• 제목/요약/키워드: chemical damage

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Ferroelectric characteristics of PZT capacitors fabricated by using chemical mechanical polishing process with change of process parameters (화학적기계적연마 공정으로 제조한 PZT 캐패시터의 공정 조건에 따른 강유전 특성 연구)

  • Jun, Young-Kil;Jung, Pan-Gum;Ko, Pil-Ju;Kim, Nam-Hoon;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.66-66
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    • 2007
  • Lead zirconate titanate (PZT) is one of the most attractive perovskite-type materials for ferroelectric random access memory (FRAM) due to its higher remanant polarization and the ability to withstand higher coercive fields. We first applied the damascene process using chemical mechanical polishing (CMP) to fabricate the PZT thin film capacitor to solve the problems of plasma etching including low etching profile and ion charging. The $0.8{\times}0.8\;{\mu}m$ square patterns of silicon dioxide on Pt/Ti/$SiO_2$/Si substrate were coated by sol-gel method with the precursor solution of PZT. Damascene process by CMP was performed to pattern the PZT thin film with the vertical sidewall and no plasma damage. The polarization-voltage (P-V) characteristics of PZT capacitors and the current-voltage characteristics (I-V) were examined by change of process parameters. To examine the CMP induced damage to PZT capacitor, the domain structure of the polished PZT thin film was also investigated by piezoresponse force microscopy (PFM).

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Investigation of Damage to Polyurethane Topcoat Based on De-icing Cycles (De-icing 횟수에 따른 폴리우레탄 탑코트의 손상 조사)

  • Donghyeon Lee;Joung-Man Park;Hyung Mi Lim;Dong-Jun Kwon
    • Composites Research
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    • v.37 no.3
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    • pp.204-208
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    • 2024
  • De-icing/anti-icing fluid is essential for removing ice formation on aircraft. It chemically removes ice using organic solvents, which can cause damage to the topcoat surface in the process. In this study, glycol-based deicing/anti-icing fluid was used to remove ice, and the resulting damage to the topcoat was examined. USB microscope was used to observe the formation and growth of ice, while a confocal microscope was employed to observe the surface morphology after treatment with de-icing/anti-icing fluid. Additionally, coating thickness measurements and Fourier transform infrared (FT-IR) analysis were conducted to investigate the physical and chemical changes on the surface. The repeated application of de-icing/anti-icing fluid showed a reduction in the ice formation rate and an increase in the growth rate. Damage during the pressurization process and surface damage to the polyurethane topcoat caused by ethylene glycol were observed during the de-icing process. Although no chemical changes were detected, the analysis revealed that surface uniformity decreased, with physical damage such as cracks and undulations forming on the surface. It was confirmed that while de-icing/anti-icing fluid is effective in removing ice, it also causes surface damage.

Time-Efficient Trajectory Planning Algorithms for Multiple Mobile Robots in Nuclear/Chemical Reconnaissance System (화방 정찰 체계에서의 다수의 이동 로봇을 위한 시간 효율적인 경로 계획 알고리즘에 대한 연구)

  • Kim, Jae-Sung;Kim, Byung-Kook
    • Journal of Institute of Control, Robotics and Systems
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    • v.15 no.10
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    • pp.1047-1055
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    • 2009
  • Since nuclear and chemical materials could damage people and disturb battlefield missions in a wide region, nuclear/chemical reconnaissance systems utilizing multiple mobile robots are highly desirable for rapid and safe reconnaissance. In this paper, we design a nuclear/chemical reconnaissance system including mobile robots. Also we propose time-efficient trajectory planning algorithms using grid coverage and contour finding methods for reconnaissance operation. For grid coverage, we performed in analysis on time consumption for various trajectory patterns generated by straight lines and arcs. We proposed BCF (Bounded Contour Finding) and BCFEP (Bounded Contour Finding with Ellipse Prediction) algorithms for contour finding. With these grid coverage and contour finding algorithms, we suggest trajectory planning algorithms for single, two or four mobile robots. Various simulations reveal that the proposed algorithms improve time-efficiency in nuclear/chemical reconnaissance missions in the given area. Also we conduct basic experiments using a commercial mobile robot and verify the time efficiency of the proposed contour finding algorithms.

In vitro metabolism of a new protective agent, KR-31543 in human liver microsomes

  • Ji, Hye-Young;Kim, Sook-Jin;Lee, Hong-Il;Lee, Seung-Seok;Lee, Dong-Ha;Lim, Hong;Lee, Hye-Suk
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.286.2-287
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    • 2003
  • The purpose of this paper was to identify the metabolic pathway of a new neuroprotective agent, KR-31543 for ischemia-reperfusion damage in human liver microsomes and characterize cytochrome P450 (CYP) enzymes involved in the in vitro metabolism of KR-31543 generates two metabolites in human liver microsomes : M1, N-(4-chlorophenyl)-N-(2-methyl-2H-tetrazol-5-ylmethyl)amine and M2, hydroxy-KR-31543. (omitted)

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Hepatoprotective Effects of Ginseng Intestinal Metabolite IH-901 on Chemical-Induced Hepatic Damage

  • Sohn, Uy-Dong;Ko, Sung-Kwon;Choi, Tae-Sik;Im, Byung-Ok ;Han, Sung-Tai;Yang, Byung-Wook;Sung, Jong-Hwan;Kim, Yong-Sung;Woo, Jae-Gwang;Cho, Young-Rae;Min, Young-Sil;Jeong, Ji-Hoon;Lee, Boo-Yong
    • Food Science and Biotechnology
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    • v.14 no.4
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    • pp.558-560
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    • 2005
  • Hepatoprotective effects of white ginseng extract (WGE), and IH-901 (20-O-${\beta}$-D-glucopyranosyl-20(S)-protopanaxadiol) derived from intestinal metabolite of ginsenoside $Rb_1$ were studied using two experimental animal models with chemical-induced hepatic damage. Administration of WGE (200 and 500 mg/kg) and IH-901 (0.01, 0.05, and 0.1 mM/kg) significantly decreased aspartate aminotransferase (AST) and alanine aminotransferase (ALT) levels in acute hepatitic mice induced by $CCl_4$. Administration of WGE (l00 mg/kg) and IH-901 (0.02, 0.04, and 0.08 mM/kg) significantly decreased AST and ALT levels in acute hepatitic rats induced by D-galactosamine. AST and ALT levels of IH-901 groups decreased. These results suggested WGE and IH-901 may have protective effects against chemical-induced hepatic damage.

Observational failure analysis of precast buildings after the 2012 Emilia earthquakes

  • Minghini, Fabio;Ongaretto, Elena;Ligabue, Veronica;Savoia, Marco;Tullini, Nerio
    • Earthquakes and Structures
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    • v.11 no.2
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    • pp.327-346
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    • 2016
  • The 2012 Emilia (Italy) earthquakes struck a highly industrialized area including several thousands of industrial prefabricated buildings. Due to the lack of specific design and detailing for earthquake resistance, precast reinforced concrete (RC) buildings suffered from severe damages and even partial or total collapses in many cases. The present study reports a data inventory of damages from field survey on prefabricated buildings. The damage database concerns more than 1400 buildings (about 30% of the total precast building stock in the struck region). Making use of the available shakemaps of the two mainshocks, damage distributions were related with distance from the nearest epicentre and corresponding Pseudo-Spectral Acceleration for a period of 1 second (PSA at 1 s) or Peak Ground Acceleration (PGA). It was found that about 90% of the severely damaged to collapsed buildings included into the database stay within 16 km from the epicentre and experienced a PSA larger than 0.12 g. Moreover, 90% of slightly to moderately damaged buildings are located at less than 25 km from the epicentre and were affected by a PSA larger than 0.06 g. Nevertheless, the undamaged buildings examined are almost uniformly distributed over the struck region and 10% of them suffered a PSA not lower than 0.19g. The damage distributions in terms of the maximum experienced PGA show a sudden increase for $PGA{\geq}0.28g$. In this PGA interval, 442 buildings were collected in the database; 55% of them suffered severe damages up to collapse, 32% reported slight to moderate damages, whereas the remaining 13% resulted undamaged.

A Study on the Wave Type and the Damage of Hair according to Water content when Heat permanent is treated - Focus on Damaged Hair -

  • Lee, Soon-Hee;Choi, Jung-Myung
    • Journal of Fashion Business
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    • v.12 no.6
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    • pp.11-22
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    • 2008
  • The goal of this study is to provide beauticians with the fundamental material to use effectively heat permanent wave in beauty industry as well as their customer's satisfaction. It carried out an experiment with damaged hair of a woman in her late twenties to investigate the change of physical and morphological characteristics by its water content when performing heat permanent wave. After spreading 0g, 1g, 2g, 3g, and 4g of water on damaged hair respectively, heat permanent wave was treated and the change of hair was observed. The change of physical characteristic was compared through permanent wave form of hair, tensile strength and elongation. The change of morphological characteristic was observed through Scanning Electron Microscope(SEM) and Transmission Electron Microscope(TEM). The result of experiment on the physical specificity revealed that permanent wave form was the most ideal when the water content was 2g, also 3g. Though the materials with much moisture content formed the results were not satisfied. The material with 0g of water content didn't make the wave. In terms of tensile strength and elongation, tensile strength was generally reduced as per the damaged degree of hair. On the contrary, elongation was increased. It observed the changes of morphological characteristic that the damage on hair cuticle was deepen, as its moisture content was decreased, and cuticle's surface was worn away. The observation of fine structure on hair section by transmission electronic microscope also certainly showed the result that damaged hair having experience with chemical treatment had got much damaged to hair cuticle as well as hair cortex. Generally chemical treatment makes hair damaged. Under consideration of this aspect, the ultimate goal of this thesis is to minimize the damage of hair caused by chemical treatment and get the satisfaction on the hair style. According to the result of experiment, the damaged hair whose moisture content was 3g showed the best permanent wave form.

Damage Effects Modeling by Chlorine Leaks of Chemical Plants (화학공장의 염소 누출에 의한 피해 영향 모델링)

  • Jeong, Gyeong-Sam;Baik, Eun-Sun
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.76-87
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    • 2018
  • This study describes the damage effects modeling for a quantitative prediction about the hazardous distances from pressurized chlorine saturated liquid tank, which has two-phase leakage. The heavy gas, chlorine is an accidental substance that is used as a raw material and intermediate in chemical plants. Based on the evaluation method for damage prediction and accident effects assessment models, the operating conditions were set as the standard conditions to reveal the optimal variables on an accident due to the leakage of a liquid chlorine storage vessel. A model of the atmospheric diffusion model, ALOHA (V5.4.4) developed by USEPA and NOAA, which is used for a risk assessment of Off-site Risk Assessment (ORA), was used. The Yeosu National Industrial Complex is designated as a model site, which manufactures and handles large quantities of chemical substances. Weather-related variables and process variables for each scenario need to be modelled to derive the characteristics of leakage accidents. The estimated levels of concern (LOC) were calculated based on the Gaussian diffusion model. As a result of ALOHA modeling, the hazardous distance due to chlorine diffusion increased with increasing air temperature and the wind speed decreased and the atmospheric stability was stabilized.

Seasonal Variations of De-icing Salt Ions Harvested from Soils and Plants according to the Salt Damage of Pinus densiflora f. multicaulis on Roadsides (가로변 반송 염해정도에 따른 토양 및 식물체 내 염류이온의 계절별 변화)

  • Lee, Jae-Man;Park, Sun-Young;Yoon, Yong-Han;Ju, Jin-Hee
    • Journal of Environmental Science International
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    • v.29 no.4
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    • pp.395-402
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    • 2020
  • This study was conducted to analyze seasonal variations of de-icing salt ions harvested from soils and plants according to salt damage of Pinus densiflora f. multicaulis, a evergreen conifer, on roadsides. Pinus densiflora f. multicaulis was divided into three groups referred to SD, ND, and WD (serious salt damage (SD) = 71-100%, normal salt damage (ND) = 31-70%, and weak salt damage (WD) = 0-30%) based on the degree of visible foliage damage, and measured acidity (pH), electrical conductivity(EC), and de-icing salt ions (K+, Ca2+, Na+, and Mg2+) harvested from soils and plants. The results indicated that acidity, electrical conductivity, and de-icing salt ions of soils and plants were significantly affected by seasonal variation and salt damage. In addition, a strong positive liner relationship was observed in plants between the concentration of de-icing salts and salt damage in spring, while the relationship among seasonal variation and salt damage in soil were not significant. The results from this study has important implications for the management of conifer species in relation to salinity and roadsides maintenance.

Effect of damage on permeability and hygro-thermal behaviour of HPCs at elevated temperatures: Part 1. Experimental results

  • Gawin, D.;Alonso, C.;Andrade, C.;Majorana, C.E.;Pesavento, F.
    • Computers and Concrete
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    • v.2 no.3
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    • pp.189-202
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    • 2005
  • This paper presents an analysis of some experimental results concerning micro-structural tests, permeability measurements and strain-stress tests of four types of High-Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$). These experimental results, obtained within the "HITECO" research programme are discussed and interpreted in the context of a recently developed mathematical model of hygro-thermal behaviour and degradation of concrete at high temperature, which is briefly presented in the Part 2 paper (Gawin, et al. 2005). Correlations between concrete permeability and porosity micro-structure, as well as between damage and cracks' volume, are found. An approximate decomposition of the thermally induced material damage into two parts, a chemical one related to cement dehydration process, and a thermal one due to micro-cracks' development caused by thermal strains at micro- and meso-scale, is performed. Constitutive relationships describing influence of temperature and material damage upon its intrinsic permeability at high temperature for 4 types of HPC are deduced. In the Part II of this paper (Gawin, et al. 2005) effect of two different damage-permeability coupling formulations on the results of computer simulations concerning hygro-thermo-mechanical performance of concrete wall during standard fire, is numerically analysed.