• 제목/요약/키워드: chemical elements

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현황분석을 통한 도시 소하천의 생태하천 계획요소에 관한 연구 -울산광역시 무거.여천천을 중심으로- (A Study on the Planning Elements for Ecological Restoration of Urban Stream through Present Condition Analysis - focused on the Yeocheon and the Mugeo stream -)

  • 김성철;이철영
    • 한국환경과학회지
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    • 제13권9호
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    • pp.747-757
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    • 2004
  • The objectives of this study were to investigate the physical, chemical, and structural characteristics of the stream, especially Mugeo and Yeochon which are being changed to ecological stream by Ulsan city, and to acquire the considerations such as the planning element and plan criteria of the streams for making ecological stream system. Water quality, water quantity, vegetation, in stream structures and facilities, and land usage of the streams were investigated and the build up capabilities of ecological stream for the two streams were also analyzed. Planning elements for restoration to ecological stream included physical and biological purification methods in water quality, short term water acquire alternatives in water quantity, and vegetation recovery plan and improvement of habitation environment in ecological system, respectively. Planing elements in physical structures and facilities also included recovery of concrete levee and removal and recovery of covered channel.

해수-석탄회 상호작용에 의한 미량원소 용출특성:Batch 실험연구

  • 박성민;김강주;황갑수;김진삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.295-298
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    • 2004
  • It was revealed that leaching of elements were partly inhibited because seawater contains plenty of dissolved ions than fresh water. On the other hands, the low activity coefficient and the formation of complex with chloride and sulfate play roles in enhancing element leachability. However, the pH buffaring capacity of seawater is the most important factor that makes the leaching of elements and its chemical behavior in the seawater system different from those in the fresh water environments. In general, the leaching from the weathered ash was smaller than that from the fresh ash. However, it was revealed that the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of ash weathering. They were dependant only on the pH of the solutions.

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FCAW에서 용접변수에 따른 용접금속 강도 및 와이어 합금원소의 회수율 변화 (Effects of Welding Parameters on Weld Metal Strength and Recovery of Alloying Elements in FCAW)

  • 정동희;방국수;박찬;장웅성;박철규
    • Journal of Welding and Joining
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    • 제26권2호
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    • pp.69-74
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    • 2008
  • 590MPa grade weldable steels were gas metal arc welded with flux cored wires. Welding parameters such as current, voltage, and speed were varied independently. Effects of each parameter on the strength and chemical composition of weld metal were investigated. Increase of voltage caused decrease of weld metal tensile strength due to the low recovery of alloying elements such as carbon and manganese. On the contrary, increase of current and speed resulted in increase of weld metal strength because of higher recovery of the alloying elements.

Relationships of Chemical Elements and their Environmental Impacts in Groundwater, Soil, and Fodder Plants in Arid Land

  • Hamdan, Ali;Khozyem, Hassan;Elbadry, Eman
    • 자원환경지질
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    • 제54권3호
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    • pp.331-352
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    • 2021
  • The relationship of both heavy metals and major elements in soil, plants, and groundwater was studied in a hyper-arid area and depends completely on the groundwater to cover its all needs. The study reviles that 27.3% of the studied groundwater was strongly acidic and has very low pH values (

Study of the organic and mineral composition of living pupae of the wild silkworm Saturnia pyri for use as food additives

  • Shukurova, Zarintac Yusif;Khalilov, Zarbali Murad;Shukurlu, Yusif Hacibala
    • International Journal of Industrial Entomology and Biomaterials
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    • 제43권2호
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    • pp.52-58
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    • 2021
  • The article presents the results of the content of the chemical and biochemical composition of the pupa of the wild silkworm Saturnia pyri belonging to the family Saturniidae, species of Lepidoptera. The nutritional value of silkworm Saturnia pyri pupae was evaluated, which contained 51% dry matter, 52.50% crude protein, 27.89% fat, 10.50% chitin fibers, 2.5% ash and 27 macro- and microelements and 25 mg alpha tocopherols in 100 g oil. The X-ray fluorescence method was used to determine the content of mineral elements in the pupa of the silkworm Saturnia pyri. It was revealed that the pupa of this type of silkworm contains 25 elements, of which the relative amount of K, Mg, Na, Ca, Al is much higher than other elements.

A review of chromatographic analysis for rare-earth elements with focus on Ln resin

  • Jihye Kim;Kihwan Choi
    • 분석과학
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    • 제36권6호
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    • pp.259-266
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    • 2023
  • The demand for rare-earth elements (REEs) is increasing owing to their significance as prominent materials in electronics, high-tech industries, geological research, nuclear forensics, and environmental monitoring. In general, the utilization of REEs in various applications requires the use of chromatographic techniques to separate individual elements. However, REEs have similar physicochemical properties, which makes them difficult to separate. Recently, several studies have examined the separation of REEs using LN resin as the stationary phase and aqueous nitric acid and hydrochloric acid solutions as eluents. Using this method, light REEs have been separated using dilute acid solutions as the eluent, whereas heavy REEs are separated using solutions with high acid concentrations. To increase the separation resolution between different REEs, either the column length or resin size is changed. In addition, the suggested methods are implemented to decrease the analysis time. This review presents technical information on the chromatographic separation of REEs using the LN resin and discusses the optimal experimental conditions.

황해 남동부 흑산니질대 퇴적물의 분포, 지화학적 조성 및 퇴적물 기원지 (Distribution Pattern, Geochemical Composition, and Provenance of the Huksan Mud Belt Sediments in the Southeastern Yellow Sea)

  • 하헌준;전승수;장태수
    • 한국지구과학회지
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    • 제34권4호
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    • pp.289-302
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    • 2013
  • 대부분 니질 퇴적물로 구성된 황해 남동부 흑산니질대 퇴적물의 기원지를 밝히기 위해 퇴적물 시료에 대해 주성분 원소와 희토류 원소(REE)를 분석하였다. 표층 퇴적물 시료는 흑산니질대 내 51지점에서 피스톤식과 박스형 시료 채취기로 획득하였다. 흑산니질대의 표층퇴적물은 니 퇴적물이 우세하게 나타나며, 평균입도는 $5-6{\phi}$이다. 공간적으로 북쪽지역은 실트함량이 높고, 남쪽지역으로 갈수록 점토함량이 증가한다. 흥미롭게도 주성분 원소와 희토류 원소 함량 특성은 퇴적물 기원 해석에 있어 다른 결과를 가져왔다. Fe/Al과 Mg/Al 함량 비, $Al_2O_3$와 MgO 함량 비, $Al_2O_3$$K_2O$를 각각 도시한 결과, 흑산니질대 퇴적물은 한국 기원의 퇴적물이 우세한 것으로 나타났다. 하지만 희토류 원소의 특성은 중국 기원의 퇴적물이 우세함을 반영한다. 이러한 기원 불일치는 각 원소의 함량 조절요인이 다르기 때문이다. 주성분 원소는 입도와 높은 상관관계를 고려할 때 입도에 따라 그 함량이 영향을 받는 것으로 해석된다. 반면에 희토류 원소는 입도와는 상관관계가 낮으며, 중광물 함량에 의해 조절되는 것으로 사료된다. 이와 같이, 각기 다른 추적자에 따른 기원의 불일치를 해결하기 위해 추가적인 연구가 필요하다.

ICP/AES에 의한 지질시료 중의 희토류원소 분석 (Determination of Rare Earth Elements in USGS Geological Materials by ICP/AES)

  • 김정석;최광순;박용준;지광용
    • 대한화학회지
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    • 제39권2호
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    • pp.28-81
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    • 1995
  • 지질시료 중의 전 회토류원소들을 유도결합플라즈마 원자방출분광법을 이용하여 동시 및 개별정량하였다. 시료는 산처리 및 알칼리 용융으로 분해하고 TOPO(triocylphosphine oxide)를 이용하여 용매추출한 다음 HCl 용액으로 역추출하여 군분리하였다. 표준암석 AGV-1에 대한 분석결과는 US Geological Survey 및 다른 문헌상의 결과와 비교하여 양호하였다.

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Determination of Boron Steel by Isotope-Dilution Inductively Coupled Plasma Mass Spectrometry after Matrix Separation

  • Park, Chang-J.
    • Bulletin of the Korean Chemical Society
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    • 제23권11호
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    • pp.1541-1544
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    • 2002
  • The concentration of B in steels is important due to its influence on mechanical properties of steel such as hardenability, hot workability, and creep resistance. An analytical method has been developed to determine B in steel samples by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). National Institute of Standard and Technology Standard Reference Material (NIST SRM) 348a was analyzed to validate the analytical method. The steel sample was digested in a centrifuge bottle with addition of aqua regia and $^{10}B$ spike isotope. Sample pH was then adjusted to higher than 10 to precipitate most matrix elements such as Fe, Cr, and Ni. After centrifugation, the supernatant solution was passed through a cation exchange column to enhance the matrix separation efficiency. B recovery efficiency was about 37%, while matrix removal efficiency was higher than 99.9% for major matrix elements. The isotope dilution method was used for quantification and the determined B concentration was in good agreement with the certified value.

황을 포함한 유기화합물인 NaDDTC의 CuNi합금에 대한 화학적 흡착에 관한 정량적 분석 (Quantitative Analysis on Chemisorption of NaDDTC as Organic Compound containing Sulfur for Cu-Ni Alloy)

  • 정길봉;김동영;장요한
    • 한국군사과학기술학회지
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    • 제18권5호
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    • pp.548-557
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    • 2015
  • This paper is results on Chemisorption of organic compound for the sea water fire fighting line of naval vessels. The quantitative analysis of Chemisorption has been investigated in seawater after immersion in 0.1 % of NaDDTC solutions for 43 hours. The morphology and topography were investigated by FE-SEM and AFM. The chemical elements were analyzed by SEM-EDS, XPS and the depth of chemical elements was measured by depth profiles. The effect of NaDDTC comes from Chemisorption between Copper and Sulfur of NaDDTC. As a result, test results showed that sulfur is helpful to protect a corrosion of seawater line.