• Title/Summary/Keyword: chemical foaming

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Processing of Porous Ceramics by Direct Foaming: A Review

  • Pokhrel, Ashish;Seo, Dong Nam;Lee, Seung Taek;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.93-102
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    • 2013
  • Macro porous ceramics possessing controlled microstructures and chemical compositions have increasingly proven useful in the industrial sphere. Their sintered structures have found application in both established and emerging, areas such as thermal insulation in buildings, filtration of liquids and molten materials, refractory insulation, bone scaffolds and tissue engineering. Stable ceramic foams can be formed by wet chemical methods using inorganic particles(e.g., $Al_2O_3$ or $SiO_2$). The wet foams are dried and sintered with improved porosity and mechanical properties. This review examines the different techniques used to prepare porous ceramics from ceramic foams, focusing on the explanation of this versatile method of direct foaming from the past to the present. Comparisons of the processes and the processing parameters are explained with the produced microstructures.

Phase Morphology and Foaming of Polypropylene/Ethylene-octene Copolymer Blends (폴리프로필렌/에틸렌옥텐 공중합체 블렌드의 상분리 구조 및 발포 특성)

  • 서관호;임정철
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.707-718
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    • 2001
  • Polypropylene (PP) exhibits many beneficial properties such as low density high thermal stability, chemical resistance, good processability and recyclability. However, only limited research has been done on expanded polypropylene (EPP). In this study, we were trying to prepare EPP with chemical blowing agent. Ethylene-octene copolymer (mPE) was melt blended with PP to enhance melt fluidity of PP at processing temperature and to make more flexible foamed material. Prior to foaming, phase morphology of PP/mPE blends were investigated to examine the effect of phase morphology on the foaming ratio and cell structure of foams. Phase morphology of PP/mPE blends were affected by the content of mPE and mixing torque ratio. At the same composition, it was affected by mixing rpm. High blowing ratio and stable cell structure were obtained in the blend which has the continuous PP matrix with dispersed droplets of mPE.

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Preparation and Effects of Low Foaming Acidic Degreasing Agents for Aluminum (알루미늄용 저기포성 산성탈지제의 제조와 그의 탈지효과)

  • Ha, Kyung-Jin;Park, Hong-Soo;Bae, Jang-Soon;Kim, Young-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.3
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    • pp.71-77
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    • 1997
  • Low foaming acidic degreasing agent(LFADAs) were prepared by blending sorbitol, n-octanoic acid, MJU-100A, Tetronix T-701, Na-dioctyl sulfosuccinate, Demol C, and phosphoric acid. The physical properties of LFADAs tested with aluminum specimen showed the following results ; when 3wt% LFADA-6 was performed at $70^{\circ}C$, the degreasing rate was 95% which is comparitively good, and the percentage of etching was 0.275% which was found to be less than that of commercialized product. When 20wt% of LFADA-6 was added at $65^{\circ}C$, the percentage of derusting was 92% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

MCPs Product and Process Design of Mixed Materials Using Axiomatic Design (공리적 설계를 이용한 발포제 혼합재료의 MCPs 제품 및 공정 설계)

  • 이경수;차성운
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1414-1417
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    • 2003
  • In chemical forming process, mixed materials of LDPE, EVA and forming agent are used. However mechanical properties has been dropping remarkably through this forming process. In this study, Above materials(LDPE, EVA) were used in microcellular foaming injection process. And various effective factors in this process were selected by Axiomatic approach and systematically estimated by DOE(Design of Experiments). As a results, injection type and rate of mixing resins have more influence on forming rate than other factors.

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Effects of MWCNT Nucleating Agent on the Formation Reaction of Rigid Polyurethane Foams

  • Ahn, WonSool;Lee, Joon-Man
    • Elastomers and Composites
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    • v.50 no.1
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    • pp.13-17
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    • 2015
  • A study of the effects of MWCNT as a nucleating agent on the formation reactions of the rigid polyurethane foams (RPUFs) was carried out. Sample PUFs, formulated with grease-type master batch of MWCNT/surfactant, were fabricated by free-rising method. Temperature changes with time during foaming process were measured using a digital thermometer. RPUF foaming process was observed to undergo 2-step processes with temperature inflection around 60 sec after the start of reaction, and then reached slowly the max. temperature. While the max. temperature of neat PUF was measured as ca. $120^{\circ}C$, that of the samples with MWCNT were as higher value as ca. $130^{\circ}C$, and, even the time to reach that temperature was reduced by about 15 sec. Average cell size of PUF samples decreased from 185.1 for the neat PUF to $162.9{\mu}m$ for the sample of 0.01 phr of MWCNT. As the result, it was considered that MWCNT in RPUF foaming process could play a roll both as a nucleating agent and as a catalyst.

Production Process of Foamed Glass by Compressive Shaping (가압성형 방법에 의한 발포유리의 제조공정)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.239-246
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    • 2013
  • Principle of foamed glass manufacturing process first starts with putting vitreous material powder into a mold. After the foaming calcination, foamed body should be annealed after separation from the mold. For this reason, existing manufacturing process could not be a continuous type process. In this study, in order to develop a continuous production process of foamed glass, the possibility of new foam glass manufacturing process was investigated by foaming calcination of the compact body obtained from compression-molding of vitreous raw materials in stead of using a mold. Through the experimental results of the foaming calcination of the compact body with adding various foaming agents such as $Na_2CO_3$, $CaCO_3$ and petroleum coke, into hydrated soda-lime vitreous raw materials, it was shown that developing a continuous process without using any molds for manufacturing foamed glass would be possible.

Effect of Waste Ground Tire Rubber on Flame Retardancy and Foaming Properties of the NBR foams (폐타이어 고무분말(GTR)이 니트릴고무(NBR) 발포체의 난연 및 발포 특성에 미치는 영향)

  • Moon, Sung-Chul;Lee, Jae-Chul;Choi, Jae-Kon;Jo, Byung-Wook
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.251-261
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    • 2003
  • The flame retardancy and foaming properties of NBR foams containing waste ground tire rubber (GTR) were studied. When the composition ratios of NBR/GTR were ranged in $100/0{\sim}80/20$ (w/w) and rubbers/flame retardants were in the range of $1/1.95{\sim}3.70 wt%$, the considerably optimized foam for flame retardancy was obtained with high limiting oxygen indices (LOI, $29.4{\sim}40.0$), low heat release rate(HRR), closed/semi-closed cell of uniformity, and reasonable expandability ($215{\sim}300 %$). The LOI was increased and the heat release rate was decreased with increasing the amount of GTR content.

Effects of Diols on the foaming and emulsion properties in surfactant solutions

  • Lee, Giam;Oh, Seong-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.4
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    • pp.488-498
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    • 2022
  • The effects of 1,3-Butanediol, 1,2-Pentanediol, and 1,2-Hexanediol in surfactant solutions on cmc, surface tension, foaming and emulsifying properties were determined. The addition of diols in aqueous surfactant solution decreased cmc and surface tension, and enhanced the foaming and emulsifying power. This trend is more significant by the longer hydrocarbon chain length of the diols. This property was confirmed because the diol's alkyl chain and the hydrophobic interaction with the surfactant reduce the cohesive force of water and increase the interaction between the head groups of the surfactant at interface. In addition, MIC test was conducted to determine the preservative power of each diol, and as a result, the antibacterial activity was effective in the order of 1,2-HDO > 1,2-PDO > 1,3-BDO. The results of this study show that diol can be applied to cosmetics as an auxiliary surfactant and antibacterial agent.

The Study on the Rheological Properties of Polymer Matrix for MIF (Molded-In Foaming) Process (MIF (Molded-In Foaming) 공정에 적합한 고분자 기재의 유변학적 특성 연구)

  • Kim, Mingeun;Song, Hyeong Yong;Kim, Dong Gun;Kim, Hyo Jun;Park, Geon Uk;Yu, Jae Keun;Hyun, Kyu
    • Elastomers and Composites
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    • v.49 no.4
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    • pp.323-329
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    • 2014
  • In order to select polymer matrix for MIF (Molded-In Foaming) process, in this study, we investigated rheological properties of commercial polymers, SBC (Styrene-Butadiene Copolymers, K-resin KK38) and SBS (Styrene- Butadiene-Styrene, KTR 101 and KTR 301). In time sweep test, the rheological properties ($G^{\prime}$, $G^{{\prime}{\prime}}$, ${\eta}^*$) of SBS at 155 and $170^{\circ}C$ display almost constant value as a function of time from 0 s to 1800 s. On contrast, the rheological properties of SBS at 185 and $200^{\circ}C$ exponentially increase as a function of time. It could be due to gelation of SBS at high temperature conditions. These increment of rheological properties are not observed in SBC. From LAOS (large amplitude oscillatory shear) test, the nonlinear rheological properties of SBS at 155 and $200^{\circ}C$ after 1800 s are compared. The nonlinear rheological properties at $155^{\circ}C$ show simple strain thinning behavior such as linear homopolymer, however, the nonlinear rheological properties at $200^{\circ}C$ show 2 times strain thinning behavior (Payne effect). It well match with the gelation of SBS at $200^{\circ}C$. From rheological studies, it is confirmed that the proper polymer matrix for MIF process (low rheological properties at initial time and high rheological properties after process) is SBS KTR 301.

Improving Light Stability of Natural Rubber Latex Foam

  • Shim, Chang Su;Oh, Jeong Seok;Hong, Chang Kook
    • Elastomers and Composites
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    • v.50 no.2
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    • pp.81-86
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    • 2015
  • In this study, natural rubber latex foam was prepared in order to replace commercialized polyurethane foams as a car seat material. Physical properties of the latex foam were investigated and the light stability was improved. The latex foam was mixed in an aqueous solution state, and the degree of foaming and the accelerator ratios were appropriately controlled. Tensile properties, hysteresis and dynamic mechanical properties of the latex foam were measured to compare with those of polyurethane foams. UV light absorbers and radical scavengers were added for improving light stability of the latex foam. Xenon lamp test was conducted to investigate the effects of the reagents on light stability. Our results revealed that the prepared latex foam including a light absorber with an antioxidant showed excellent light stable performances.