• 제목/요약/키워드: chemical elements

검색결과 1,274건 처리시간 0.029초

Alkali-Swollen Morphology of Native Cellulose Fibers

  • Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • 제35권2호
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    • pp.16-22
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    • 2007
  • The behavior of ramie fibers and some wood elements in the early stage of alkali swelling was examined. When the fibers were treated with alkali solution, they significantly shrank in length and swelled in wall thickness. Ramie fibers showed a shrinkage averaging 23% in length and a swelling averaging 92% in width in 100 seconds treating time. Dimensional changes showed different fashion in each element of woods. The tracheids of latewood especially in Pinus densiflora and Larix kaempferi woods swelled intensively and showed balloon swelling, but in the case of Cryptomeria japonica, it was hardly observed. The swelling morphology of libriform fibers was similar to that of tracheids. The walls of vessel elements and parenchyma cells also swelled considerably in thickness but, no balloon swelling was found in both elements. The differences of swelling in different elements can be interpreted in terms of the differences of organization and/or chemical components of the cell walls.

Transport and Loadings of Nutrients and Dissolved Major and Trace Elements in the Yeongsan River, Korea

  • Cha Hyun-Ju;Cho, Yeong-Gil
    • Journal of the korean society of oceanography
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    • 제37권2호
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    • pp.66-75
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    • 2002
  • Temporal variation of nutrients and dissolved major and trace elements have been studied in the Yeongsan River, Korea. There were significant temporal fluctuations in the concentrations of these elements depending upon the flow condition. $NH_4$, $PO_4$, Na, Mg, Ca, K, Mn, Cu, Ni, Zn, Co, As and U concentrations were inversely related to the flow; that is, they are the highest at low flow and the lowest at high flow. It indicates that these elements are derived from point sources such as rock weathering and/or human activities and then diluted by increasing flow. Meanwhile, Fe and Si concentrations varied proportionally to the flow indicating that they are derived from diffuse sources including reactions within soil. The concentration-flow relationships showed that hydrology of the river is the most important factor controlling the chemical composition of the Yeongsan riverwater, which was compatible of the results of R-mode factor analysis.

인도네시아 반둥 남부 수방산지역에서의 토양지화학 탐사 (Soil Geochemical Exploration of the Mt. Subang Area of the Southern Part of the Bandung, Indonesia)

  • 김인준;이재호;이사로;서정률;김유봉;이규호
    • 자원환경지질
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    • 제37권2호
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    • pp.173-184
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    • 2004
  • 인도네시아 반둥 남부 수방산지역에 대하여 정밀토양지화학탐사를 실시하였으며, 정밀지표지질조사도 병행하였다. 정밀토양지화학탐사에서 채취한 토양시료의 화학분석 값은 Ag:11ppm(평균함량 : 1.91ppm), Au:548ppb(평균함량 : 42.39 ppb), Cu:89ppm(평균함량 : 51.40 ppm), Pb : 190ppm(평균함량 : 23.69 ppm), Zn: 157ppm(평균함량 :61.78ppm)이다. 또한 정밀토양지화학탐사를 실시하여 이들에 대한 화학분석치 결과와 통계처리를 한 결과 등 모든 데이터를 종합 분석한 결과, 연구지역 중동부지역에서 다원소 지화학이상대가 확인되었다.

팔라디움-은합금의 반복주조시 도재와 금속간의 화학적 결합에 관한 실험적 연구 (AN EXPERIMENTAL STUDY ON THE CHEMICAL BOND STRENGTH AT THE INTERFACE BETWEEN PORCELAIN AND SUCCESSIVELY RECAST PALLADIUM-SILVER CERAMIC ALLOY)

  • 김태균;이선형;양재호;정헌영
    • 대한치과보철학회지
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    • 제27권1호
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    • pp.31-47
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    • 1989
  • The purpose of this study was to evaluate the chemical bond strength of successively recast Pd-Ag ceramic alloys with porcelain and to investigate changes of quantity of trace elements at the metal-porcelain interface. Porcelain was fired as usual manner on the each successively recast specimen. Rectangular planar shear test was performed and bond strength was measured by Instron universal testing machine. Diffusion of trace elements at the each interface was observed by ESCA (Electron Spectroscopy for Chemical Analysis). The obtained results were as follows : 1. Chemical bond strength was significantly decreased after second recasting. But in case of first recasting, there was no significant decrease of bond strength statistically (p<0.05). 2. Bond strength was not significantly decreased in each generation, when fifty percents new alloy was added (p<0.05). 3. Ag, Sn and In were observed at the porcelain interface. But Pd was not observed. 4. The quantity of Ag, In ions were progressively increased at the metal-porcelain interface as the casting was repeated. Silver ion was most significantly increased.

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전북(全北) 전주지역(全州地域) 화강암(花崗岩) 및 낭산지역(郎山地域) 화강암(花崗岩)의 풍화(風化)에 따른 화학조성(化學組成)의 변화(變化)와 주요원소(主要元素)의 상대적이동(相對的移動) (Variation of Chemical Composition and Relative migration of major Elements in the Weathering of Jeon-Ju granite and Rang-San granite)

  • 남기상
    • 자원환경지질
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    • 제8권4호
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    • pp.211-221
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    • 1975
  • Weathering of granites has a geochemical role of great significance, because of their abundance and because of chemical instability near the surface of the earth, which is more pronounced than in most other rocks. On the other hand the granites are tectonically fragile and "react" to deformation with marked facility, giving rise to a whole gamut of deformed rocks. Therefore, the writer has studied on the weathering of granitic rocks at of Iri city and Jeonju city Jeollabukdo, Korea, The fresh and weathered rocks were used as material for the investigation. The results obtained by chemical analysis and observation are as follows. 1) The order of mobility in major elements was Ca, Na and K$H_2O$ was observed clearly and late stages of weathering processes. 3) The early stage of weathering is commenced by physical weathering and followed by chemical weathering. 4) The ratio of FeO/. $Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3 $ decreased uniformly from early to late stage of weathering processes. 5) It was proved that weathering potential of granite was larger than that of basaltic rocks.

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Review on sodium corrosion evolution of nuclear-grade 316 stainless steel for sodium-cooled fast reactor applications

  • Dai, Yaonan;Zheng, Xiaotao;Ding, Peishan
    • Nuclear Engineering and Technology
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    • 제53권11호
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    • pp.3474-3490
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    • 2021
  • Sodium-cooled fast reactor (SFR) is the preferred technology of the generation-IV fast neutron reactor, and its core body mainly uses nuclear-grade 316 stainless steel. In order to prolong the design life of SFRs to 60 years and more, it is necessary to summarize and analyze the anti-corrosion effect of nuclear grade 316 stainless steel in high temperature sodium environment. The research on sodium corrosion of nuclear grade 316 stainless steel is mainly composed of several important factors, including the microstructure of stainless steel (ferrite layer, degradation layer, etc.), the trace chemical elements of stainless steel (Cr, Ni and Mo, etc) and liquid impurity elements in sodium (O, C and N, etc), carburization and mechanical properties of stainless steel, etc. Through summarizing and constructing the sodium corrosion rate equations of nuclear grade 316 stainless steel, the stainless steel loss of thickness can be predicted. By analyzing the effects of temperature, oxygen content in sodium and velocity of sodium on corrosion rate, the basis for establishing integrity evaluation standard of SFR core components with sodium corrosion is provided.

황사발생지역에서 토양입자의 화학적 특성 (Soil Chemical Properties in Asian Dust Source region in Northern China)

  • 한진석;신선아;공부주;박문수;박순웅;김수진
    • 환경영향평가
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    • 제13권6호
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    • pp.277-284
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    • 2004
  • The chemical composition and properties of soil were determined at selected sites, such as Loess plateau, Gobi and sand deserts in northern China, where most dust storms occur. Although the transport of this sort of dust storms to Korean peninsula is a well-documented phenomenon, there is not enough information about the very source regions. In this reason, this study tried to measure the chemical composition, including soil elements, anthropogenic elements and ions for soil samples so that certain properties of some major source regions of Asian Dust can be provided. Furthermore, the results are classified into four types of soil like Loess, Loess & sand, Gobi, and sand in order to identify the characteristics and difference among the types. $(X/Al)_{crust}$ values for each soil type were also calculated in this study and compared with those of other references including Asian Dust material(ADM). The results indicated that Ca contribution was higher than Al in all the soil types of this study including ADM and, compared with the values of urban area, contribution of anthropogenic elements such as Cr, Pb, Zn was quite low. However, it must be noted that there is such a variation in the result of soil composition, but it is also certain that the very source region soil composition resolved from this study could support the enhanced study on Asian Dust phenomenon in Korea.

북부 미시간 지역에 분포하는 선캠브리아기의 염기성 암맥에 대한 지화학적인 연구 (Geochemistry of Precambrian Mafic Dikes in Northern Michigan, U.S.A.: Implications for the Paleo-Tectonic Environment)

  • 위수민
    • 자원환경지질
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    • 제24권4호
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    • pp.447-463
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    • 1991
  • 본 논문은 슈피리어호 남부에 분포하는 선캠브리아기의 염기성 암맥들에 대하여 마그마의 기원과 그들이 생성될 당시의 지구조적인 환경을 알기 위하여 암석 및 지화학적인 연구가 행하여 졌다. 46개의 시료에 대한 주성분, 미량원소 및 희토류 원소들에 대한 화학분석이 이루어졌다. 이들의 화학성분은 전형적인 콘티넨탈 쏠레아이트 (contiental tholeiite)의 성격을 띄우며, 다소 철성분이 부화된 분화경향을 나타낸다. 부동원소 (immobile element)들을 이용한 tectonic discrimination diagram 에 의하면 모 마그마는 현재의 T-type MORB와 유사한 Ti의 함량이 많은 쏠레아이틱(tholeiitic)현무암으로 사료된다. 분화가 진행될수록 암석의 화학적 성질은 지각과의 동화작용(crustral asimilation)에 의해 많은 영향을 받는 것으로 나타난다. 분화가 많이 진행된 암석들은 Rb, K, Ba, Th 과 같은 LIL원소의 증가를 보인 반면에 Nb, P, Ti과 같은 HFS 원소들은 그들과 물리, 화학적 성질이 비슷한 이웃한 원소들보다 현저한 감소를 나타내었다. 이러한 특징은 마그마의 기원에서 유래된 것 뿐만 아니라 지각과의 동화작용이 병행함으로 기인되었다고 사료된다. 이 암석들의 지화학적 특성을 살펴보면 지각의 섭입과 관련되어(subduction related)생성된 암석의 화학성분과는 현저한 차이를 나타내며, 판(板)내에서 생성된 현무암(Within plate basalt)과 해양지각에서 형성된 현무암 (MORB)에서 보이는 특성을 나타낸다. 이러한 지화학적인 특성을 살펴볼 때 이 암석들은 rifting과 같은 extensional tectonic 환경에서 생성된 것으로 사료된다.

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Lyotropic Chromonic Liquid Crystals: Effects of Additives and Optical Applications

  • Park, H.S.;Tortora, L.;Vasyuta, R.M.;Golovin, A.B.;Augustin, E.;Finotello, D.;Lavrentovich, O.D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.307-310
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    • 2007
  • We describe effects of ionic and neutral additives on phase and structural behavior of the lyotropic chromonic liquid crystals used in preparation of optical elements such as polarizers and compensators.

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Influence of Different A Elements on Bonding and Elastic Properties of Zr2AC (A = Al, Si, P, S): A Theoretical Investigation

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.609-614
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    • 2013
  • Extended H$\ddot{u}$ckel tight-binding band structure calculations are used to address the chemical bonding and elastic properties of $Zr_2AC$ (A=Al, Si, P, and S). Elastic properties are interpreted by analyzing the density of states and the crystal orbital overlap population for the respective phases. Our results show that the bulk modulus of these ternary compounds is determined by the strength of Zr-A bonds.