• Title/Summary/Keyword: chemical elements

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Alkali-Swollen Morphology of Native Cellulose Fibers

  • Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.2
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    • pp.16-22
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    • 2007
  • The behavior of ramie fibers and some wood elements in the early stage of alkali swelling was examined. When the fibers were treated with alkali solution, they significantly shrank in length and swelled in wall thickness. Ramie fibers showed a shrinkage averaging 23% in length and a swelling averaging 92% in width in 100 seconds treating time. Dimensional changes showed different fashion in each element of woods. The tracheids of latewood especially in Pinus densiflora and Larix kaempferi woods swelled intensively and showed balloon swelling, but in the case of Cryptomeria japonica, it was hardly observed. The swelling morphology of libriform fibers was similar to that of tracheids. The walls of vessel elements and parenchyma cells also swelled considerably in thickness but, no balloon swelling was found in both elements. The differences of swelling in different elements can be interpreted in terms of the differences of organization and/or chemical components of the cell walls.

Transport and Loadings of Nutrients and Dissolved Major and Trace Elements in the Yeongsan River, Korea

  • Cha Hyun-Ju;Cho, Yeong-Gil
    • Journal of the korean society of oceanography
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    • v.37 no.2
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    • pp.66-75
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    • 2002
  • Temporal variation of nutrients and dissolved major and trace elements have been studied in the Yeongsan River, Korea. There were significant temporal fluctuations in the concentrations of these elements depending upon the flow condition. $NH_4$, $PO_4$, Na, Mg, Ca, K, Mn, Cu, Ni, Zn, Co, As and U concentrations were inversely related to the flow; that is, they are the highest at low flow and the lowest at high flow. It indicates that these elements are derived from point sources such as rock weathering and/or human activities and then diluted by increasing flow. Meanwhile, Fe and Si concentrations varied proportionally to the flow indicating that they are derived from diffuse sources including reactions within soil. The concentration-flow relationships showed that hydrology of the river is the most important factor controlling the chemical composition of the Yeongsan riverwater, which was compatible of the results of R-mode factor analysis.

Soil Geochemical Exploration of the Mt. Subang Area of the Southern Part of the Bandung, Indonesia (인도네시아 반둥 남부 수방산지역에서의 토양지화학 탐사)

  • 김인준;이재호;이사로;서정률;김유봉;이규호
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.173-184
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    • 2004
  • The geochemical exploration was carried out of the soil systems in the survey areas(Mt. Subang area). The chemical values of soil samples for soil in this area are defined such as over values of Ag : 11 ppm(Average : 1.91 ppm), Au 548 ppb(Average 42.39 ppb), Cu : 89 ppm(Average:51.40 ppm), Pb:190 ppm(Average : 23.69 ppm), Zn : 157 ppm(Average : 61.78 ppm), respectively. Anomalous areas for each element have been chosen based on the factors such as, geologic settings, geochemical survey, chemical analysis of ore, chemical analysis of soil. statistical processing of the chemical analysis. Therefore, multi-elements anomalies area were recognized in the east-center part of the study area.

AN EXPERIMENTAL STUDY ON THE CHEMICAL BOND STRENGTH AT THE INTERFACE BETWEEN PORCELAIN AND SUCCESSIVELY RECAST PALLADIUM-SILVER CERAMIC ALLOY (팔라디움-은합금의 반복주조시 도재와 금속간의 화학적 결합에 관한 실험적 연구)

  • Kim, Tae-Kyun;Lee, Sun-Hyung;Yang, Jae-Ho;Chong, Hun-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.1
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    • pp.31-47
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    • 1989
  • The purpose of this study was to evaluate the chemical bond strength of successively recast Pd-Ag ceramic alloys with porcelain and to investigate changes of quantity of trace elements at the metal-porcelain interface. Porcelain was fired as usual manner on the each successively recast specimen. Rectangular planar shear test was performed and bond strength was measured by Instron universal testing machine. Diffusion of trace elements at the each interface was observed by ESCA (Electron Spectroscopy for Chemical Analysis). The obtained results were as follows : 1. Chemical bond strength was significantly decreased after second recasting. But in case of first recasting, there was no significant decrease of bond strength statistically (p<0.05). 2. Bond strength was not significantly decreased in each generation, when fifty percents new alloy was added (p<0.05). 3. Ag, Sn and In were observed at the porcelain interface. But Pd was not observed. 4. The quantity of Ag, In ions were progressively increased at the metal-porcelain interface as the casting was repeated. Silver ion was most significantly increased.

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Variation of Chemical Composition and Relative migration of major Elements in the Weathering of Jeon-Ju granite and Rang-San granite (전북(全北) 전주지역(全州地域) 화강암(花崗岩) 및 낭산지역(郎山地域) 화강암(花崗岩)의 풍화(風化)에 따른 화학조성(化學組成)의 변화(變化)와 주요원소(主要元素)의 상대적이동(相對的移動))

  • Nam, Ki Sang
    • Economic and Environmental Geology
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    • v.8 no.4
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    • pp.211-221
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    • 1975
  • Weathering of granites has a geochemical role of great significance, because of their abundance and because of chemical instability near the surface of the earth, which is more pronounced than in most other rocks. On the other hand the granites are tectonically fragile and "react" to deformation with marked facility, giving rise to a whole gamut of deformed rocks. Therefore, the writer has studied on the weathering of granitic rocks at of Iri city and Jeonju city Jeollabukdo, Korea, The fresh and weathered rocks were used as material for the investigation. The results obtained by chemical analysis and observation are as follows. 1) The order of mobility in major elements was Ca, Na and K$H_2O$ was observed clearly and late stages of weathering processes. 3) The early stage of weathering is commenced by physical weathering and followed by chemical weathering. 4) The ratio of FeO/. $Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3 $ decreased uniformly from early to late stage of weathering processes. 5) It was proved that weathering potential of granite was larger than that of basaltic rocks.

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Review on sodium corrosion evolution of nuclear-grade 316 stainless steel for sodium-cooled fast reactor applications

  • Dai, Yaonan;Zheng, Xiaotao;Ding, Peishan
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3474-3490
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    • 2021
  • Sodium-cooled fast reactor (SFR) is the preferred technology of the generation-IV fast neutron reactor, and its core body mainly uses nuclear-grade 316 stainless steel. In order to prolong the design life of SFRs to 60 years and more, it is necessary to summarize and analyze the anti-corrosion effect of nuclear grade 316 stainless steel in high temperature sodium environment. The research on sodium corrosion of nuclear grade 316 stainless steel is mainly composed of several important factors, including the microstructure of stainless steel (ferrite layer, degradation layer, etc.), the trace chemical elements of stainless steel (Cr, Ni and Mo, etc) and liquid impurity elements in sodium (O, C and N, etc), carburization and mechanical properties of stainless steel, etc. Through summarizing and constructing the sodium corrosion rate equations of nuclear grade 316 stainless steel, the stainless steel loss of thickness can be predicted. By analyzing the effects of temperature, oxygen content in sodium and velocity of sodium on corrosion rate, the basis for establishing integrity evaluation standard of SFR core components with sodium corrosion is provided.

Soil Chemical Properties in Asian Dust Source region in Northern China (황사발생지역에서 토양입자의 화학적 특성)

  • Han, J.S.;Shin, Sun-A;Kong, B.J.;Park, M.S.;Park, S.U.;Kim, S.J.
    • Journal of Environmental Impact Assessment
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    • v.13 no.6
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    • pp.277-284
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    • 2004
  • The chemical composition and properties of soil were determined at selected sites, such as Loess plateau, Gobi and sand deserts in northern China, where most dust storms occur. Although the transport of this sort of dust storms to Korean peninsula is a well-documented phenomenon, there is not enough information about the very source regions. In this reason, this study tried to measure the chemical composition, including soil elements, anthropogenic elements and ions for soil samples so that certain properties of some major source regions of Asian Dust can be provided. Furthermore, the results are classified into four types of soil like Loess, Loess & sand, Gobi, and sand in order to identify the characteristics and difference among the types. $(X/Al)_{crust}$ values for each soil type were also calculated in this study and compared with those of other references including Asian Dust material(ADM). The results indicated that Ca contribution was higher than Al in all the soil types of this study including ADM and, compared with the values of urban area, contribution of anthropogenic elements such as Cr, Pb, Zn was quite low. However, it must be noted that there is such a variation in the result of soil composition, but it is also certain that the very source region soil composition resolved from this study could support the enhanced study on Asian Dust phenomenon in Korea.

Geochemistry of Precambrian Mafic Dikes in Northern Michigan, U.S.A.: Implications for the Paleo-Tectonic Environment (북부 미시간 지역에 분포하는 선캠브리아기의 염기성 암맥에 대한 지화학적인 연구)

  • Wee, Soo Meen
    • Economic and Environmental Geology
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    • v.24 no.4
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    • pp.447-463
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    • 1991
  • Petrological and chemical studies of Precambrian dikes in the southern Lake Superior region were conducted with the objects of evaluating magma source and constraining models for the paleo-tectonic environment. Forty-six samples were analyzed for major, trace, and rare earth elements. Chemical data of the studied dikes are typical of continental tholeiites and showing iron-enrichment fractionation trend. With wallrock contamination carefully evaluated, a series of tectonic discriminating methods utilizing immobile trace elements indicate that the source magma was a high-Ti tholeiitic basalt similar to present-day T-type MORB. Effect of chemical contamination from wallrock assimilation accmulates with increasing differentiation. Evolved rocks show LREE enriched patterns and have enhanced levels of LIL elements (e.g., Rb, K, Ba, Th), but low levels of high field strength elements (e.g., Nb, P, Ti) with respect to their neighboring elements. It is suggested from this study that this enrichment possibly due to a combination of a feature inherited from the subcontinental lithosphere and crustal contamination. Geochemical signatures of these rocks are distinctively different from those of arc-related volcanics. Comparisons with chemistries of modern magmas show a pattern of overlap between Within-plate and ocean-floor characteristics, and chemical signatures of these rocks favor a model of intrusion into a crustal environment undergoing lithospheric attenuation.

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Lyotropic Chromonic Liquid Crystals: Effects of Additives and Optical Applications

  • Park, H.S.;Tortora, L.;Vasyuta, R.M.;Golovin, A.B.;Augustin, E.;Finotello, D.;Lavrentovich, O.D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.307-310
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    • 2007
  • We describe effects of ionic and neutral additives on phase and structural behavior of the lyotropic chromonic liquid crystals used in preparation of optical elements such as polarizers and compensators.

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Influence of Different A Elements on Bonding and Elastic Properties of Zr2AC (A = Al, Si, P, S): A Theoretical Investigation

  • Kang, Dae-Bok
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.609-614
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    • 2013
  • Extended H$\ddot{u}$ckel tight-binding band structure calculations are used to address the chemical bonding and elastic properties of $Zr_2AC$ (A=Al, Si, P, and S). Elastic properties are interpreted by analyzing the density of states and the crystal orbital overlap population for the respective phases. Our results show that the bulk modulus of these ternary compounds is determined by the strength of Zr-A bonds.