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http://dx.doi.org/10.5012/bkcs.2014.35.1.218

A Series of Transition-metal Coordination Complexes Assembled from 3-Nitrophthalic Acid and Thiabendazole: Synthesis, Structure and Properties  

Xu, Wen-Jia (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Xue, Qi-Jun (College of pharmacy, Liaoning University)
Liang, Peng (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Zhang, Ling-Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Huang, Yan-Feng (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Feng, Yu (College of Chemistry and Chemical Engineering, Guangxi University for Nationalities)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.1, 2014 , pp. 218-224 More about this Journal
Abstract
In order to explore new coordination frameworks with novel designed 3-nitrophthalic acid and the same N-donor ancillary ligand, a series of novel coordination complexes, namely, $[Cd_2(3-NPA)_2(TBZ)_2(H_2O)_2]{\cdot}2H_2O$(1), $[Zn_2(3-NPA)_2(TBZ)_2]$(2), $[Zn_2O(3-NPA)(TBZ)(H_2O)]_n$(3), $[Co(3-NPA)(TBZ)(H_2O)]_n$(4) (3-$NPAH_2$ = 3-nitrophthalic acid), have been hydrothermally synthesized through the reaction of 3-nitrophthalic acid with divalent transition-metal salts in the presence of N-donor ancillary coligand (TBZ = thiabendazole). As a result of various coordination modes of the versatile 3-$NPAH_2$ and the coligand TBZ, these complexes exhibit structural diversity. X-ray structure analysis reveals that 1 and 2 are 0D molecular rings, while 3 and 4 are one-dimensional (1D) infinite chain polymers. And the weak O-H${\cdots}$O hydrogen bonds and C-H${\cdots}$O nonclassical hydrogen bonds as well as ${\pi}-{\pi}$ stacking also play important roles in affecting the final structure where complexes 1, 3 and 4 have 3D supramolecular architectures, while complex 2 has a 2D supramolecular network. Also, IR spectra, fluorescence properties and thermal decomposition process of complexes 1-4 were investigated.
Keywords
Transition-metal complexes; Coordination modes of the carboxylate groups; 3-Nitrophthalic acid; Thiabendazole;
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