• Title/Summary/Keyword: chemical diversity

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Two Species of Endophytic Penicillium from Pinus rigida in Korea

  • Kim, Chang-Sun;Park, Myung-Soo;Yu, Seung-Hun
    • Mycobiology
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    • v.36 no.4
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    • pp.222-227
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    • 2008
  • Upon studying the diversity of fungal endophytes associated with pine trees in Korea, many species of Penicillium were encountered. In this study, we report two species of Penicillium isolated from the needles of Pinus rigida. Based on ID region analysis, cultural and morphological characteristics, the two species were identified as Penicillium fellutanum and P. toxicarium, both of which are new to Korea.

Actinofuranone C, a New 3-Furanone-Bearing Polyketide from a Dung Beetle-Associated Bacterium

  • Um, Soohyun;Bang, Hea-Son;Shin, Jongheon;Oh, Dong-Chan
    • Natural Product Sciences
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    • v.19 no.1
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    • pp.71-75
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    • 2013
  • Actinofuranone C (1), a new 3-furanone-bearing polyketide, was isolated from an actinobacterium (Amycolatopsis sp.) associated with a female of the dung beetle, Copris tripartitus Waterhouse. The structure of actinofuranone C was elucidated by the spectroscopic interpretation of NMR, mass, UV, and IR data. The discovery of actinofuranone C indicates that chemical investigation of insect-associated microorganisms would be an effective strategy to explore natural chemical diversity.

Metallothionein Induces Site-specific Cleavages in tRNAPhe

  • Seon, Jung-Yun;Koh, Moon-Joo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.921-924
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    • 2005
  • It is known that metallothionein (MT) plays a role in the scavenging of free radicals, which is produced under various stress conditions. MT may function as an antioxidant that protects against oxidative damage of DNA, protein, and lipid induced by superoxide anion, hydrogen peroxide, hydroxyl radical, nitric oxide, and peroxynitrite. This study was undertaken to test the hypothesis that MT also protects from RNA damage induced by peroxynitrite, an important reactive nitrogen species that causes a diversity of pathological processes. A cell-free system was used. RNA damage was detected by the mobility of $tRNA^{Phe}$ in electrophoresis. Cleavages on tRNA were not induced by 3-morpholinosydnomine, which produces peroxynitrite directly. MT induced tRNA damage which was site specific.

Structural Studies of the Self-Assemblies Created with Dipyrrins

  • Shin, Ji-Young;Patrick, Brian O.;Son, Seung-Bae;Hahn, Jae-Ryang;Dolphin, David
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.1004-1013
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    • 2010
  • Three-dimensional superstructures of unique self-assemblies generated by exploring the conformational flexibility of various dipyrromethenes through creation of hydrogen-bonds with metal-halide anions are reported and the conformational diversity is thoroughly described in the solid and solution states by X-ray diffraction analysis and variable temperature NMR spectroscopy. The tetrahedral or octahedral structures of their precursors, various metal-dipyrromethene complexes, are also reported, based on the crystallographic data. STM images of the self-assemblies observed on graphite surfaces present interesting arrangements and appear as tubular bunches.

Diverse mechanism on cadmium uptake among rice varieties

  • Lee, Sang Beom;Kim, Kyu Won;Kim, Gyeong Jin;Choi, Buung;Yoo, Ji Hyok;Oh, Kyeong Seok;Moon, Byeong Churl;Park, Yong-jin;Park, Sang Won
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.157-157
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    • 2017
  • In last study, Genome-Wide Association Studies (GWAS) was conducted for cadmium content of 295 rice varieties including 137 rice core set and 157 Korea breeding varieties collected from Kongju National University. The results showed that 9 varieties had SNP allele and amino acid substitution in exon of chromosome 1. This study was aim to understanding mechanism of cadmium uptake to confirm correlation of cadmium and other mineral nutrients (Cu, Mn, Fe) among 9 rice varieties. Nine varieties were planted on polluted soil of mine in Korea and cadmium content in root, stem, leaf and it's brown rice was analyzed by ICP-MS (Inductively Coupled Plasma Mass spectrometer, Agilent 7700E, US). Results of this study showed that mechanism for cadmium uptake and accumulation was diversity among varieties. Chin-nong and Ho-nong contained higher levels of cadmium in root, but contained relatively lower levels cadmium in brown rice than other varieties. Cheong-nam, Nam-pyeong, Gan-cheok, Suan absorbed high levels of cadmium through root and then accumulated high cadmium to brown rice. Meanwhile, Yeong-deok and Su-kwang absorbed lower cadmium in root, but high cadmium was accumulated in brown rice. Correlations between cadmium and other mineral nutrients (Cu, Mn, Fe) were analyzed by using SPSS statistics 20. The contents of iron in leaf had minus correlation (p<0.05) with cooper and cadmium in root, cadmium in brown rice. Therefore understanding of cadmium uptake mechanism among varieties will be used to basic data for further breeding and phytoremediation.

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A Series of Transition-metal Coordination Complexes Assembled from 3-Nitrophthalic Acid and Thiabendazole: Synthesis, Structure and Properties

  • Xu, Wen-Jia;Xue, Qi-Jun;Liang, Peng;Zhang, Ling-Yu;Huang, Yan-Feng;Feng, Yu
    • Bulletin of the Korean Chemical Society
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    • v.35 no.1
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    • pp.218-224
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    • 2014
  • In order to explore new coordination frameworks with novel designed 3-nitrophthalic acid and the same N-donor ancillary ligand, a series of novel coordination complexes, namely, $[Cd_2(3-NPA)_2(TBZ)_2(H_2O)_2]{\cdot}2H_2O$(1), $[Zn_2(3-NPA)_2(TBZ)_2]$(2), $[Zn_2O(3-NPA)(TBZ)(H_2O)]_n$(3), $[Co(3-NPA)(TBZ)(H_2O)]_n$(4) (3-$NPAH_2$ = 3-nitrophthalic acid), have been hydrothermally synthesized through the reaction of 3-nitrophthalic acid with divalent transition-metal salts in the presence of N-donor ancillary coligand (TBZ = thiabendazole). As a result of various coordination modes of the versatile 3-$NPAH_2$ and the coligand TBZ, these complexes exhibit structural diversity. X-ray structure analysis reveals that 1 and 2 are 0D molecular rings, while 3 and 4 are one-dimensional (1D) infinite chain polymers. And the weak O-H${\cdots}$O hydrogen bonds and C-H${\cdots}$O nonclassical hydrogen bonds as well as ${\pi}-{\pi}$ stacking also play important roles in affecting the final structure where complexes 1, 3 and 4 have 3D supramolecular architectures, while complex 2 has a 2D supramolecular network. Also, IR spectra, fluorescence properties and thermal decomposition process of complexes 1-4 were investigated.

A Study on Analysis and Implications of Domestic and Foreign Chemical Engineering Programs (국내·외 대학 화학공학 유관학과 교육과정 분석)

  • Hwang, Ju-young;Lee, Kyu-nyo;Yi, Kwang-bok;Han, su-kyoung;Rhee, Young-woo
    • Journal of Engineering Education Research
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    • v.21 no.4
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    • pp.53-62
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    • 2018
  • The purpose of this study is to investigate the current conditions of the domestic and foreign curricula in the field of chemical engineering and to draw implications. The results of the study are as follows. Most of the domestic research universities (including non-certified universities) have curricula organized within the scope of the ABEEK certification, which is the minimum standard guide for chemical engineering curricula. However, we are concerned that chemical engineering education in some domestic universities may lack in education quality and program relevance. Graduates from these universities may not have equivalent qualifications as international graduates. It is considered that most of the 12 domestic universities organize their subjects according to the certificate of accreditation standard and to the traditional subjects of chemistry in the 'Department of Chemical Engineering' or 'Department of Chemical and Biological Engineering Chemical and Biological Engineering'. However, due to the increase in the number of overlapping subjects with other majors because of the movement towards academic diversity, the integrity of the chemical engineering curricula is at risk. In addition, after surveying the major and research areas of the department professors, it has been found that there is a shortage of professors who have majored in chemical engineering. Therefore, there is a concern that students may lack understanding of the core principles of chemical engineering. The results of the analysis of the curricula of overseas research universities (including non-certified universities) are as follows. Although the chemical engineering industry in developed countries like the United States and Europe is advancing and changing very quickly, the chemical engineering education in these countries is highly focused on traditional subjects and other related subjects in order to cultivate traditionally trained chemical engineers. The Department of Chemical Engineering at overseas universities still maintains the academic integrity of the chemical engineering field. This is a significant suggestion for our country. On the other hand, domestic universities are changing the name of their chemical engineering major, or even if the name is maintained, they are fusing their curriculum with other majors such as material engineering. Therefore, it is very necessary at this point to start a discussion regarding the integrity of the department of chemical engineering in Korea. We hope that the departments of chemical engineering in domestic universities maintain the integrity of traditional chemical engineering while operating the curriculum within the scope of the standards of the engineering education certification system.

Stream Eco-corridor Restoration by Out-aged Small Dam Removal - Focused on Gokreung River Gokreung 2 Small Dam Removal - (기능을 상실한 보 철거를 통한 하천생태통로 복원 - 곡릉천 곡릉2보 철거를 대상으로 -)

  • Ahn, Hong Kyu;Woo, Hyoseop;Rhee, Dong Seop;Kim, Kyu Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.2
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    • pp.40-54
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    • 2008
  • Small and large dams are installed in the course of a stream for maintaining the water level of the stream or obtaining agricultural water. Currently about 18,000 of them are installed in Korea to supply water. However, the environmental problems of small dams are well known : the interruption of stream eco-corridors, deterioration of water quality in the upper reaches of the small dam, changes in the habitats of riparian organisms, damages to the stream scenery. In a very few of these small dams artificial eco-corridors like fishways are installed, but the number is very minimal.Accordingly, to efficiently restore stream eco-corridors by removing these small dams, it will be necessary to closely examine physical impacts, such as changes in the riverbed and changes in the shape of the stream caused by the removal, chemical impacts, such as changes in water quality, and transport and accumulation of contaminated sediments and biological impacts, such as changes in the habitats of organisms, and develop related technologies in advance, and have these technologies verified through demonstration application in the sites. In this study, we analyzed the physical, chemical and ecological impacts of the removal of the above-mentioned small dams, and conducted a research on the demonstration small dam removal project for a spot investigation. As a result, the small dam removal will restore the eco-corridor, there by improving the habitat of fishes and crustaceans. The number of major underwater organisms inhabiting the Gokreungcheon, such as Korean spotted sleepers, Chinese minnows, Microphysogobio yaluensis, Abbottina rivularis, stone morokos, striped shinners, long-nosed barbels, and Chinese mitten crabs, is expected to increase, and the food chain in the ecosystem will improve so that species diversity will improve as well.

The Study of Development of Color-Mud for Boryeong Mud Festival by Color Pigment (착색안료를 이용한 보령머드축제용 유색머드의 개발)

  • Shim, Seung-Bo;Oh, Seong-Geun;Hong, Kyung-Hee;Chun, Yong-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2300-2305
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    • 2010
  • This study was performed about color-contained mud to provide fun and diversity for the event of mud self massage as a core program of Boryeong Mud Festival which has become one of representative festivals in Korea. Adjusting its own lower brightness of mud and based on the primary study performed about the expressivity of yellowish colors, inorganic colors (oxidized steel in red, ultra marine pink, ultra marine blue, chrome oxide green) were added for the development of colored mud in diverse colors on the basis of Korean traditional colors. It had been judged about each expressivity of color by methods of colormeter, naked eyes inspection and feeling of usage, etc. For the color decided, it had been examined about the coloring when it got wet with the cleaning condition so that it can be used for the event of mud self massage as a program of Boryeong Mud Festival to increase diversity of the Festival and also attempted to develope colored mud to show Korean traditional colors.

Genetic Distribution Pattern of Bluegill Sunfish Lepomis macrochirus in Freshwater Ecosystems across Korea

  • Lau, Hwee Hui;Huang, Jingting;Kwan, Ye-Seul;Lee, Wan-Ok;Won, Yong-Jin
    • Animal Systematics, Evolution and Diversity
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    • v.25 no.3
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    • pp.325-329
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    • 2009
  • Lepomis macrochirus from the family Centrarchidae, commonly known as Bluegill sunfish, is an introduced freshwater fish in Korea that thrives in lakes, ponds, reservoirs and rivers. Since its introduction into Korea in 1969, Lepomis macrochirus has rapidly dispersed out and increased in number almost all over the freshwater ecosystems in Korea. Consequently this species causes a severe ecological problem, threatening native fishes due to its omnivorous foraging behaviors upon fish juveniles and many freshwater invertebrates. To address population genetic structure of L. macrochirus, 74 fish samples from 10 populations were collected and compared for their mitochondrial D-loop control region. As the result we found that the genetic diversity of L. macrochirus is extremely low such as resulting only four haplotypes with a few nucleotide differences among them. Analysis of molecular variance (AMOVA) revealed that the source of population genetic variation is largely retained in the comparisons among individuals within populations, while it is relatively low with slight significance at the highest hierarchical group. This distribution pattern differs from what is expected when biogeography is under the influence of natural geographic barriers such as mountain ranges in Korea. Instead the result is accord with the influential role of random spreading events facilitated by local people for aquaculture and fishing, and subsequent dispersals since its single point of introduction into Korea.