• 제목/요약/키워드: chemical facility

검색결과 380건 처리시간 0.022초

연구실 사고분류 체계 개발 (Development of Accident Taxonomy for Experimental Laboratory)

  • 박교식
    • 한국안전학회지
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    • 제31권5호
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    • pp.49-53
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    • 2016
  • The goal of this study is to analyze accidents occurred at experimental laboratory and to suggest hierarchical taxonomy applicable to prepare countermeasures reducing the experimental laboratory accidents. Recent 5 years accidents were analyzed and classified according to their primary cause, facility or human. Then in case of facility, the accidents were further classified whether they can be fixed by organization or by individual. In case of human factor, they were classified into physical, chemical, or biological to prepare precise measures. Depending on the adequacy of appropriate practice, several measures were suggested such as; whether to improve training of laboratory workers, or to improve training the system, or to improve or prepare practice substantially. A new taxonomy for laboratory accident was suggested complying other governmental agencies' classification such as KOSHA and KGS. Additionally, two kinds of possibilities were suggested such as possibility of major accident and possibility of disaster which can be defined as laboratory accident causing large scale of harmful consequence to residential area or environment by fire, explosion and/or toxic release of hazardous chemicals and/or microbiology.

Effect of Temperature on the Adsorption and Desorption Characteristics of Methyl Iodide over TEDA-Impregnated Activated Carbon

  • Park, Geun-Il;Kim, In-Tae;Lee, Jae-Kwang;Ryu, Seung-Kon;Kim, Joo-Hyung
    • Carbon letters
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    • 제2권1호
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    • pp.9-14
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    • 2001
  • Adsorption and desorption characteristics of methyl iodide at high temperature conditions up to $250^{\circ}C$ by TEDA-impregnated activated carbon, which is used for radioiodine retention in nuclear facility, was experimentally evaluated. In the range of temperature from $30^{\circ}C$ to $250^{\circ}C$, the adsorption capacity of base activated carbon decreased sharply with increasing temperature but that of TEDA-impregnated activated carbon showed higher value even at high temperature ranges. Especially, the desorption amount of methyl iodide on TEDA-impregnated carbon represented lower value than that on unimpregnated carbon. The breakthrough curves of methyl iodide in the fixed bed packed with base carbon and TEDA-impregnated activated carbon at high temperature were compared. TEDA-impregnated activated carbon would be applicable to adsorption process up to $150^{\circ}C$ for the removal of radioiodine in a nuclear facility.

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유해화학물질 누출궤적 평가모듈 개발을 통한 화학공장 방류벽 높이의 적정성 평가 (Appropriateness Assessment of Dike Height of a Chemical Plant through Development of a Hazardous Chemical Leakage Trajectory Evaluation Module)

  • 유병태;김형기
    • 한국화재소방학회논문지
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    • 제33권4호
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    • pp.121-129
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    • 2019
  • 정부는 2015년 보다 체계적이고 안전하게 화학물질을 관리하고 취급 할 수 있도록 법 제명 변경과 함께 「화학물질관리법」을 전부개정 하였으며, 특히 유해화학물질을 제조·저장·보관하는 취급시설의 설치 및 관리 기준을 대폭 강화하였다. 하지만, 일부 취급시설 기준의 경우 물리적인 공간부족과 시설개선과정 중 사고발생우려 등의 이유로 강화된 기준을 이행하기 어려운 상황이 생김에 따라 이러한 시설에 대해 2018년부터 "안전성평가"라는 특례를 운영하고 있다. 본 연구에서는 유해화학물질 누출궤적 평가모듈 개발을 통해 현장에 설치된 염산과 황산 저장탱크의 방류벽 높이 적정성을 검증하고 이격거리에 따른 방류벽 높이를 제시하였다. 이를 활용하여 산업현장에서는 보다 손쉽게 해당 취급시설의 안전성 평가 특례신청이 가능할 것으로 판단된다. 또한, 본 연구의 결과는 유해화학물질 취급시설의 설계에도 활용하여 유해화학물질 취급시설의 안전성 향상에 기여할 것으로 기대된다.

화학물질관리법상의 유해화학물질 안전관리 개선방안 연구 : 안전성평가 사례 중심 (Development on the Safety Management System of Hazardous Chemicals under the Chemicals Control Act: Focusing on Safety Assessment System)

  • 유병태;이은별;김종구
    • 한국안전학회지
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    • 제34권3호
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    • pp.96-101
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    • 2019
  • Chemicals Control Act have been strengthened to control more safely hazardous chemicals from 2015. In particular, the standards for the installation and management of handling facilities was enhanced with specific regulations depending on type of the facilities and the hazardous chemicals. However, some standards for handling facilities caused difficulties in implementing the strengthened standards due to various field conditions, such as lack of physical space. The Ministry of Environment is implementing Safety Assessment System (SAS) to solve these problems since 2018. However, many plants have difficulties in preparing alternative methods to pass the safety evaluation. The purpose of this study was to review and analyze the SAS and to suggest alternative measures in terms of management and technical aspects through the case study of hydrochloric acid storage tanks. The following safety solutions were suggested for handling facilities that had insufficient the space and capacity for the retaining wall due to physical space. Firstly, insufficient space was resolved by introducing equipment relocation or demolition, and retaining wall expansion. Secondly, the wall of the surrounding buildings was used as an alternative to the retaining wall with additional chemical resistant treatment. Finally, sensor installation and facility inspection were suggested as ways to improve chemical safety. Therefore, improvement of chemical accident prevention system is required not only in terms of facilities supplementation but also management aspect. The results of this study are expected to be available for similar facilities and will be based on the preparation of additional safety assessment as alternatives measures in the future.

고에너지물질 비군사화 시설의 후처리 공정 모사 및 열교환기 합성망을 이용한 에너지 최적화 (Simulation and Process Optimization of High Energetic Materials Demilitarization Facility Gas Treatment Process)

  • 황래문;김현수;오민;문일
    • 한국군사과학기술학회지
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    • 제24권1호
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    • pp.79-83
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    • 2021
  • The expiration date of high energetic materials(HEM), such as HMX, RDX, TNT, is important. If the expiration date is violated, the expected specification of HEM would not be satisfied which may cause a different conclusion in an urgent situation. As a result, this HEM should maintain fresh conditions which cause the accumulation of waste HEM. If HEM is landfilled during demilitarization, the impact on living organizations is serious. Additionally, landfilling HEM has a possibility of explosion. In this research, the process flow diagram of the demilitarization gas treatment process was simulated while satisfying the law of the environment in Korea. After validation of simulation, it was optimized thermodynamically using Heat Exchanger Network Synthesis(HENs). This study is expected to enhance the energy efficiency of the original facility by suggesting developed designs. This research was supported by Agency of Defense Development NE32 Korea. Thanks to Agency of Defense Development, Korea

실규모 연속유입간헐폭기 공정(ICEAS)에서 최적운전조건이 경제성에 미치는 영향 (Economic implications of optimal operating conditions in a full-scale continuous intermittent cycle extended aeration system (ICEAS))

  • 정용재;최윤성;이승환
    • 상하수도학회지
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    • 제38권1호
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    • pp.29-38
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    • 2024
  • Wastewater management is increasingly emphasizing economic and environmental sustainability. Traditional methods in sewage treatment plants have significant implications for the environment and the economy due to power and chemical consumption, and sludge generation. To address these challenges, a study was conducted to develop the Intermittent Cycle Extended Aeration System (ICEAS). This approach was implemented as the primary technique in a full-scale wastewater treatment facility, utilizing key operational factors within the standard Sequencing Batch Reactor (SBR) process. The optimal operational approach, identified in this study, was put into practice at the research facility from January 2020 to December 2022. By implementing management strategies within the biological reactor, it was shown that maintaining and reducing chemical quantities, sludge generation, power consumption, and related costs could yield economic benefits. Moreover, adapting operations to influent characteristics and seasonal conditions allowed for efficient blower operation, reducing unnecessary electricity consumption and ensuring proper dissolved oxygen levels. Despite annual increases in influent flow rate and concentration, this study demonstrated the ability to maintain and reduce sludge production, electricity consumption, and chemical usage. Additionally, systematic responses to emergencies and abnormal situations significantly contributed to economic, technical, and environmental benefits.

A STUDY ON DEGREASING DETERGENT AND METHOD FOR THE IPP TEST FACILITY

  • Kim Yong-Wook;Lee Jung-Ho;Kang Sun-Il;Kim Sang-Heon;Oh Seung-Hyub
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2004년도 한국우주과학회보 제13권2호
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    • pp.262-265
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    • 2004
  • As a cryogen, LOx is a light blue, odorless, transparent liquid. Also it is not shock sensitive and does not decompose. However, it is a strong oxidizer and will vigorously support combustion. Therefore all harmful contaminants (such as grease, oil, fingerprint and organic materials) that could cause malfunctions, fires, or explosions in a oxygen environments must be completely removed prior to the introduction of oxygen. Especially, grease ingredient located inside of the LOx supply line, pipe and PHS (Pneumo-Hydraulic System) part can make drastic chemical reaction with oxygen. Therefore, to protect rapid reaction such as explosion, grease ingredient must be surely eliminated by a regular and irregular degreasing. Study on the availability, effectiveness and selection of degreasing detergents and method is described in this paper, and it will be useful for the construction and management of IPP test facility.

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화학물질 안전관리 시설기준 합리화 연구 : 방류벽 중심 (A Study of the Rationalization of Handling Facility Safety Management Standard for Hazardous Chemicals : Focusing on Dike)

  • 김남석;유병태
    • 한국가스학회지
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    • 제24권2호
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    • pp.29-35
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    • 2020
  • 화학사고의 예방 및 대응을 위한 화학물질관리법이 2015년 전부 개정되었다. 이를 계기로 유해화학물질 취급시설의 설치 및 관리기준도 상당히 강화되었다. 하지만, 일부 기존시설의 경우 시설기준 준수가 어려운 쉽지 않은 경우가 발생하지만 일괄적으로 적용되고 있어 산업계에서는 어려움을 호소하고 있는 실정이다. 본 연구에서는 이러한 최근 2년(2017-2018)간 취급시설 중 민원(1,087건)이 가장 많았던(2017:117건, 2018:83건) 방류벽에 대한 선행연구, Flacs 시뮬레이션, 국내·외 기준, 만족도 조사 등을 통해 보다 합리적인 방안을 마련하고자 하였다. 이에 현재 가동 중인 기존시설에 한하여 방류벽의 설치 목적을 고려하여 화학물질 유·누출을 신속하게 감지할 수 있고 신뢰성을 높이기 위해 감지기를 추가로 설치하거나 상시 모니터링이 가능한 폐쇄회로텔레비전(CCTV)을 추가로 설치·운영하는 경우 추가 대체방안으로 인정하였다. 이는 부지를 확보하기 힘들거나, 공사비용 등 경제적인 문제로 법적인 규제를 이행하지 못하는 영세사업장 또는 중소기업의 안전측면과 비용적인 측면에 도움이 될 것이다.

다중이용시설 화학테러에 대비한 관리방안 연구 (Study on the Management Plan for the Preparation of Chemical Terrorism in Multi-use Facilities)

  • 윤성용;김시국;홍성철
    • 한국화재소방학회논문지
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    • 제33권2호
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    • pp.68-78
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    • 2019
  • 현대 사회는 과거의 테러성향과는 다른 불특정 다수를 대상으로 하는 소프트 타깃의 형태로 테러의 패러다임이 전환되고 있으며 화학물질을 이용한 테러가 빈번하게 일어나고 있다. 이에 본 연구에서는 다중이용시설에 국한하여 피난환경 및 특성, 테러대응 매뉴얼 분석, 국내 화학물질 관리 현황을 분석하여 다중이용시설 화학테러 대비를 위해 다음과 같은 관리방안을 제안하였다. 첫째, 복잡한 다중이용시설 공간에 대비하여 테러발생 시 신속한 현장대응을 할 수 있도록 다중이용시설의 정보를 사전에 파악할 수 있는 가이드라인을 제시하고 등급에 따른 관리를 제안하였다. 둘째, 테러대응 매뉴얼의 취약점을 분석하고 화학테러의 유형 및 특성을 사전에 파악하여 화학테러에 신속한 대응을 할 수 있도록 화학테러에 사용할 가능성이 있는 물질들을 선별하는 방안을 제안하였다. 셋째, 선별된 화학물질을 대상으로 사회적 관심물질과 같은 용어제정을 통해 통합 관리해야하는 필요성을 제안하였다. 이를 통해 다중이용시설 화학테러 대비를 위한 개선방안이 추가적으로 마련될 것으로 보여 지며, 추후 국외 사례를 통한 문제점 분석과 이를 통한 맞춤형 대책을 강구해야 할 것으로 사료된다.

백화점 내 업종별 판매매장에 따른 오염물질 배출현황 평가 (Evaluation of Pollutants Emissions according to the Selling Store in Department Store)

  • 왕형석;황준석;장성진;김수민
    • 한국가구학회지
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    • 제26권1호
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    • pp.71-76
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    • 2015
  • It is important thing that air quality affects human health. And It is more important thing that Indoor Air Quality more affects human health than Outdoor Air Quality. The cause of that is indoor air pollutants are more absorbed than outdoor air pollutants. By the way, in case of Multi-use facility for example office, department store, school etc., it has a feature that there are more people than any other buildings. therethrough, effects of Indoor Air Quality of Multi-use facility affect more people's health than Indoor Air Quality of any other buildings. However, in multi-use facility, specifically retail store, chemical treated materials are used for interior finishing, showcase finishing and product finishing because esthetic element is more added for detention of customer. Consequently, in place where demands brisk sales, possibility that indoor air is polluted by VOCs is high. This study considered retail store's Indoor Air Quality. as result of experiment, figure of department store's air pollution exceed about 5~20 times in guideline of multi-use facility's Indoor Air Quality in any kind of shop of department store (guideline : $500{\mu}g/m^3$).