks in Woogak Mounyain, Koheung-gun, Jeonnam-do)

  • 김성욱;김국락;한지영;윤원섭;김춘식;김인수
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2004년도 춘계학술발표회
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    • pp.882-889
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    • 2004
  • Wetness index obtained from topography data of Woogak Mountain was compared with chemical alteration index(CAI), clay minerall contents of rock, and magnetic susceptibility changes of outcrops, and they show a close interrelationship. It is shown that the wetness index can be used as a quantitative indicator of the weathering degree of rocks. Moreover, wetness index simulate quantitatively the hydrologic condition of the local area. Therefore, it is anticipated that wetness index can be used as the data that calculate the weathering speed of rock and weathering grade in the study of weathering sensitivity of rock.

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남한강 수계에서 장기 이화학적 수질특성에 대한 토지이용도 및 계절성 강우의 영향 (Influence of Landuse Pattern and Seasonal Precipitation on the Long-term Physico-chemical Water Quality in Namhan River Watershed)

  • 이지은;최지웅;안광국
    • 한국환경과학회지
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    • 제21권9호
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    • pp.1115-1129
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    • 2012
  • The objective of this study was to analyze long-term annual and seasonal trends of water chemistry on landuse patterns and seasonal precipitation using 72 sampling sites within Namhan River watershed during 2001-2010. Water quality, based on multi-parameters of water temperature(WT), dissolved oxygen(DO), biochemical oxygen demand(BOD), chemical oxygen demand(COD), suspended solids(SS), total nitrogen(TN), total phosphorus(TP), and electric conductivity(EC) varied largely depending on monsoon rain and landuse patterns such as forest, cropland, and residence. Concentrations of BOD and COD as an indicator for organic matter pollution, increased during summer monsoon season at the cropland and residential streams. Values of TN and TP were higher in residential streams than in the forest and cropland streams. In the meantime, DO values had weak relations to the landuse patterns of forest and cropland cover. Water quality was worst in cropland and residential streams, and also most degradated in 4th order streams. Overall, our results suggest that efficient water quality management is required in the cropland and residential landuse streams.

머신러닝을 이용한 반도체 웨이퍼 평탄화 공정품질 예측 및 해석 모형 개발 (Predicting and Interpreting Quality of CMP Process for Semiconductor Wafers Using Machine Learning)

  • 안정언;정재윤
    • 한국빅데이터학회지
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    • 제4권2호
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    • pp.61-71
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    • 2019
  • 반도체 웨이퍼의 표면을 연마하여 평탄화하는 Chemical Mechanical Planarization(CMP) 공정은 다양한 화학물질과 물리적인 기계장치에 의한 작용을 받기 때문에 공정을 안정적으로 관리하기 힘들다. CMP 공정에서 품질 지표로는 Material Removal Rate(MRR)를 많이 사용하고, CMP 공정의 안정적 관리를 위해서는 MRR을 예측하는 것이 중요하다. 본 연구에서는 머신러닝 기법들을 이용하여 CMP 공정에서 수집된 시계열 센서 데이터를 분석하여 MRR을 예측하는 모형과 공정 품질을 해석하기 위한 분류 모형을 개발한다. 나아가 분류 결과를 분석하여, CMP 공정 품질에 영향을 미치는 유의미한 변수를 파악하고 고품질을 유지하기 위한 공정 조건을 설명한다.

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UO22+ Ion-Selective Membrane Electrode Based on a Naphthol-Derivative Schiff's Base 2,2'-[1,2-Ethandiyl bis(nitriloethylidene)]bis(1-naphthalene)

  • Shamsipur, Mojtaba;Saeidi, Mahboubeh;Yari, Abdullah;Yaganeh-Faal, Ali;Mashhadizadeh, Mohammad Hossein;Azimi, Gholamhasan;Naeimi, Hossein;Sharghi, Hashem
    • Bulletin of the Korean Chemical Society
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    • 제25권5호
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    • pp.629-633
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    • 2004
  • A new PVC membrane electrode for $UO_2^{2+}$ ion based on 2,2'-[1,2-ethanediyl bis (nitriloethylidene)]bis(1-naphthalene) as a suitable ionophore was prepared. The electrode exhibites a Nernstian response for $UO_2^{2+}$ ion over a wide concentration range ($1.0{\times}10^{-1}-1.0{\times}10^{-7}$M) with a slope of 28.5 ${\pm}$ 0.8 mV/decade. The limit of detection is $7.0{\times}10^{-8}$M. The electrode has a response time of < 20 s and a useful working pH range of 3-4. The proposed membrane sensor shows good discriminating abilities towards $UO_2^{2+}$ ion with regard to several alkali, alkaline earth transition and heavy metal ions. It was successfully used to the recovery of uranyl ion from, tap water and, as an indicator electrode, in potentiometric titration of $UO_2^{2+}$ ion with Piroxycam.

산-염기 중화반응 실험의 문제점 분석 및 개선 방안 (An Analysis and Improvement of the Experiment of the Acid-Base Neutralization Reaction)

  • 전영화;홍란선;강영진;강성주
    • 대한화학회지
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    • 제48권2호
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    • pp.189-194
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    • 2004
  • 이 연구에서는 산-염기 중화반응의 실험 방법에 관련된 과학 교과서 내용을 분석하고, 문제점을 개선하는데 목적이 있다. NaOH-HCl 수용액의 중화반응실험에서 1) 페놀프탈레인의 decoloration, 2) 염 생성 확인을 위해 적정된 용액의 농축을 위한 가열 과정에서의 색 변화, 3) 염 결정 확인의 어려움이 문제점으로 지적되었다. 이러한 문제점들은 페놀프탈레인의 구조변화에 근거하여 설명하였고, 개선된 실험방법을 제시하였다.

Investigation of Gold and Silver Nanoparticles as Acid-base pH Indicators and Their Transition pH Ranges

  • Jung, Byoung Gue;Jo, Jihee;Yu, Jin Won;Lim, Jong Kuk
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3595-3600
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    • 2014
  • Monitoring of pH, especially under highly alkaline conditions, is necessary in various processes in the industrial, biotechnological, agricultural, and environmental fields. However, few pH indicators that can function at highly alkaline levels are available, and most of which are organic-based pH indicators. Several years ago, it was reported that gold nanoparticles prepared using trisodium citrate dihydrate were rapidly aggregated at pH values higher than ~12.7. A shift of surface plasmon resonance for such aggregated gold nanoparticles can be applied to pH indicators, allowing for the substitution of traditional organic-based pH indicators. The most important characteristic of pH indicators is the transition pH range. Herein, gold and silver nanoparticles are prepared using different reducing agents, and their transition pH ranges are examined. The results showed that all nanoparticles prepared in this study exhibit similar transition pH ranges spanning 11.9-13.0, regardless of the nanoparticle material, reducing agents, and concentration.

저가형 냉각탑 자동 수질 진단 시스템 개발 (Development of a Low-cost Automatic Water Quality Diagnosis System for Cooling Towers)

  • 김정환;박한빈;강태삼;박정근
    • 센서학회지
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    • 제23권1호
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    • pp.58-65
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    • 2014
  • We developed a low-cost automatic diagnosis system for water quality in cooling towers to measure the concentrations of key ingredients such as $Ca^{2+}$, $Cl^-$, $PO{_4}^{3-}$, and $Fe^{2+}$. $Ca^{2+}$, and $Cl^-$ are the main factors that cause the generation of scale, corrosion, and sludge in water pipes. $PO{_4}^{3-}$ prevents corrosion, sludge and scale by inhibiting the ions (i.e., $Ca^{2+}$, $Cl^-$) from sticking to the pipes. $Fe^{2+}$ is an indicator of pipe corrosion. The proposed system consists of a microprocessor, a specimen container and heater, a precision pump, relays and valves, LED optical sources, and photo detectors. It automatically collects water samples and carries out pretreatment for determining the concentration of each chemical, and then estimates the concentration of each ion using low-cost LED optical sources and detectors. Experimental results showed that the accuracy of the proposed system is sufficiently high for water quality diagnosis and management of cooling towers, demonstrating the possibility of the proposed system's wide usage in real environments.