• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.1927-1928
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• 2014

• 대한화학회지
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• 제8권1호
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• pp.15-19
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• 1964

Basicities of nine dimethylanilines have been determined in 50, 70, and 90 volume % ethanol, at $25^{\circ},\;30^{\circ},\;35^{\circ},\;and\;40^{\circ}C$. Temperature coefficients were found to be independent of solvent composition, while they showed a linear correlation with basicities of the compounds. Thermodynamic parameters obtained have been used in the discussion of substituent and solvent effects in conjunction with the general equation derived in the preceding papers.

• Bulletin of the Korean Chemical Society
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• 제7권1호
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• pp.20-23
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• 1986

A reduced condition for liquid-gas phase transition from the singularity of compressibility is derived using diagrammatic approach and is examined in the hard sphere system. The condition turns out that the Percus-Yevick and the Hyper-Netted-Chain approximation never conceive the idea of phase transition, and explains that the liquid-gas transition does not exist in hard sphere system. The solid-fluid transition is considered on the viewpoint of correlation function and diagrammatic analysis.

• Bulletin of the Korean Chemical Society
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• 제10권1호
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• pp.47-50
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• 1989

The methanolysis reactions of phenylacetyl chlorides have been investigated in methanol-acetonitrile mixtures at temperatures ranging - $15.0-0.0^{\circ}C.$ Substituent and solvent effects on the rate supported an associative $S_N2$ mechanism for the solvolysis. Activation parameters indicated that the reaction is entropy controlled, while the a/s ratios of the Taft's solvactochromic correlation proved to be remarkably constant with a typical value of 0.50 that is consistent for the reactions proceeding by a typical $S_N2$ path.

• Bulletin of the Korean Chemical Society
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• 제22권8호
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• pp.816-820
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• 2001

A new copper hexacyanoferrate modified electrode was constructed by mechanical immobilization. The modified electrode was characterised by cyclic voltammetric experiments. Electrocatalytic oxidation of glutathione was effective at the modified electrode at a significantly reduced overpotential and at broader pH range. The modified electrode shows a stable and linear response in the concentration range of 9 ${\times}$10-5 to 9.9 ${\times}$10-4M with a correlation coefficient of 0.9995. The modified electrode exhibits excellent stability, reproducibility and rapid response and can be used in flow injection analysis for the determination of glutathione.

• Bulletin of the Korean Chemical Society
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• 제15권10호
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• pp.868-873
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• 1994

We have re-examined the linear solvation energy relationships in reversed phase liquid chromatography by considering various solutes including quite a number of compounds of strong hydrogen bond capability. We observed that solutes of strong hydrogen bond ability should be excluded in order to obtain resonable correlations between In k' and solute polarity parameters and that inclusion of one or two such solutes causes severe distortions of correlation results. This anomaly may be due to existence of residual silanol groups in the stationary phase, that is, their specific interactions with solutes.

• Bulletin of the Korean Chemical Society
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• 제18권9호
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• pp.1028-1031
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• 1997

Electrostatic interaction is a very important parameter for the membrane selectivity. In this work, the electrical double layer establishment on the surface of metal oxide material from the Stern-Grahame model has been described. Then, some examples of rejection using micro and mesoporous ceramic membranes have been given. A correlation between the charges of the membrane material and the species to be filtered has been precised. Two rejection mechanisms have to be taken into account the size of the solutes and the electrostatic interactions.

• Bulletin of the Korean Chemical Society
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• 제19권4호
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• pp.434-436
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• 1998

The mechanism of nucleophilic displacement was studied by using three variable systems of ${\rho}_X,\; {\rho}_Y,\; and {\rho}_Z$ obtained from the change of substituent X, Y, and Z for the reaction of (Z)-substituted benzyl (X)-benzensulfonates with (Y)-substituted thiobenzamides in acetone at 45 ℃. The results ${\rho}_Z$<0 and ${\rho}_YZ$>${\rho}_XZ$ indicate that this reaction series proceeded via a dissociative $S_N2$ mechanism. The prediction of the movement of TS by using the sign of ${\rho}_XZ{\cdot}{\rho}_{YZ}$ accorded with the Hammond postulate.

• Bulletin of the Korean Chemical Society
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• 제21권5호
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• pp.493-496
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• 2000

By use of the rotational distribution expression previously derived based on the collisional time correlation function formalism, the rotational distributions of $CO_2$ vibrational ground state (00°0) after collisions with hot H, D, or Cl atom have been constructed. Energy and rotational quantum number parameters which can characterize the rotational distributions are also calculated and compared with those deduced from the experimental distribution. The results from this work would be very useful in predicting the rotational distributions in the lower J region for which experimental data are not available due to the interference from the ambient $CO_2$.

• Bulletin of the Korean Chemical Society
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• 제16권11호
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• pp.1113-1118
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• 1995

The Schlo'gl model with the first order transition for a photochemical reaction is considered to study the dynamic behaviors in the neighborhood of the Gaussian white noise by obtaining the explicit results of the time-dependent variance and time correlation function with the aid of approximate methods based on the stationary properties of the system. Then, we discuss the effect of external noise strength on the stability of the model at steady states in detail.