• Title/Summary/Keyword: chemical elements

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Utilization of Wood by-product and Development of Horticultural Growing Media (임산부산물을 이용한 원예용 혼합상토 개발)

  • Jung, Ji Young;Lim, Ki-Byung;Kim, Ji Su;Park, Han Min;Yang, Jae-Kyung
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.435-442
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    • 2015
  • The main objective of this work was to identify and evaluate possible substrate alternatives or amendments to peat moss. This study involves the physical and chemical characterization and growth test of wood sawdust and wood fiber in order to evaluate their use as components of horticultural media. The carbohydrate content, C/N ratio, pH, phenolic compound, total porosity and water holding capacity were 58.9%, 425.1, 4.8, 181.8 ($mg{\cdot}g^{-1}$), 82.5% and 47.1% in wood sawdust and 41.1%, 240.8, 5.9, 29.8 ($mg{\cdot}g^{-1}$), 90.6% and 56.2% in wood fiber, respectively. Wood sawdust (K, $998.0mg{\cdot}100g^{-1}$ ; Ca, $1196.0mg{\cdot}100g^{-1}$; Mg, $105.6mg{\cdot}100g^{-1}$) and wood fiber (K, $1250.1mg{\cdot}100g^{-1}$; Ca, $1982.6mg{\cdot}100g^{-1}$; Mg, $173.1mg{\cdot}100g^{-1}$) showed adequate mineral elements properties compared to peat moss (K, $0.02mg{\cdot}100g^{-1}$; Ca, $0.57mg{\cdot}100g^{-1}$; Mg, $0.13mg{\cdot}100g^{-1}$) for their use as growing media. The mixtures of the horticultural media were prepared using different substrate as wood sawdust and wood fiber to grow Chinese cabbage (Brassica campestris L.) in a greenhouse. The seed germination, leaf area and stem height were 75%, $0.50cm^2$ and 2.8 cm in PS substrate (containing 30% peat moss, 10% perlite and 60% wood sawdust) and 95%, $0.65cm^2$ and 3.3 cm in PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber), respectively. The seed germination and stem height of the PF substrate (containing 30% peat moss, 10% perlite and 60% wood fiber) was higher than those in peat moss (control). Utilization of wood by-product can be considered as an alternative media component to substitute the widely using expensive peat moss.

Origin of B, Br and Sr in Groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, with Emphasis on Hydrochemistry (지하수의 수질화학적 특징과 붕소, 브롬, 스트론튬 성인에 대한 고찰)

  • Choo, Chang-Oh;Lee, Jin-Kook;Lee, Chang-Joo;Park, Ki-Ho;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.235-250
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    • 2009
  • Environmental elements such as B, Br, and Sr in groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, were investigated in order to know their origin with emphasis on hydrochemistry. pH ranges from 7.37 to 8.39. B content is 0.41${\sim}$4.62 mg/L with an average 1.74 mg/L and Br content is 0${\sim}$3.24 mg/L with an average 2.22 mg/L, and Sr content is 0.93${\sim}$8.64 mg/L with an average 2.76 mg/L. The water types plotted by the Piper diagram are different but mostly $Ca-HCO_3$. Some constituents contributing to EC are Na, $SO_4$, Cl with high determinative coefficients($R^2$) of 0.85, 0.70, 0.90, respectively. The coefficients($R^2$) of Cl to Na, K, $SO_4$ are 0.54, 0.68, 0.53, respectively. It should be noted that there are high cocfficients($R^2$) of B-Sr and $Sr-SO_4$ with 0.65, 0.64, respectively. The Cl/Br ratios are 5.21${\sim}$30.70 due to significant depletion of Cl. The $SO_4/Cl$ ratios are 1.32${\sim}$27.24 with an average of 5.92, ascribed to abundant introduction of $SO_4$ or significant depletion of Cl. Chemical speciation calculated shows that B exists mostly as $H_3BO_3$ with less $H_2BO^-_3$ and Br exists as only $Br^-$. Sr exists mostly as $Sr^2$ with less $SO_4$. Saturation index represents that goundwater is supersaturated with respect to barite, kaolinite, illite, K-mica, and smectite while it is slightly undersaturated with respect to silica, gypsum, anhydrite, talc, chrysotile, feldspar, kaolinite, illite, K-mica, and smectite. The saturation index of celestine is -2.23${\sim}$-0.13 indicating more Sr can be incorporated into groundwater. Groundwater is still much undersaturated to halite. It is likely that the origin of S and Sr was related to the Yucheon volcanic rocks. Br might be originated from the local geological features with introduction of anthropogenic matters.

Mineralogy and Genesis of Hydrothermal Deposits in the Southeastern Part of Korean Peninsula : (5) Deogbong Napseok Deposit (우리나라 동남부 지역의 열수광상에 대한 광물학적 및 광상학적 연구:(5) 덕봉납석광상)

  • Kim, Soo-Jin;Choo, Chang-Oh;Kim, Won-Sa
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.25-39
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    • 1994
  • The Deogbong napseok clay deposit which is composed mainly of dickite and pyrophyllite has been formed by hydrothermal alteration of the Late Cretaceous volcanic rocks consisting of andesitic tuff and andesite. The mineralogy of the napseok ores and the hydrothermal alteration processes have been studied in order to know the nature of the interaction between minerals and fluids for the formation of the deposit. Chemical distribution shows that alkali elements and silica were mobile but alumina was relatively immobile during the hydrothermal processes. It is evident that enrichment of alumina and leaching of silica from the host rock led to the formation of the napseok ore, whereas the enrichment of silica in the outer zone of the deposit gave rise to the silica zone. A large amount of microcrystalline quartz closely associated with dickite and pyrophyllite suggests the increasing activity of silica. Thus Si which was released away from the argillic zone by the increasing activity of silica. Thus Si which was released away from the argillic zone by the increasing activity of silica solubility moved out precipitating in the margin of the deposit to form the silica zone. Variation in dickite crystallinity implies the local change in the stability of the system. Thermodynamic calculation shows that the invariant point of pyrophyllite-dickite (kaolinite)-diaspore-quartz assemblages at 500 bars in the system $Al_{2}O_{3}-SiO_{2}-H_{2}O$ is about 300 $^{\circ}C$. Based on the mineral assemblages and the experimental data reported, it is estimated that the main episode of hydrothermal alteration occurred at least above 270 to 300 $^{\circ}C$ and $X_{CO_2}$ <0.025. Mineral occurrence and chemical variation indicate that the activity of Al is high in the upper part of the deposit, whereas the activity of Si is high in the lower part and the margin of the deposit. The nonequilibrium phase relations observed in the Deogbong deposit might be due to local change in intensive thermodynamic variables and fluid transport properties that resulted in the formation of nonequilibrium phases b of several stages.

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Characteristics and Distribution Pattern of Carbonate Rock Resources in Kangwon Area: The Middle Carboniferous Yobong Formation in the Northern Part of Yeongwoleup, Kangwon, Korea (강원 지역에 분포하는 석회석 자원의 특성과 부존환경: 영월읍 북부 지역의 중기 석탄기 요봉층을 중심으로)

  • Park, Soo-In;Lee, Hee-Kwon;Lee, Sang-Hun
    • Journal of the Korean earth science society
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    • v.21 no.5
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    • pp.583-594
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    • 2000
  • The Middle Carboniferous Yobong Formation with North-South trending is distributed in the Yeongheungri and Samokri of Yeongwoleup, Kangwon Province, Korea. A light gray thick and massive pure limestone is developed in the middle part of the Yobong Formation and it has been exploited for a long time. This study was carried out to investigate the lithological characteristics and geochemical compositions of the limestones and to figure out how geologic structures control the disribution of the limestones of the formation. The limestones of the Yobong formation are characterized by the fine and dense textures and the light gray to light brown in color. The limestones are composed of crinoid fragments, small foraminifers, fusulinids, gastropods, ostracods, etc. Based on the amount of grains and matrix, the Yobong Limestone can be classified as fine packstones and wackestones. The chemical analysis of limestones of the Yobong Formation was carried out to measure the contents of CaO, MgO, Al$_2$O$_3$, Fe$_2$O$_3$ and SiO$_2$. The content of CaO ranges from 48.12 to 59.31% and its average is about 54.52%. The average content of MgO is about 0.32% and the coutents of Al$_2$O$_3$, Fe$_2$O$_3$ and SiO$_2$ are relatively low. The amounts of Al$_2$O$_3$, Fe$_2$O$_3$ and SiO$_2$ of the limestones vary according to the kinds of limestone and their stratigraphical horizons in the formation. Generally, the CaO content of the limestones of the Yobong Formation decreases towards the top of the formation. Using geometric and structural analysis, we determined five progressively overprinted phases of deformation recorded in the study area. The anticline and syncline formed during the first and fourth deformation had controlled the distribution pattern of the Yobong Limestone of the Yobong Formation. The structures of deformation D$_1$ consist of F$_1$ isoclinal folds and foliations. The D$_2$ deformation had formed the isoclinal interstratal F$_2$ folds and axial plane cleavages which are locally developed within mudstones. The structural elements of deformation D$_3$ are axial plane cleavages associated with recumbent F$_3$ folds. These structures are overprinted by meso-scale and regional F$_4$ folds which are regionally dominant. Finally, the structures of D$_5$ consist of the thrust faults and folds associated with the thrust faults.

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Establishment of an Ice Core Processing Method and Analytical Procedures for Fundamental Proxies (빙하코어의 전처리 방법 및 기초 프록시 분석법 확립)

  • Jun, Seong Joon;Hong, Sang Bum;Hur, Soon Do;Lee, Jeonghoon;Kang, Jung-Ho;Hwang, Hee Jin;Chung, Ji Woong;Jung, Hye Jin;Han, Changhee;Hong, Sungmin
    • Ocean and Polar Research
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    • v.36 no.1
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    • pp.13-24
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    • 2014
  • We established the first complete ice core processing method and analytical procedures for fundamental proxies, using a 40.2 m long ice core drilled on the Mt. Tsambagarav glacier in the Mongolian Altai mountains in July 2008. The whole core was first divided into two sub ice core sections and the measurements of the visual stratigraphy and electrical conductivity were performed on the surface of these sub core sections. A continuous sequence of samples was then prepared for chemical analyses (stable isotope ratios of oxygen ($^{18}O/^{16}O$) and hydrogen ($^2H/^1H$), soluble ions and trace elements). A total of 29 insoluble dust layers were identified from the measurement of visual stratigraphy. The electrical conductivity measurement (ECM) shows 11 peaks with the current more than 0.8 ${\mu}A$ Comparing the profiles of $SO_4{^{2-}}$ and $Cl^-$ concentrations to correlate with known volcanic eruptions, the first two ECM peaks appear to be linked to the eruptions (January and June 2007) of Kliuchevskoi volcano on the Kamchatka Peninsula of Russia, which supports the reliability of our ECM data. Finally, the composition of stable isotopes (${\delta}^{18}O$ and ${\delta}D$) shows a well-defined seasonal variation, suggesting that various chemical proxies may have been well preserved in the successive ice layers of Tsambagarav ice core. Our ice core processing method and analytical procedures for fundamental proxies are expected to be used for paleoclimate and paleoenvironmental studies from polar and alpine ice cores.

Chemical Composition and Physiological Activity of Opuntia ficus-indica depending on Different Cultivation Regions (재배지역별 보검선인장 줄기의 영양성분 및 생리활성 평가)

  • Lee, Sang Hoon;Jeong, Yun Sook;Song, Jin;Hwang, Kyung-A;Noh, Geon Min;Hwang, In Guk
    • The Korean Journal of Food And Nutrition
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    • v.29 no.4
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    • pp.521-528
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    • 2016
  • This study was conducted to investigate changes in the proximate composition, antioxidant activities, and ${\alpha}$-glucosidase inhibitory activity of Opuntia ficus-indica (OFI) cladodes cultivated in Jeju (JJ1, JJ2, JJ3) and Jeonnam (JN1, JN2). The difference in the proximate composition (crude protein, lipid and ash content) of OFI between the two regions was not significant. Ca, Mg and Na were the major mineral components of OFI. The ascorbic acid content of OFI ranged from 57.87 to 143.72 mg/100 g. A 70% ethanol extract was used to investigate the antioxidant content and activity as well as the ${\alpha}$-glucosidase inhibitory activity. The total polyphenol and flavonoid contents of OFI were 38.69~55.29 and 3.33~4.03 mg/g, respectively. The antioxidant activities based on the DPPH and ABTS free radical scavenging assays were 45.19~61.52% and 39.15~51.96%, respectively, at a concentration of 1 mg/mL. The inhibitory activity of OFI extracts against rat intestinal ${\alpha}$-glucosidase was 29.72~45.73% at 1 mg/mL concentration, and JN1 showed the highest ${\alpha}$-glucosidase inhibitory activity. This information could be very useful for authentication of Opuntia species with the highest potential as sources of nutritional and therapeutic elements.

Physio-Chemical Characteristics of Soil, Stream Sediment and Soil Water Contaminated by the Abandoned Coal Mine in Keumsan, Chungnam (충남(忠南) 금산(錦山) 폐탄광지역(廢炭鑛地域)의 토양(土壤), 하상퇴적물(河床堆積物) 및 토양수(土壤水)의 이화학적(理化學的) 특성(特性))

  • Min, Ell Sik;Kim, Myung Hee;Song, Suckhwan
    • Journal of Korean Society of Forest Science
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    • v.86 no.3
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    • pp.324-333
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    • 1997
  • The research has been made for the effects of the pollution by the abandoned coal mine drainage on the physical and chemical properties of soil, stream sediment and soil water. The soils overspreaded by the abandoned coal don't develop solum and the bulk density is $1.83g/m^3$, compared with $1.14-1.38g/m^3$ in the other forest soils. The soil pH range in coal bearing region ie, from 4.01 to 4.11 and non-coal bearing soil range is from 5.03 to 5.13. Heavy metals such as As, Cr, Ni, Mo and Ba of coal bearing soils and polluted stream sediments have larger concentration than those of non-coal content and non-polluted. Especially As and Mo concentrations are largely high in coal bearing. The relative ratios $K_2O/Na_2O$ of geochemical elements are higher in coal bearing soil and polluted stream sediments than those of non-coal bearing soils and non-polluted stream sediments as well as black shales of the Changri Formation. However, $MgO+Fe_2O_3+TiO_2/CaO+K_2O$ are the opposite trends, so that the ratios are lower in the polluted regions. The soil water pHs in the polluted regions are the strong acid(pH3.4-4.2) and buffer capacity of the polluted soil is low because canons such as $Na^+$, $K^+$, $Mg^{+2}$are leached by the acidification.

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On the Components of Edible Marine Algae in Korea -I. The Components of Several Edible Brown Algae- (한국산(韓國産) 식용(食用) 해조류(海藻類)의 성분(成分)에 관(關)한 연구(硏究) -I. 수종(數種) 식용(食用) 갈조류(褐藻類)의 구성(構成) 성분(成分)에 대(對)하여-)

  • Lee, In-Kyu;Shim, Sang-Chil;Cho, Han-Ok;Rhee, Chong-Ouk
    • Applied Biological Chemistry
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    • v.14 no.3
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    • pp.213-220
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    • 1971
  • In order to investigate chemical components of edible marine algae in Korea, the present work is carried out with ten edible and two non-edible species of brown algae, collected from Cheju-island during October, 28-30 in 1970. Among the general components, water content is about 14-16% to dry weight and the crude protein about 16%, which are almost similar in content compared with several non-cultivate edible land plants. The content of crude fat is about 0.7-2.0%, and that of crude fiber about 3-8%, while the content of crude ash is 9.17-16.89%. The last one is more than two times in content compared with the land plants. The reducing sugar is about 0.27-2.49% in general. On the other hand, among the minerals Ca content is the most abundant, 1.73-2.51%, and the next is S, 1.0-1.8%. Mg and I are around 0.1-1%, while K and Na are about 1% in content. Among the micro-elements, Fe and Zn are about 0.01-0.03%, and Cu and Mn 0.001-0.005% in content. There is no special significant difference in chemical components between the edible and non-edible species of brown algae. Moreover, so far as the present investigation is concerned, there can be found no significant inter-species relationship on the taxonomical or phylogenetical points of view, considering their components.

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Mineralogical Studies of the Tourmaline for Medicinal Applications by Production Localities (본초 광물로서의 활용을 위한 산지별 전기석의 광물학적 연구)

  • Jie, Yan;Kim, Seon-ok;Park, Hee Yul;Park, Maeng-Eon
    • Economic and Environmental Geology
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    • v.51 no.4
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    • pp.345-358
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    • 2018
  • In this study, we have performed electron probe micro analyzer (EPMA), X-ray differaction (XRD), inductively coupled plasma spectroscopy (ICP), Fourier transform Raman spectroscopy (FT-Raman), far-infrared (FIR), nuclear magnetic resonance (NMR), and pH-DO Analyses for characterizing medicinal mineralogy aspect of the black tourmaline (Shantung, china), black and pink tourmaline (Minas Geraris, Brazil), black touemaline (Daeyu mine, Korea). In addition, heating effects of the tourmaline sauna as well as the effects of tourmaline powder-added soap on skin troubles have been investigated. It has been revealed that chemical composition of the tourmaline is either high in Fe-, Al-, B-rich types. Ratio of the K-Ca, Na-K, and Fe-B reflects the component change property of solid solution. $CaO/CaO+Na_2O$ and MgO/FeO+MgO ratio show high positive correlation. When tourmaline reacts with distilled water, extended reaction time DO values approximately decrease and it stabilizes at DO = 10. Otherwise, pH values increase until 6 hours and it stabilizes at pH = 8 after 24 hours. Distilled water changes to alkaline when it reacts with tourmaline powder and particles. Tourmaline showed lower absorption spectrum strength and transmittance at short wave, where absorption spectrum wavelength and strength were determined by the content of the composition elements and characteristics of crystallography. Increase of the Fe content has been confirmed to be the cause for the reduction of irradiation. For the chemical composition and spectral property of the tourmaline particle samples, it has been found that Si and Fe contents show positive correlation with Far-Infrared irradiation, while Al and Mg contents show negative correlation. For tourmaline powder, it has been confirmed that $^{17}O-NMR$ FWHM (full width at half maximum) decreases when reacts with distilled water. Tourmaline sauna (approximately $100^{\circ}C$) was found to increase $0.5-1.5^{\circ}C$ of body temperature, average of 12 heartbeat, and 10mg Hg of blood pressure. Tourmaline soap had very good aesthetic effect to skin and was confirmed to have above the average improvements to skin troubles (e.g., allergy or atopy).

A Preliminary Study on Stratigraphy and Petrochemistry of the Okcheon Group, Southwestern Okcheon Metamorphic Belt (서남 옥천변성대 옥천층군의 층서 및 암석화학에 대한 예비연구)

  • 유인창;김성원;오창환;이덕수
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.511-525
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    • 2003
  • The Okcheon Group in the southwestern part of the Okcheon Metamorphic Belt is subdivided into two distinct tectonostratigraphic units: the Boeun unit in the south and the Pibanryeong unit in the north. The Boeun unit consists of petites, psammites, carbonaceous petites, limestones and pebble-bearing quartzites. The Pibanryeong unit is composed of petites, well-sorted fine-grained psammites, carbonaceous psammites and quartzites. In order to outlining stratigraphy and depositional environments of the Okcheon Group, detailed stratigraphic sections were measured in three locations; one section(Gosan section) of the Boeun unit and two sections(Sorungjae and Hwangryeongzae sections) of the Pibanryeong unit. The Gosan section of the Boeun unit is interpreted to be deposited in the shallow marine environments, whereas the Sorungjae and Hwangryeonaiae sections of the Pibanryeong unit appear to be deposited in slope and deep basin environments. This result indicates rapid subsidence between deposition of the Boeun and Pibanryeong units in sedimentary environment. The trace of sedimentological environments in the Hwasan area was investigated by geochemical analysis of 109 metapelitic and psammitic rock samples. Distinct chemical variations of politic and psammitic rocks from the Boeun and Pibanryeong units in the study area are evident from plots of major elements and $A1_2O_3$/$SiO_2$ versus Basicity Index($Fe_2O_3{+}MgO$)/($SiO_2{+}K_2O{+}Na_2O$). The rocks show a progressive chemical trend from the Boeun unit to the Pibanryeong unit on these diagrams. They in the southern sector of the Boeun unit display lower values and a comparatively wide range of $A1_2O_3$/$SiO_2$ and Basicity Index, as compared with those from the northern sector of the Boeun and Pibanryeong units. The southern sector of the Pibanryeong unit including narrow staurolite-bearing zone is characterized by values that are transitional between the Boeun and Pibanryeong units. These data, combined with depositional environment progressively deepened towards the northwest, support a half-graben model for the Okcheon basin, as proposed by Cluzel et al.(1990)