• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.390-396
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• 2012

In order to understand the nature of dendritic zinc growth, electrochemical zinc redox reaction on nickel plate was investigated in aqueous solutions containing different concentrations, 0.2, 0.1 and 0.02 $mol{\cdot}dm^{-3}$ (M), of zinc sulfate ($ZnSO_4$) or zinc chloride ($ZnCl_2$). Zinc ion was efficiently reduced and oxidized on nickel in the high-concentration (0.2 M) solution, whereas relatively poor efficiency was obtained from the other low-concentration solutions (0,1 and 0.02 M). Cyclic voltammetry (CV) analysis revealed that the 0.2 M electrolyte solution decomposes at more positive potentials than the 0.1 and the 0.02 M solutions. These results suggested that the concentration of electrolyte solution and anion would be an important factor that suppresses the reaction of the zinc dendrite formation. Scanning Electron Microscopy (SEM) data revealed that the shape of dendritic zinc and its growing behavior were also influenced by electrolyte concentration.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.92-101
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• 2023

To solve the problem of climate change, carbon neutrality has now become a necessity rather than an option. Hydrogen is not only a energy storage that can supplement the intermittent production of renewable energy, but is also considered a good alternative in the field of utilization as it does not emit carbon dioxide after reaction. In order to revitalize hydrogen vehicles, one of the fields of hydrogen utilization, the construction of hydrogen station infrastructure must be preceded. Prioritization of risk factors is necessary for efficient operation and risk assessment of hydrogen stations, but due to the short operation period of domestic hydrogen stations, there is a lack of frequency data on accidents and their reliability is low. In this study, we aim to identify the causes and consequences of deviations in hydrogen stations through HAZOP analysis. Additionally, we intend to analyze them using Fuzzy-AHP. Through this, we intend to derive the decision values for the causes of deviations in hydrogen stations and apply them to hydrogen accident cases and risk assessments to confirm the reliability and utility of the data.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.3
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• pp.209-218
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• 2022

Recently, research on the development of anion exchange membranes (AEMs) has received considerable attention from the scientific community around the world. Here, we fabricated a series of AEMs with branched structures with different alkyl spacers and conducted comparative evaluations. The introduction of these branched structures is an attempt to overcome the low ionic conductivity and stability problems that AEMs are currently facing. To this end, branched polymers with different spacer lengths were synthesized and properties of each membrane prepared according to the branched structure were compared. The chemical structure of the polymer was investigated by proton nuclear magnetic resonance, Fourier transform infrared, and gel permeation chromatography, and the thermal properties were investigated using thermogravimetric analysis. The branched anion exchange membrane with (CH₂)₃ and (CH₂)₆ spacers exhibited ionic conductivities of 8.9 mS cm^-1 and 22 mS cm^-1 at 90℃, respectively. This means that the length of the spacer affects the ionic conductivity. Therefore, this study showing the effect of the spacer length on the ionic conductivity of the membrane in the polymer structure constituting the ion exchange membrane is judged to be very useful for future application studies of AEM fuel cells.

• Clean Technology
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• v.29 no.3
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• pp.217-226
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• 2023

The amount of hydrogen adsorbed in arrays of single walled carbon nanotubes (SWNTs) was studied as a function of nanotube diameter and distance between the nearest-neighbor nanotubes on square arrangements using a grand canonical Monte Carlo simulation. The influence of the geometry of a triangle array with the same diameters and distances was also studied. Hydrogen-carbon and hydrogen-hydrogen interactions were modeled with Lennard-Jones potentials for short range interactions and electrostatic interactions were added for hydrogen-hydrogen pairs to consider quantum contributions at low temperatures. At 194.5 K, Type I isotherms for large-diameter SWNTs and Type IV isotherms without hysteresis between adsorption and desorption processes for wider tube separations were observed. At 200 bars, the gravimetric hydrogen storage capacity of the SWNTs was reached or exceeded the US Department of Energy (DOE) target, but the volumetric capacity was about 70% of the DOE target. At 77 K, a two-step adsorption was observed, corresponding to a monolayer formation step followed by a condensation step. Hydrogen was adsorbed first to the inner surface of the nanotubes, then to the outer surface, intratubular space and the interstitial channels between the nanotube bundles. The simulation indicated that SWNTs of various diameters and distances in a wide range of configurations exceeded the DOE gravimetric and volumetric targets at under 1 bar.

• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.104-109
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• 2007

Single fuel cell was fabricated with a MEA (membrane electrode assembly) that had a $4cm^2$ active area and with silicon bipolar plates those were introduced to miniaturize the fuel cell by replacing heavy weight graphite plates. Optimum humidification condition for the single cell was selected based on performance results obtained varying humidifier temperature at a fixed feed rate of hydrogen and oxygen. Furthermore, to study the effect of humidification condition on the performance of a fuel cell stack, the fuel cell stack consisting of two MEAs and silicon bipolar plates was studied, then problems and characteristics of silicon-based fuel cell stack were examined.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.240-248
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• 2011

All-vanadium redox flow battery (VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide range of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. Among consisting elements of the VRFB, the ion exchange membrane and the electrode play important roles. In this study, carbon PVC coposite sheets for the VRFB have been developed and electrochemical characteristics investigated. Current collector for VRFB, carbon PVC composite sheets (CPCS), were prepared with G-1028 as a conducting particle, PVC as a polymer, Dibutyl phthalate (DBP) as a plasticizer and fumed Silica (FS) as a dispersion agent. CPCS has been shown to have the characteristics as an excellent current collector for VRFB and electrochemical properties of specific resistivity 0.31 ${\Omega}cm$, which were composed of G-1028 80 wt%, PVC 10 wt%, DBP 5 wt% and FS 5 wt%.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.5
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• pp.531-535
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• 2017

The performance of all-vanadium redox flow battery (VRFB) was tested with an increase of the current density. APS membrane (anion exchange membrane) and GF050CH (cabon felt) were used as a separator and electrode, respectively. An average energy efficiency of the VRFB was 79.5%, 68.1%, and 62.8% for the current density of $60mA/cm^2$, $120mA/cm^2$, and $160mA/cm^2$, respectively. It was confirmed that VRFB can be used as a energy storage system at the higher current density even if the energy efficiency was deceased about 21%.

• Korean Chemical Engineering Research
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• v.48 no.3
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• pp.322-326
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• 2010

Stability of sodium borohydride solution during storage was studied. In order to enhance the $NaBH_4$ stability, NaOH and KOH were added to the $NaBH_4$ solution. The effect of concentration of the borohydride and alkaline solution, temperature and materials of storage vessels on the rate of borohydride hydrolysis was investigated. The rate of hydrogen evolution decreased as the concentration of alkaline increased due to increase of $NaBH_4$ stability in the solution. The stability of $NaBH_4$ solution decreased when the borohydride concentration raised from 10 to 15 wt% and then increased when the $NaBH_4$ concentration increased above 15 wt% due to increase in the pH of the concentrated solution. The activity coefficient of hydrolysis of $NaBH_4$ solution(NaOH 3.0 wt%, $NaBH_4$ 25 wt%) was 115.1 kJ/mol and this value was 1.5~4.0 times higher than that of hydrolysis of $NaBH_4$ solution with catalyst. The borohydride solutions in glass and stainless-steel vessel were more stable than the solution in plastic(PE) vessel.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.207-207
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• 2000

Multi- and single-wall carbon nanotubes are promising new carbon materials in nano-electronics, field-emitters, CRT-displays, hydrogen storage materials, biomedical tracers and so forth. The present talk will deal with a high-yield synthesis on quasi-aligned multi-wall carbon nanotubes via a chemical vapor deposition technique. I will also talk about a possible growth mechanism on single-wall carbon nanotubes based on newly obtained experimental results.