• Title/Summary/Keyword: chemical elements

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A Study on the Planning Elements for Ecological Restoration of Urban Stream through Present Condition Analysis - focused on the Yeocheon and the Mugeo stream - (현황분석을 통한 도시 소하천의 생태하천 계획요소에 관한 연구 -울산광역시 무거.여천천을 중심으로-)

  • Kim, Seong Cheol;Lee, Cheol Yeong
    • Journal of Environmental Science International
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    • v.13 no.9
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    • pp.747-757
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    • 2004
  • The objectives of this study were to investigate the physical, chemical, and structural characteristics of the stream, especially Mugeo and Yeochon which are being changed to ecological stream by Ulsan city, and to acquire the considerations such as the planning element and plan criteria of the streams for making ecological stream system. Water quality, water quantity, vegetation, in stream structures and facilities, and land usage of the streams were investigated and the build up capabilities of ecological stream for the two streams were also analyzed. Planning elements for restoration to ecological stream included physical and biological purification methods in water quality, short term water acquire alternatives in water quantity, and vegetation recovery plan and improvement of habitation environment in ecological system, respectively. Planing elements in physical structures and facilities also included recovery of concrete levee and removal and recovery of covered channel.

해수-석탄회 상호작용에 의한 미량원소 용출특성:Batch 실험연구

  • 박성민;김강주;황갑수;김진삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.295-298
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    • 2004
  • It was revealed that leaching of elements were partly inhibited because seawater contains plenty of dissolved ions than fresh water. On the other hands, the low activity coefficient and the formation of complex with chloride and sulfate play roles in enhancing element leachability. However, the pH buffaring capacity of seawater is the most important factor that makes the leaching of elements and its chemical behavior in the seawater system different from those in the fresh water environments. In general, the leaching from the weathered ash was smaller than that from the fresh ash. However, it was revealed that the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of ash weathering. They were dependant only on the pH of the solutions.

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Effects of Welding Parameters on Weld Metal Strength and Recovery of Alloying Elements in FCAW (FCAW에서 용접변수에 따른 용접금속 강도 및 와이어 합금원소의 회수율 변화)

  • Jung, Dong-Hee;Bang, Kook-Soo;Park, Chan;Chang, Woong-Sung;Park, Chul-Gyu
    • Journal of Welding and Joining
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    • v.26 no.2
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    • pp.69-74
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    • 2008
  • 590MPa grade weldable steels were gas metal arc welded with flux cored wires. Welding parameters such as current, voltage, and speed were varied independently. Effects of each parameter on the strength and chemical composition of weld metal were investigated. Increase of voltage caused decrease of weld metal tensile strength due to the low recovery of alloying elements such as carbon and manganese. On the contrary, increase of current and speed resulted in increase of weld metal strength because of higher recovery of the alloying elements.

Relationships of Chemical Elements and their Environmental Impacts in Groundwater, Soil, and Fodder Plants in Arid Land

  • Hamdan, Ali;Khozyem, Hassan;Elbadry, Eman
    • Economic and Environmental Geology
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    • v.54 no.3
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    • pp.331-352
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    • 2021
  • The relationship of both heavy metals and major elements in soil, plants, and groundwater was studied in a hyper-arid area and depends completely on the groundwater to cover its all needs. The study reviles that 27.3% of the studied groundwater was strongly acidic and has very low pH values (

Study of the organic and mineral composition of living pupae of the wild silkworm Saturnia pyri for use as food additives

  • Shukurova, Zarintac Yusif;Khalilov, Zarbali Murad;Shukurlu, Yusif Hacibala
    • International Journal of Industrial Entomology and Biomaterials
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    • v.43 no.2
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    • pp.52-58
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    • 2021
  • The article presents the results of the content of the chemical and biochemical composition of the pupa of the wild silkworm Saturnia pyri belonging to the family Saturniidae, species of Lepidoptera. The nutritional value of silkworm Saturnia pyri pupae was evaluated, which contained 51% dry matter, 52.50% crude protein, 27.89% fat, 10.50% chitin fibers, 2.5% ash and 27 macro- and microelements and 25 mg alpha tocopherols in 100 g oil. The X-ray fluorescence method was used to determine the content of mineral elements in the pupa of the silkworm Saturnia pyri. It was revealed that the pupa of this type of silkworm contains 25 elements, of which the relative amount of K, Mg, Na, Ca, Al is much higher than other elements.

A review of chromatographic analysis for rare-earth elements with focus on Ln resin

  • Jihye Kim;Kihwan Choi
    • Analytical Science and Technology
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    • v.36 no.6
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    • pp.259-266
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    • 2023
  • The demand for rare-earth elements (REEs) is increasing owing to their significance as prominent materials in electronics, high-tech industries, geological research, nuclear forensics, and environmental monitoring. In general, the utilization of REEs in various applications requires the use of chromatographic techniques to separate individual elements. However, REEs have similar physicochemical properties, which makes them difficult to separate. Recently, several studies have examined the separation of REEs using LN resin as the stationary phase and aqueous nitric acid and hydrochloric acid solutions as eluents. Using this method, light REEs have been separated using dilute acid solutions as the eluent, whereas heavy REEs are separated using solutions with high acid concentrations. To increase the separation resolution between different REEs, either the column length or resin size is changed. In addition, the suggested methods are implemented to decrease the analysis time. This review presents technical information on the chromatographic separation of REEs using the LN resin and discusses the optimal experimental conditions.

Distribution Pattern, Geochemical Composition, and Provenance of the Huksan Mud Belt Sediments in the Southeastern Yellow Sea (황해 남동부 흑산니질대 퇴적물의 분포, 지화학적 조성 및 퇴적물 기원지)

  • Ha, Hun Jun;Chun, Seung Soo;Chang, Tae Soo
    • Journal of the Korean earth science society
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    • v.34 no.4
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    • pp.289-302
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    • 2013
  • In order to determine the provenance of the Huksan Mud Belt sediments in the southeastern Yellow Sea, the major and rare earth elements of the same sediments were analyzed. The surface sediments were sampled from top of piston-cores and box-cores taken at 51 sites within the Huksan Mud Belt. With the mean grain size of $5-6{\phi}$, the sediments of the study area are mud-dominated. The spatial distribution patterns show that silt content is high in the northern Mud Belt, whereas clay content increases as it moves toward the southern Mud Belt. Interestingly, the geochemical compositions both of major and rare earth elements have resulted in differences of sediment provenance. Among the major elements, plots of Fe/Al vs. Mg/Al ratios, $Al_2O_3$ vs. MgO ratios, and $Al_2O_3$ vs. $K_2O$ reveal that the Huksan Mud Belt sediments are dominated by the Korean river-derived sediments. However, the characteristics of rare earth elements infer sediments originating from the Chinese rivers. This discrepancy between the above provenances is attributed to the different contributory factors in the content of chemical elements. Considering strong correlation between major elements with grain sizes, the contents of the major elements are thought to be influenced by the grain size. However, there is a weak correlation between rare earth elements and grain sizes. The behaviour of rare earth elements may be controlled by heavy minerals, rather than grain sizes. Further study requires to solve the discrepancy arose from the difference in applied chemical tracers.

Determination of Rare Earth Elements in USGS Geological Materials by ICP/AES (ICP/AES에 의한 지질시료 중의 희토류원소 분석)

  • 김정석;최광순;박용준;지광용
    • Journal of the Korean Chemical Society
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    • v.39 no.2
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    • pp.28-81
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    • 1995
  • Inductively coupled plasma atomic emission spectrometry was used for the determination of all 14 rare earth elements (REE) in geological materials. Samples were decomposed by using acid digestion followed by alkaline fusion. Group separation of the REE was achieved by solvent extraction with TOPO (trioctylphosphine oxide) and back extraction into HCl. The results for standard rock sample, AGV-1, showed a good agreement with those obtained by US Geological Survey as well as reported values in other articles.

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Determination of Boron Steel by Isotope-Dilution Inductively Coupled Plasma Mass Spectrometry after Matrix Separation

  • Park, Chang-J.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1541-1544
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    • 2002
  • The concentration of B in steels is important due to its influence on mechanical properties of steel such as hardenability, hot workability, and creep resistance. An analytical method has been developed to determine B in steel samples by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). National Institute of Standard and Technology Standard Reference Material (NIST SRM) 348a was analyzed to validate the analytical method. The steel sample was digested in a centrifuge bottle with addition of aqua regia and $^{10}B$ spike isotope. Sample pH was then adjusted to higher than 10 to precipitate most matrix elements such as Fe, Cr, and Ni. After centrifugation, the supernatant solution was passed through a cation exchange column to enhance the matrix separation efficiency. B recovery efficiency was about 37%, while matrix removal efficiency was higher than 99.9% for major matrix elements. The isotope dilution method was used for quantification and the determined B concentration was in good agreement with the certified value.

Quantitative Analysis on Chemisorption of NaDDTC as Organic Compound containing Sulfur for Cu-Ni Alloy (황을 포함한 유기화합물인 NaDDTC의 CuNi합금에 대한 화학적 흡착에 관한 정량적 분석)

  • Jung, Gilbong;Kim, Dongyung;Jang, Yohan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.5
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    • pp.548-557
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    • 2015
  • This paper is results on Chemisorption of organic compound for the sea water fire fighting line of naval vessels. The quantitative analysis of Chemisorption has been investigated in seawater after immersion in 0.1 % of NaDDTC solutions for 43 hours. The morphology and topography were investigated by FE-SEM and AFM. The chemical elements were analyzed by SEM-EDS, XPS and the depth of chemical elements was measured by depth profiles. The effect of NaDDTC comes from Chemisorption between Copper and Sulfur of NaDDTC. As a result, test results showed that sulfur is helpful to protect a corrosion of seawater line.