• Title/Summary/Keyword: chemical form distribution

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Characteristics of Heavy Metals (Ba, Cr) Distribution in Soil (토양 중 중금속(Ba, Cr)의 분포특성 평가)

  • Yoon, Jeong-Ki;Kim, Rog-Young;Kim, Ji In;Noh, Hoe-Jung;Yu, Soon-Ju;Kim, Tae Seung;Lee, Myung Gyu;Yun, Dae-Geun;Lee, Hong-gil;Kim, In Ja;Park, Gyoung-Hun
    • Journal of Soil and Groundwater Environment
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    • v.20 no.7
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    • pp.61-69
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    • 2015
  • This study was performed to provide fundamental data to establish the new soil pollution standards and the soil contamination management plans in a rational manner. The distribution characteristics of new soil contaminants such as barium (Ba) and chromium (Cr) in soils (n=140) were investigated in relation to land-use classification and geological features. Also, the sequential extraction test was conducted to evaluate fate and mobility of new soil contaminants. The soil samples taken from 140 sites were analyzed to survey distribution levels of selected new soil contaminants. The average concentration and range for hazardous metals (Ba, Cr) were Ba 128.946 (26.757~489.587) mg/kg, Cr 30.121 (2.579~132.783) mg/kg. Based on land use classification, the highest Ba concentration was found in factory soils, followed by dry field and park soils, while Cr concentration was highest in rice paddy soils, followed by dry field and factory soils. Within 10 geological units investigated the highest Ba and Cr concentrations were observed in the soils from Okcheon group and metamorphic rocks, respectively. The BCR (European Community Bureau of Reference) sequential extraction was conducted to identify chemical distributional existence of 2 elements of soils from each geological unit. Ba in soils is mainly assumed to exists as reducible form (such as BaSO4, BaCO3) and Cr in soils mainly is assumed to exist as residual form (such as Cr2O3, CrxFe1-x(OH)3(x < 1)).

Mathematical Modeling of Degree of Hydration and Adiabatic Temperature Rise (콘크리트의 수화도 및 단열온도상승량 예측모델 개발)

  • 차수원
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.118-125
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    • 2002
  • Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

Characterization of the Physical Form of Allergenic Cry j 1 in the Urban Atmosphere and Determination of Cry j 1 Denaturation by Air Pollutants

  • Wang, Qingyue;Morita, Jun;Gong, Xiumin;Nakamura, Shinichi;Suzuki, Miho;Lu, Senlin;Sekiguchi, Kazuhiko;Nakajima, Takuya;Nakajima, Daisuke;Miwa, Makoto
    • Asian Journal of Atmospheric Environment
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    • v.6 no.1
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    • pp.33-40
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    • 2012
  • In this study, we characterized the physical form of allergenic Cry j 1 in the urban atmosphere. Through an immunofluorescence antibody method, we showed that allergenic Cry j 1 exists as fine particles (${\leq}1.1{\mu}m$). To determine Cry j 1 concentrations and its particle size distribution, we used the ELISA method to confirm that most Cry j 1 exists as fine particles in the urban atmosphere and is found at high concentrations on fine day next to rainy day. Furthermore, we evaluated Cry j 1 denaturation by using the Biacore J system based on the surface plasmon resonence (SPR) principle and sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE). We showed that the dissociation constant ($K_D$) of Cry j 1 that has been exposed to urban polluted air is lower ($1.76{\times}10^{-14}$ M) than that of Cry j 1 ($1.32{\times}10^{-9}-3.37{\times}10^{-9}$ M) of original pollen grains that has not been exposed to air pollutants. Cry j 1 turns into low molecular weight proteins by reacting with various acidic solutions. In sum, we showed that allergenic Cry j 1 exists as fine particles that can deposit in the lower respiratory tract. This finding clarifies the relationship between Japanese cedar pollinosis and air pollutants.

Determination of hey Fuel Ratio According to Fuel Composition (IV) - Overall Estimation of Methods- (연료 조성에 따른 공연비 산정 (IV) - 공연비 계산방식의 평가-)

  • Park Chanjun;Ohm Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1155-1162
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    • 2004
  • This paper is the forth paper of several companion papers which compare the method of Air-Fuel ratio determination. In the previous work, various AFR calculations were performed for various fuels and the results were compared with each other. The comparison, however, were limited to numerical value and estimation of each equation or method was insufficient. In this paper, the overall estimation of the methods was attempted. Also, the method of trouble shooting of instrumentation was presented. Through the estimation of methods, it is concluded that the Eltinge method contains inherently the most perfect thermal dissociation model as far as the exhaust composition is concerned; therefore, this might be regarded as the most general equation of AFR determination among the existing ones. The others might be considered as approximate form. In addition, the mal-distribution factor in Eltinge method is qualitatively equivalent to thermal dissociation chemical equilibrium constant K. Lastly, it is illustrated that all instrumentation error, including the sampling line leakage, can be easily detected through the analyzing the exhaust component on the Eltinge chart.

The Effect of Substrate DC Bias on the Low -Temperature Si homoepitaxy in a Ultrahigh Vacuum Electron Cyclotron Resonance Chemical Vapor Deposition (초고진공 전자 사이클로트론 화학 기상 증착 장치에 의한 저온 실리콘 에피 성장에 기판 DC 바이어스가 미치는 영향)

  • 태흥식;황석희;박상준;윤의준;황기웅;송세안
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.501-506
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    • 1993
  • The spatial potential distribution of electron cyclotron resonance plasma is measured as a function of tehsubstrate DC bias by Langmuir probe method. It is observed that the substrate DC bias changes the slope of the plasma potential near the subsrate, resulting in changes in flux and energy of the impinging ions across plasma $_strate boundary along themagnetric field. The effect of the substrate DC bias on the low-temperature silicon homoepitaxy (below $560^{\circ}C$) is examine dby in situ reflection high energy electron diffraction (RHEED), cross-section transmission electron microscopy (XTEM),plan-view TEM and high resolution transmision electron microscopy(HRTEM). While the polycrystalline silicon layers are grow withnegative substrate biases, the single crystaline silicon layers are grown with negative substrate biases, the singel crystalline silicon layers are grown with positive substrate biases. As the substrate bias changes form negative to positive values, the growth rate decreases. It is concluded that the control of the ion energy during plasma deposition is very important in silicon epitaxy at low temperatures below $560^{\circ}C$ by UHV-ECRCVD.VD.

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Accumulation of $^{l69}Yb$ Citrate in Tumor Bearing Mice (흰쥐 육종 180에서 $^{169}Yb-Citrate$의 종양 친화성)

  • Kim, Jang-Hee;Hong, Sung-Woon;Lim, Sang-Moo;Lee, Jhin-Oh
    • The Korean Journal of Nuclear Medicine
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    • v.22 no.1
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    • pp.77-81
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    • 1988
  • Tumor localizing properties of $^{67}Ga$ citrate and $^{169}Yb$ citrate were studies with sarcoma 180 bearing mice. To compare precisely the accumulation of $^{67}Ga$ citrate and $^{169}Yb$ citrate in tumor tissue itself, $^{67}Ga$ and l63yb were administered simultaneously as a mixture of same chemical form of citrate. The yield of $^{169}Yb$ labeled citrated and the of radiopharmaceuticals purity was identified more than 90% by chromatography on silica gel plates. $^{67}Ga$ and $^{169}Yb$ were injected into mice and the mice were killed at 3, 24, and 48 hours following intraperitoneal injection of the radiopharmaceuticals. The retention value of $^{67}Ga$ and $^{169}Yb$ in tumor was similar but they differ from each other markedly in normal tissue distribution. $^{169}Yb$ citrate is cleared up from blood more rapidly than $^{67}Ga$ citrate, and a high tumor to blood ratio is achieved shortly after injection.

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Preparation of Nanoparticles in Drug Delivery System Using Guar Derivatives and Dialysis Method

  • Na, Kun;Kim, Yu-Eun;Lee, Ki-Young
    • Journal of Microbiology and Biotechnology
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    • v.9 no.1
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    • pp.50-55
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    • 1999
  • To develop a new form of controlled release dosage for administering for indomethacin (IND), two formulations of IND-loaded nanoparticles were designed based on polysaccharide (guar) derivatives. Nanoparticles prepared by the dialysis method were characterized with respect to morphology, size distribution, drug content, and in vitro drug release. Morphological studies by scanning electron microscopy (SEM) indicated that guar acetate (GA) nanoparticles were spherical in shape and had a smooth surface. The particle size distributions of formulation I (40mg of GA) and formulation II (80mg of GA) were shown to be $250.78\pm185.13nm$ and $718\pm145.90nm$ in distilled water ($20$^{\circ}C$), respectively. The drug loading efficiencies of nanoparticles were approximately 26% and 31% for formulations I and II, respectively. The differential scanning calorimetry (DSC) results indicated that the IND was perfectly distributed within GA nanoparticles. We also found, from the X-ray diffractometry analysis, that a decrease in the degree of crystallinity of the drug occurred in the nanoparticles. No changes between the original IND and the released IND from GA nanoparticles were detected by FT-IR. Using guar acetate, it is possible to design nanoparticles which allow the controlled release of IND over an extended period of time.

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Effects of convection on physical vapor transport of Hg2Cl2 in the presence of Kr - Part I: under microgravity environments

  • Lee, Yong Keun;Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.20-26
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    • 2013
  • Special attention in the role of convection in vapor crystal growth has been paid since some single crystals under microgravity environments less than 1 $g_0$ exhibits a diffusive-convection mode and much uniformity in front of the crystal regions than a normal gravity acceleration of 1 $g_0$. The total molar fluxes show asymmetrical patterns in interfacial distribution, which indicates the occurrence of either one single or more than one convective cell. As the gravitational level decreases form 1 $g_0$ down to $1.0{\times}10^{-4}\;g_0$, the intensity of convection, indicative of the maximum molar fluxes, is reduced significantly for ${\Delta}T=30K$ and 90 K. The total molar fluxes decay first order exponentially with the partial pressure of component B, PB (Torr) for 20 Torr ${\leq}PB{\leq}$ 300 Torr, and two gravity accelerations of $g_y=1\;g_0$ and 0.1 $g_0$.

A study on the charateristic of Natural Spring Water Quality in Seoul (서울시 일원의 약수터 수질특성에 관한 연구)

  • 김익수;권승미;이지영;김주형;이재영
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.57-59
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    • 2002
  • Because of the growing demand for protect and maintain one's health, population search for good water increase very rapid in recent. This study was performed to investigate the at 432 sites natural spring water quality in Seoul. Samples for analysis were collected form January to December in 2001. The quality of water was evaluated by analyzing fourty items of Korea drinking water criteria. The main results of this study were as follows 1. The rate of natural spring water was 26.6% and the Total colony, E.Coli and Yersinia of the total incongruence cause was 67.9% 2. The distribution of phisical-chemical item on the incongruence cause was Residues on evaporation 8.6%, Turbidity 4.3%, Nitrate nitrogen 2.5%, pH 2.5% and F-1,2% 3. The most population area of mean drinking population per one day was that man of Gangnam was 312.92 person. Next to Yangcheon Seocho Seodaemun and Dongjak was 229.6, 195.31, 190.50, 190,00 person. 4. The more person and the number of natural spring water, the more non passed drinking criteria natural spring water except for Gangnam and Gangbuk. 5. The corelationship of drinking population and results of the tests do not exist and the corelationship of results and Total colony, E.Coli, Color, Turbidity, KMNO4 consumption, Residues on evaporation, Fe, Mn, Zn and A1 are existed positive relationship.

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The Study of Cyanobacterial Flora from Geothermal Springs of Bakreswar, West Bengal, India

  • Debnath, Manojit;Mandal, Narayan Chandra;Ray, Samit
    • ALGAE
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    • v.24 no.4
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    • pp.185-193
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    • 2009
  • Geothermal springs in India, formed as a result of volcanic or tectonic activities, are characterized by high temperature and relatively abundant reduced compounds. These thermal springs are inhabited by characteristic thermophilic organisms including cyanobacteria. Cyanobacteria are among the few organisms that can occupy high temperature aquatic environments including hot springs. In alkaline and neutral hot springs and streams flowing from them cyanobacteria can form thick colourful mats that exhibit banding patterns. The present investigation involves study of mat forming cyanobacterial flora from hot springs located in Bakreswar, West Bengal, India. The important species found are Synechococcus bigranulatus, S. lividus, Gloeocapsa gelatinosa, G. muralis, Phormidium laminosum, P. frigidum, Oscillatoria princes, O. fragilis, Lyngbya lutea, Pseudanabaena sp., Calothrix thermalis, and Fischerella thermalis. Their distribution pattern in relation to physico-chemical parameters of spring water has also been studied. Three cyanobacterial strains of the above mentioned list were grown in culture and their pigment content and nitrogen fixing capacity were also studied. Nitrogen fixing capacities of Calothrix thermalis, Nostoc sp. (isolated in culture) and Fischerella thermalis are 5.14, 0.29, and 2.60 n mole $C_2H_4/{\mu}g$ of Chl-${\alpha}$/hr respectively. Carotenoid : Chlorophyll-${\alpha}$ ratio of four mat samples collected from Kharkunda, Suryakunda, Dudhkunda and bathing pool are 2.45, 1.60, 1.48, and 1.34, respectively. Higher value of Carotenoid : Chlorophyll-${\alpha}$ ratio coincided with higher temperature.