• Title/Summary/Keyword: chemical heat conversion

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Influence of Nanostructured TiO2 Electrode Fabricated with Acid-treated Paste on the Photovoltaic Efficiency of Dye-Sensitized Solar Cells (산처리된 페이스트로 제조한 나노 구조체 TiO2 전극이 염료감응형 태양전지의 효율에 미치는 영향)

  • Lee, Jae-Wook;Hwang, Kyung-Jun;Roh, Sung-Hee;Kim, Sun-Il
    • Applied Chemistry for Engineering
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    • v.18 no.4
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    • pp.356-360
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    • 2007
  • Recently, dye sensitized solar cells (DSSCs) composed of nanoporous $TiO_2$, light-sensitive dyes, electrolytes, and counter electrode have been received much attention. Nanostructured particles with higher surface area for the higher adsorption of Ru (II) dye are required to increase the quantity of light absorption. Also, it has been reported that the key factor to achieve high energy conversion efficiency in the photoelectrode of DSSC is the heat treatment of $TiO_2$ paste with acid addition. In this work, we investigated the influence of acid treatment of $TiO_2$ solar cell on the photovoltaic performance of DSSC. The working electrodes fabricated in this work were characterized by X-ray photoelectron spectroscopy (XPS), extended X-ray absorption fine structure (EXAFS), field emission scanning electron microscope (FE-SEM), and atomic force microscope (AFM). In addition, the influence of nanostructured photoelectrode fabricated with the acid-treated paste on the energy conversion efficiency was investigated on the basis of photocurrent-potential curves. It was found that the influence of acid-treated paste on the photovoltaic efficiency was significant.

Rigorous Modeling and Simulation of Multi-tubular Reactor for Water Gas Shift Reaction (Water Gas Shift Reaction을 위한 Multi-tubular Reactor 모델링 및 모사)

  • Park, Junyong;Choi, Youngjae;Kim, Kihyun;Oh, Min
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.931-937
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    • 2008
  • Rigorous multiscale modelling and simulation of the MTR for WGSR was carried out to accurately predict the behavior of process variables and the reactor performance. The MTR consists of 4 fixed bed tube reactors packed with heterogeneous catalysts, as well as surrounding shell part for the cooling purpose. Considering that fluid flow field and reaction kinetics give a great influence on the reactor performance, employing multiscale methodology encompassing Computational Fluid Dynamics (CFD) and process modeling was natural and, in a sense, inevitable conclusion. Inlet and outlet temperature of the reactant fluid at the tube side was $345^{\circ}C$ and $390^{\circ}C$, respectively and the CO conversion at the exit of the tube side with these conditions approached to about 0.89. At the shell side, the inlet and outlet temperature of the cooling fluid, which flows counter-currently to tube flow, was $190^{\circ}C$ and $240^{\circ}C$. From this heat exchange, the energy saving was achieved for the flow at shell side and temperature of the tube side was properly controlled to obtain high CO conversion. The simulation results from this research were accurately comparable to the experimental data from various papers.

THE USE OF NEAR INFRARED REFLECTANCE SPECTROSCOPY(NIRS) TO PREDICT CHEMICAL COMPOSITION ON MAIZE SILAGE

  • D.Cozzolino;Fassio, A.;Mieres, J.;Y.Acosta
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1610-1610
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    • 2001
  • Microbiological examination of silage is of little value in gauging the outcome of silage, and so chemical analysis is more reliable and meaningful indicator of quality. On the other hand chemical assessments of the principal fermentation products provide an unequivocal basis on which to judge quality. Livestock require energy, protein, minerals and vitamins from their food. While fresh forages provide these essential items, conserved forages on the other hand may be deficient in one or more of them. The aim of the conservation process is to preserve as many of the original nutrients as possible, particularly energy and protein components (Woolford, 1984). Silage fermentation is important to preservation of forage with respect of feeding value and animal performance. Chemical and bacteriological changes in the silo during the fermentation process can affect adversely nutrient yield and quality (Moe and Carr, 1984). Many of the important chemical components of silage must be assayed in fresh or by extraction of the fresh material, since drying either by heat or lyophilisation, volatilises components such as acids or nitrogenous components, or effects conversion to other compounds (Abrams et al., 1987). Maize silage dorms the basis of winter rations for the vast majority of dairy and beef cattle production in Uruguay. Since nutrient intake, particularly energy, from forages is influenced by both voluntary dry matter intake and digestibility; there is a need for a rapid technique for predicting these parameters in farm advisory systems. Near Infrared Reflectance Spectroscopy (NIRS) is increasingly used as a rapid, accurate method of evaluating chemical constituents in cereals and dried forages. For many years NIRS was applied to assess chemical composition in dry materials (Norris et al., 1976, Flinn et al., 1992; Murray, 1993, De Boever et al., 1996, De la Roza et al., 1998). The objectives of this study were (1) to determine the potential of NIRS to assess the chemical composition of dried maize samples and (2) to attempt calibrations on undried samples either for farm advisory systems or for animal nutrition research purposes in Uruguay. NIRS were used to assess the chemical composition of whole - plant maize silage samples (Zea mays, L). A representative population of samples (n = 350) covering a wide distribution in chemical characteristics were used. Samples were scanned at 2 nm intervals over the wavelength range 400-2500 nm in a NIRS 6500 (NIRSystems, Silver Spring, MD, USA) in reflectance mode. Cross validation was used to avoid overfitting of the equations. The optimum calibrations were selected on the basis of minimizing the standard error of cross validation (SECV). The calibration statistics were R$^2$ 0. 86 (SECV: 11.4), 0.90 (SECV: 5.7), 0.90 (SECV: 16.9) for dry matter (DM), crude protein (CP), acid detergent fiber (ADF) in g kg$\^$-1/ on dry matter, respectively for maize silage samples. This work demonstrates the potential of NIRS to analyse whole - maize silage in a wide range of chemical characteristics for both advisory farm and nutritive evaluation.

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$Cu_2ZnSnS_4$ Thin Film Absorber Synthesized by Chemical Bath Deposition for Solar Cell Applications

  • Arepalli, Vinaya Kumar;Kumar, Challa Kiran;Park, Nam-Kyu;Nang, Lam Van;Kim, Eui-Tae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.35.1-35.1
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    • 2011
  • New photovoltaic (PV) materials and manufacturing approaches are needed for meeting the demand for lower-cost solar cells. The prototypal thin-film photovoltaic absorbers (CdTe and $Cu(In,Ga)Se_2$) can achieve solar conversion efficiencies of up to 20% and are now commercially available, but the presence of toxic (Cd,Se) and expensive elemental components (In, Te) is a real issue as the demand for photovoltaics rapidly increases. To overcome these limitations, there has been substantial interest in developing viable alternative materials, such as $Cu_2ZnSnS_4$ (CZTS) is an emerging solar absorber that is structurally similar to CIGS, but contains only earth abundant, non-toxic elements and has a near optimal direct band gap energy of 1.4~1.6 ev and a large absorption coefficient of ${\sim}10^4\;cm^{-1}$. The CZTS absorber layers are grown and investigated by various fabrication methods, such as thermal evaporation, e-beam evaporation with a post sulfurization, sputtering, non-vacuum sol-gel, pulsed laser, spray-pyrolysis method and electrodeposition technique. In the present work, we report an alternative method for large area deposition of CZTS thin films that is potentially high throughput and inexpensive when used to produce monolithically integrated solar panel modules. Specifically, we have developed an aqueous chemical approach based on chemical bath deposition (CBD) with a subsequent sulfurization heat treatment. Samples produced by our method were analyzed by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, absorbance and photoluminescence. The results show that this inexpensive and relatively benign process produces thin films of CZTS exhibiting uniform composition, kesterite crystal structure, and good optical properties. A preliminary solar cell device was fabricated to demonstrate rectifying and photovoltaic behavior.

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Model Development of Spray Dryer Absorber FGD Process (Spray Dryer Absorber 배연탈황공정의 모델 개발)

  • Jang, Sun-Hee;Oh, Eui-Kyung;Lee, Hyung-Keun;Kim, Sun-Geon
    • Clean Technology
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    • v.2 no.1
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    • pp.80-95
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    • 1996
  • A mathematical model has been developed for simulating the spray dryer absorber (SDA) used in semi-dry flue gas desulfurization process. Fundamental equations include the component mass and heat balances in both gas and droplet phases and the equation of motion for a single droplet. The model developed described the pilot-plant data much better than the existing SPRAYMOD-M model. The effect of the process variables, whose values were chosen within the operation limits of the actual pilot plants, on % $SO_2$ removal or conversion of the sorbent were calculated, and discussed in terms of $SO_2$ absorption rate, the residence time of flue gas, the velocity and drying time of droplets. Finally, the % $SO_2$ removal was calculated with two independent process variables and the results were shown on three-dimensional or two-dimensional diagrams with the lines of constant % $SO_2$ removal, so that they can be easily applied to preliminary design of the SDA.

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KIER Liquefaction R & D's status (KIER 액화 기술 개발 현황)

  • Yang, Jung-Il;Yang, Jung Hoon;Lee, Ho-Tae;Chun, Dong Hyun;Kim, Hak-Joo;Jung, Heon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.110.1-110.1
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    • 2010
  • A bench scale slurry bubble column reactor (SBCR) with active-Fe based catalyst was developed for the Fischer-Tropsch synthesis (FTS) reaction. Considering the highly exothermic reaction heat generated in the bench scale SBCR, an effective cooling system was devised consisting of a U-type dip tube submerged in the reactor. Also, the physical and chemical properties of the catalyst were controlled so as to achieve high activity for the CO conversion and liquid oil ($C_{5+}$) production. Firstly, the FTS performance of the FeCuK/$SiO_2$ catalyst in the SBCR under reaction conditions of $265^{\circ}C$, 2.5 MPa, and $H_2/CO=1$ was investigated. The CO conversion and liquid oil ($C_{5+}$) productivity in the reaction were 88.6% and 0.226 $g/g_{cat}-h$, respectively, corresponding to a liquid oil ($C_{5+}$) production rate of 0.03 bbl/day. To investigate the FTS reaction behavior in the bench scale SBCR, the effects of the space velocity and superficial velocity of the synthesis gas and reaction temperature were also studied. The liquid oil production rate increased upto 0.057 bbl/day with increasing space velocity from 2.61 to 3.92 $SL/h-g_{Fe}$ and it was confirmed that the SBCR bench system developed in this research precisely simulated the FTS reaction behavior reported in the small scale slurry reactor.

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Performance comparison of acidogenic fermentation and hydrogen fermentation using bench-scale leaching-bed reactors for food waste (벤치스케일 침출상 반응조를 이용한 음식폐기물 처리 시 신발효 및 수소발효의 거동특성 비교)

  • Han, Sun-Ki
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.3
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    • pp.97-105
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    • 2007
  • This study was conducted to compare the performances of acidogenic fermentation and hydrogen fermentation using bench-scale leaching-bed reactors for organic solid waste. Acidogenic fermenters were operated with dilution rates (D) of 2.0, 3.0 and $4.0d^{-1}$ after employing anaerobic sludge and hydrogen fermenters were operated with D of 2.0, 4.0 and $6.0d^{-1}$ after employing heat-treated anaerobic sludge. The highest chemical oxygen demand (COD) conversion efficiency (56.2%) was obtained in acidogenic fermentation with D of $3.0d^{-1}$. Only volatile fatty acid (VFA) was produced as a metabolite. On the other hand, hydrogen fermentation did not show higher COD conversion efficiency (49.3%) than acidogenic fermentation, but it produced hydrogen gas (5.1% of total COD) which was a clean and environmentally friendly fuel with a high energy yield. Therefore, either acidogenic fermentation or hydrogen fermentation could be applied to organic solid waste depending on the purpose of treatment, which could maximize the economics of anaerobic treatment.

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Solar CO2-Reforming of Methane Using a Double-Layer Absorber (더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Kim, Dong-Yeon;Lee, Jin-Gyu;Lee, Ju-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.267-273
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    • 2012
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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Design, Analysis and Experiment of Potato Gun with a Spherical Projectile (구형 탄환을 이용한 감자총의 설계, 해석 및 시험)

  • Kang, Hong-Jae;Kim, Ji-Hwan;Kim, Young-Sik;Son, So-Eun;Choi, Han-Ul;Choi, Jeong-Yeol
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.10
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    • pp.796-804
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    • 2013
  • The "Potato Gun," a simple heat engine, is fabricated, tested and analyzed as a part of engineering education program of combustion and propulsion classes. Combustor pressure is predicted by the chemical equilibrium analysis of a constant volume combustor. Then, the internal ballistics, the conversion of thermal energy into the mechanical energy of a projectile, is predicted though the expansion process. The trajectory of a projectile is estimated by considering the aerodynamic effect around the spherical projectile. The energy conversion efficiency and the equivalence ratio of the fuel-air mixture could be estimated by the comparison of the experimental results and the theoretical prediction. The present work would be an example of attracting the interest of students for the application of the engineering principles at undergraduate level by recycling the waste materials.

Solar CO2-Reforming of Methane Using a Double-Layer Absorber (더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Kim, Dong-Yeon;Shin, Il-Yoong;Lee, Ju-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.80-86
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    • 2011
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber - the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam - was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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