• Title/Summary/Keyword: chemical communication

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A study on phase transition of Hydrogel: (I)Volume Phase Transition of N-Isopropylacrylamide gel (수화겔의 상전이에 관한 연구: (I)폴리(N-이소프로필아크릴아미드)겔의 부피상전이)

  • Park, Sang-Bo;Min, Seong-Kee
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.1
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    • pp.11-20
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    • 2003
  • Equilibrium swelling curves of N-isopropyl acrylamide(NIPA) gel and its ionized copolymer gels were obtained as a function of temperature. Discontinuous volume changes of the gels were observed. Phase transition temperature was increased with the ionized counter parts of the gels. Equilibrium swelling of ionized copolymer gel cylinder was found to depend strongly on their diameters. Crosslinking density of NIPA gel was adjusted by increasing N,N'-methylenebisacrylamide(BIS). Phase transition temperature was increased with the crosslinking density.

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The Statistical Mechanics of the Rubber Elasticity which is Affected by the Entanglement Effects (고무탄성에 영향을 미치는 사슬 얽힘 효과에 대한 통계역학적 고찰)

  • Park, Sang-Bo;Lee, Tae-Hong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.1
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    • pp.45-58
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    • 2003
  • The entanglement effects were described by means of holes through which the network chain must pass. Inhomogeneous entanglement effects were related to the hole distributions on the surface and in the center of spheres in the network chains. It was assumed that holes were subjected to the affiance deformation and the network chains were gaussian distribution. The results of this model calculation was compared with the compression- extension experimental data of PDMS (polydimethyl siloxane) rubber, and then hole's relative position was known to be in the center of two adjacent holes.

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A study on phase transition of Hydrogel: (II)Solubility of N-Isopropylacrylamide Gel (수화겔의 상전이에 관한 연구 : (II)폴리(N-이소프로필아크릴아미드)겔의 용해도)

  • Park, Sang-Bo;Hwa, Won-Jo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.21 no.1
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    • pp.81-90
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    • 2003
  • To understand the thermoresponsive volume phase transition of an N-isopropyl acrylamide(NIPA) gel on water, the solubility parameter of neutral NIPA gel was determined by swelling the gel with various solvents. Water was found not to be a good solvent for NIPA gel. Equilibrium swelling curves of NIPA gel were respectively obtained by immersing in pure water, ethanol, n-propanol and some mixed solvents. On adding a small amount of alcohols to water, volume phase transition of NIPA gel in water was changed. Phase transition temperature of this gel was decreased with the increase of the carbon number of alcohol.

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Properties of Urethane-Based IPN Elastomers (우레탄을 기초로 한 IPN 탄성체의 성질)

  • Min, Seong-Kee;Park, Chan-Young
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.2
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    • pp.37-54
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    • 2004
  • IPNs have interpenetrating motion and phase separation behavior of independent polymers, respectively, and also these are affected by the physical interaction of polymer components. First of all, 2- and 3-component IPNs based on PU are prepared by combination with two or three components of PU, PMMA, PS and epoxy resin. And then the entire physical properties concerning morphological and mechanical behaviors of these IPNs are measured by employing FT-IR, SEM, Rheovibron, and DSC, etc. Compared with pure component, Tg's of IPN are shifted to higher temperature in all IPN kinds, and these are considered in attribution to internal movement of glass transition temperature or partial phenomenon of interpenetration. Rheovibron measurement results in a broader distribution with peaks of tan${\delta}$ or E", and this morphologically represents a medium degree of partially mixed IPNs in confirmation of SEM photographs.

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A Review on Silicon Oxide Sureface Passivation for High Efficiency Crystalline Silicon Solar Cell (고효율 결정질 실리콘 태양전지 적용을 위한 실리콘 산화막 표면 패시베이션)

  • Jeon, Minhan;Kang, Jiyoon;Balaji, Nagarajan;Park, Cheolmin;Song, Jinsoo;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.6
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    • pp.321-326
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    • 2016
  • Minimizing the carrier recombination and electrical loss through surface passivation is required for high efficiency c-Si solar cell. Usually, $SiN_X$, $SiO_X$, $SiON_X$ and $AlO_X$ layers are used as passivation layer in solar cell application. Silicon oxide layer is one of the good passivation layer in Si based solar cell application. It has good selective carrier, low interface state density, good thermal stability and tunneling effect. Recently tunneling based passivation layer is used for high efficiency Si solar cell such as HIT, TOPCon and TRIEX structure. In this paper, we focused on silicon oxide grown by various the method (thermal, wet-chemical, plasma) and passivation effect in c-Si solar cell.

Implementation of Elbow Method to improve the Gases Classification Performance based on the RBFN-NSG Algorithm

  • Jeon, Jin-Young;Choi, Jang-Sik;Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.25 no.6
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    • pp.431-434
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    • 2016
  • Currently, the radial basis function network (RBFN) and various other neural networks are employed to classify gases using chemical sensors arrays, and their performance is steadily improving. In particular, the identification performance of the RBFN algorithm is being improved by optimizing parameters such as the center, width, and weight, and improved algorithms such as the radial basis function network-stochastic gradient (RBFN-SG) and radial basis function network-normalized stochastic gradient (RBFN-NSG) have been announced. In this study, we optimized the number of centers, which is one of the parameters of the RBFN-NSG algorithm, and observed the change in the identification performance. For the experiment, repeated measurement data of 8 samples were used, and the elbow method was applied to determine the optimal number of centers for each sample of input data. The experiment was carried out in two cases(the only one center per sample and the optimal number of centers obtained by elbow method), and the experimental results were compared using the mean square error (MSE). From the results of the experiments, we observed that the case having an optimal number of centers, obtained using the elbow method, showed a better identification performance than that without any optimization.

Optical Property of $TiO_2$ Thin Film growing by Atmospheric Pressure Chemical Vapor Deposition (APCVD법으로 성장된 $TiO_2$ 박막의 광학적 특성)

  • Sim, You-Mi;Lee, Kwang-Soo;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.212-213
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    • 2007
  • $TiO_2$ 박막은 좋은 내구성 전기적 특성과 함께 가시광선 영역에서의 높은 투과율, 높은 굴절률을 나타내어 태양전지의 반사 방지막, TFT 절연막, 광학적 필터에 쓰이는 다층 광학적 코팅 재료 등에 쓰이며 높은 이용가치로 인해 이에 대한 많은 연구가 이루어지고 있다. 본 논문에서는 APCVD(Atmospheric Pressure Chemical Vapor Deposition)법을 이용하여 $200^{\circ}C$에서 $350^{\circ}C$까지 증착 온도를 변화시키며 $TiO_2$ 박막을 제조할 때 나타나는 광학적 특징 변화에 대한 연구를 수행하였다. 온도가 증가할수록 굴절률은 커지고 $TiO_2$, 박막안의 기공과 결함의 비율은 감소하였다. 광투과율은 UV범위 이후에서 급격한 증가를 보였으며 온도가 증가함에 따라 흡수단이 긴 파장쪽으로 이동하였다. 흡수단의 증가는 광학적 밴드갭과 연관되며 온도가 증가할수록 광학적 밴드갭은 낮아지는 것을 확인할 수 있었다.

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Characteristics of Electromagnetic Wave Absorber Sheet for 2.4 GHz Wireless Communication Frequency Bands Using Fe Based Alloy Soft Magnetic Metal Powder (Fe-계 연자성 금속분말을 이용한 2.4 GHz 대역 무선통신용 전파 흡수체의 특성 평가)

  • Kim, ByeongCheol;Seo, ManCheol;Yun, Yeochun
    • Korean Journal of Materials Research
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    • v.29 no.9
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    • pp.532-541
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    • 2019
  • Information and communication technologies are developing rapidly as IC chip size becomes smaller and information processing becomes faster. With this development, digital circuit technology is being widely applied to mobile phones, wireless LANs, mobile terminals, and digital communications, in which high frequency range of GHz is used. In high-density electronic circuits, issues of noise and EMC(Electro-Magnetic Compatibility) arising from cross talk between interconnects or devices should be solved. In this study, sheet-type electromagnetic wave absorbers that cause electromagnetic wave attenuation are fabricated using composites based on soft magnetic metal powder and silicon rubber to solve the problem of electromagnetic waves generated in wireless communication products operating at the frequency range of 2.4 GHz. Sendust(Fe-Si-Al) and carbonyl iron(Fe-C) were used as soft magnetic metals, and their concentrations and sheet thicknesses were varied. Using soft magnetic metal powder, a sheet is fabricated to exhibit maximum electromagnetic attenuation in the target frequency band, and a value of 34.2dB(99.9 % absorption) is achieved at the target frequency.

Relation between Regression-based Food Additives and Carcinogenesis using Big Data Analysis (빅 데이터 분석을 활용한 회귀분석 기반 식품 첨가물과 암 발생 관계)

  • Lee, Kuk Hyung;Lee, Jun-Hee;Kim, Jeong-Joon;Kim, Young-Gon
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.1
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    • pp.203-210
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    • 2018
  • Well-Bing Many consumer forms of natural foods that are not chemically processed due to heat are becoming popular. However, it is very difficult to find foods that do not contain chemical food additives in the modern. Also, there are many products that do not have proper marking of ingredients of chemical food additives or are omitted from marking. Based on the annual data on chemical food additive consumption in Korea, this paper will examine the occurrence of cancer, which is emerging by additives, through time series analysis and regression analysis, one of the big data analysis techniques. Of the total population.

Evaluation of 1.3-㎛ Wavelength VCSELs Grown by Metal Organic Chemical Vapor Deposition for 10 Gb/s Fiber Transmission

  • Park, Chanwook;Lee, Seoung Hun;Jung, Hae Won;An, Shinmo;Lee, El-Hang;Yoo, Byueng-Su;Roh, Jay;Kim, Kyong Hon
    • Journal of the Optical Society of Korea
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    • v.16 no.3
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    • pp.313-317
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    • 2012
  • We have evaluated a 1.3 ${\mu}m$ vertical-cavity surface-emitting laser (VCSEL), whose bottom mirror and central active layer were grown by metal organic chemical vapor deposition (MOCVD) and whose top mirror was covered with a dielectric coating, for 10 Gb/s data transmission over single-mode fibers (SMFs). Successful demonstration of error-free transmission of the directly modulated VCSEL signals at data rate of 10 Gb/s over a 10 km-long SMF was achieved for operating temperatures from $20^{\circ}C$ to $60^{\circ}C$ up to bit-error-rate (BER) of $10^{-12}$. The DC bias current and modulation currents are only 7 mA and 6 mA, respectively. The results indicate that the VCSEL is a good low-power consuming optical signal source for 10 GBASE Ethernet applications under controlled environments.