• 제목/요약/키워드: chemical bleaching

검색결과 121건 처리시간 0.03초

마찰과 세탁에 의한 극세섬유 직물의 표면과 촉감변화에 관한 연구 (End Use Tactile Property of the Split-type Nylon/PET Microfiber Fabrics)

  • 오경화;윤재희
    • 한국의류학회지
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    • 제28권3_4호
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    • pp.539-545
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    • 2004
  • In this study, the effect of washing, bleaching, and abrasion on tactile and the water absorption properties of the split-type Nylon/Polyester (N/P) microfiber pile-knit was investigated under various enduse conditions. We examined the water absorption and surface properties of PET microfiber which will be very useful in the future. We also studied the variations of their performance during usage caused by friction and repeated washing, regard to all kinds of physical, chemical changes which will appear while using those textiles. Progress in further splitting of PET microfiber fabric is observed with increases in the number of washing and bleaching cycles, and treatment temperature. Initial water absorption (%) was increased with progress in splitting, which provided efficient capillary channel. Surface properties were varied with additional splitting by washing and abrasion. Formation of pilling and splitting by abrasion increase surface roughness, diminishing tactile property, and reduced water absorption property. The current results from this study is expected to provide the appropriate washing management guide to consumers, and to inform end-use performance of product to a producer for improving product quality.

Optical Bleaching Behaviour of Neutron Irradiated KCI Single Crystal

  • Suh, In-Suck
    • Nuclear Engineering and Technology
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    • 제5권4호
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    • pp.286-290
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    • 1973
  • 염화카리움 단결정중 수산화물을 제거하고 이를 극미량의 음이온 불순물을 가하여 결정내에 점결함을 형성시키는 전 처리를 하였다. 이들 시료를 빛이 차단된 상태에서 액체질소 온도에서 원자로에 조사하였고 조사된 시료를 자외선으로 쪼인다음 4가지 산화상태 즉 -2, 0, +4, +6가의 $^{35}$ 를 화학적으로 상호분리하여 방사능을 계측하였다. 음이온 불순물로 처리된 시료는 순수한 결정에 비하여 낮은 산화상태 (-2가)의 $^{35}$ S 더 많이 생성되었고, 음이온 불순물로 처리된 시료 및 순수한 결정 모두를 자외선으로 쪼였을 때 30분까지는 -2가의 $^{35}$ S가 급격히 증가함을 알았다.

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화학처리에 의한 케나프 섬유인 물리적 특성인 변화 (The Change of Physical Characteristics of Kenaf Fiber by the Chemical Processes)

  • 유혜자;이혜자;김정희;안춘순;송경헌;한영숙
    • 한국의류학회지
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    • 제30권7호
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    • pp.1025-1033
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    • 2006
  • Kenaf bast can be obtained by decortication of Kenaf stem. Kenaf fibers are much more rough than cotton fiber because they include impurities as pectin, lignin and hemicellulose besides cellulose. The purpose of this research is to investigate the distribution of kenaf fiber length and diameter during the processes of removing impurities. To remove pectin, kenaf bast was retted chemically. A half of the retted kenaf fiber bundle were scoured and bleached. The other half one were treated with $NaClO_2$ solution to remove lignin, and were treated with sodium hydroxide solution to remove hemicellulose. Four kinds of specimens that were obtained for investigating physical characteristics. Length and diameter of 100 fibers on each specimen was measured. The tensile strength of 100 fiber bundles were measured. And also the color values of them were measured with spectrocolorimeter. The length of retted kenaf fiber was 16.97cm. Then it decreased to 11.43cm after bleaching. Kenaf fiber bundles could be finer by chemical processes that remove non-cellulosic materials. The thickness of retted fiber was $132{\mu}m$. And after undergoing the chemical processes to remove non-cellulosic materials, the thickness of kenaf fiber became finer as $73{\mu}m$. Tensile strength of the retted kenaf fiber bundles was 11.37Mpa. The retted kenaf fiber lost their strength as 22.6% by bleaching and as 18.3% by treatment for removing lignin. The retted kenaf fiber showed low whiteness as 56.48 of L*value. After bleaching, the kenaf fibers have creamy white color and their whiteness got 90.02 of L*value. After the treatment for removing hemicellulose, the kenaf fibers also have creamy white color and their whiteness got L* value of 79.02.

청변균 및 살균제처리재의 펄프화특성 (Pulping Features of Blue-stained and Fungicide-treated Woods)

  • 조남석;정선화
    • 펄프종이기술
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    • 제37권3호
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    • pp.66-73
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    • 2005
  • This study was performed to understand the changes in wood extractives, mainly acetone extracts, in pine woods (Pinus densiflora and Pinus rigida) treated by three blue stain fungi (BSF) such as native BSF in Korea, Leptographium sp., screened Albino strain(BSFcs-1) and commercial Cartapip and fungicide, Wood guard. In addition their pulping and bleaching properties were investigated. BSF treatment has significantly reduced acetone extracts, $25.1{\sim}30.4%$ decreasing in red pine and $22.9{\sim}28.1%$ in pitch pine. Three week aging treatment showed about 20% decreasing in red pine and 19.3% in pitch pine. There were not so significant differences in extracts reduction among native BSF and Albino-type strains (Albino strain, BSFcs-1, and commercial Cartapip). But fungicide, Wood guard, treated wood showed relatively lower decreasing rates of extractives, 14% in red pine and 10.1% in pitch pine. Therefore it is understandable that the fungicide could protect the wood from blue stain fungi attack, but has no effect on its extractive reduction. Concerned to pulping properties of BSF and fungicide treated woods, red pine and pitch pine, optimum pulping condition was 20% active alkali, wood to liquor ratio 1 to 6, $170^{\circ}C$, and 2.5 hr. In the case of BSF woods, optimum pulping condition was same as the sound wood, $43.5{\sim}45%$ of pulp yields and $1.3{\sim}1.45%$ of rejects. Screened pulp yield of fungicide treated wood was lower than those of BSF treated woods. Rejects in pulps were higher in fungicide-treated wood than BSF treated woods. Bleaching pulp yields were ranged of 92 to 93.5%. BSF, Cartapip and fungicide treated woods resulted in lower brightness of $55{\sim}58%$, but Albino-type strain(BSFcs-1) $61.3{\sim}62.3%$, very similar to untreated one. Therefore bleaching chemicals could be saved in the processing of chemical pulping.

탈색모발의 인장강도에 관한 연구 (Study on the Tensile Strength of Bleached Hair)

  • 이귀영;장병수
    • Applied Microscopy
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    • 제38권3호
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    • pp.251-257
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    • 2008
  • 본 연구는 탈색회수에 따른 모발의 인장강도 변화를 측정하여 건강모발과 비교하였으며, 인장시험 결과 절단된 모발의 단면을 주사전자현미경을 사용하여 형태학적 변화 양상을 관찰하였다. 인장시험에서 건강모발은 인장강도가 $14.66g/cm^2$으로 측정되었고, 탈색 1회, 2회, 3회 모발은 각각 $12.95g/cm^2$, $12.61g/cm^2$, $11.43g/cm^2$으로 나타났다. 결국 탈색모발은 탈색 횟수가 증가할수록 인장강도가 감소하였다. 건강모발과 탈색모발의 인장강도 시험 후 절단된 모발 단면의 주사전자현미경 관찰에서 건강모발은 표면의 큐티클세포들이 들떠서 분리되어 있었으며, 탈색모발의 표면은 건강모발의 표면보다 더 심하게 큐티클세포들이 분리에 있었다. 탈색모발의 큐티클세포들은 모발표면의 바깥쪽으로 심하게 휘어져 분리되어 있었다. 큐티클세포의 분리는 세포막사이 복합체의 파괴에 의해서 일어났으며 큐티클세포의 세포질의 일부인 내큐티클의 파괴에 의한 분리는 일어나지 않았다.

ULTRAVIOLET MICROSCOPIC STUDY ON LIGNIN DISTRIBUTION IN THE FIBER CELL WALL OF BCTMP

  • Seung-Lak YooN;Yasuo KOJIMA;Lee, Seon-Ho
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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    • pp.375-380
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    • 1999
  • In order to improve the optical properties of high yield pulp, bleached chemi-thermo-mechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching. This pulp was used for the evaluation of the improvement of optical properties, chemical characteristics of lignin in fiber, and the relationship between lignin and optical properties in fiber cell wall. By hydrogen peroxide treatment, the brightness was improved, but the post color number (PC No.) was not. There was little improvement on optical properties by ozone treatment, but his could be solved by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make nay change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved due to the removal of non-aromatic conjugated structure.

현상처리된 치과용 방사선필름의 크롬 증강효과에 대하여 (CHROMIUM INTENSIFICATION OF A PROCESSED DENTAL RADIOGRAPH)

  • 박명선;박태원
    • 치과방사선
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    • 제20권2호
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    • pp.211-217
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    • 1990
  • This study was undertaken to determine (1) the usefulness of chromium intensifier to improve the dignostic quality of light radiograph; (2) the effect of chromium intensifier on density, contrast; and (3) the effect of various chemical concentrations on density. The following results obtained: 1. CHROMIUM INTENSIFIER is useful for intensifying and improving the diagnostic quality of a light dental radiograph. 2. The degree of intensification can be controlled by varying bleaching time, repeating the processing, varying the proportions of the potassium bicarbonate and hydrochloric acid solutions. 3. The image produced is black and permanent. 4. The intensifier increases density and contrast.

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해수를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구 (The study of chemical treatment of pulp mill bleaching waste liquor using sea water)

  • 정병곤;이헌모;윤종호
    • 환경위생공학
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    • 제12권1호
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    • pp.39-48
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    • 1997
  • The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

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목질분해효소에 의한 고지의 재활용 기술연구(제2보)-조효소가 폐지의 표백 특성 및 종이의 물성에 미치는 영향- (Studies on the Recycling Technology of the Waste Paper with Wood Degradable Enzyme(II)-Effect of Crude Enzyme on the Bleaching Characteristics and Physical Properties of Waste Paper-)

  • 양재경;장준복;엄태진
    • 펄프종이기술
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    • 제30권3호
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    • pp.15-21
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    • 1998
  • Crude enzymes of Trichoderma viride and Phanerochaete chrysosporium were evaluated for their effect to brightness and physical properties of recycled pulp from newspaper and corrugated container board. The brightness of recycled pulp from newspaper increased with crude enzymes from Trichoderma viride and Phanerochaete chrysosporium. The brightness of recycled pulp of corrugated container board increased with crude enzyme from Phanerochaete chrysosporium, but decreased with crude enzyme from Trichoderma viride. The Δbrightness with chemical bleaching of crude enzyme treated pulp was lower than that of heat killed enzyme treated pulp, but the final brightness of pulp was increased. Modification of recycled paper with crude enzymes can result in a substantial increase in physical properties with little no loss in pulp freeness.

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KS-62 균주에 의한 펄프 표백 폐액처리에 관한 연구 (Studies on the Treatment of Pulp Bleaching Effluent with KS-62 Fungus)

  • 조준형;은주영
    • 펄프종이기술
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    • 제32권1호
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    • pp.86-93
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    • 2000
  • High Colored kraft bleaching effluent is one of the main constrains in pulp and paper industry due to its dissloved lignin derivatives. The degradation of lignin in pulp and paper mill effluent is mainly caused by white-rot fungi. This paper showed that the treatment with KS-62 fungus significantly reduced the color and chemical oxygen demand in the effluent. The amounts of Mn ions in the wastewater would play roles in the induction and activity of MnP (Managanese peroxidase). Extracellular MnP was isolated from the fungus KS-62. The treatment with the MnP had the most effective decolorizatiion in the wastewater treatment using nutrients mediu.

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