• 제목/요약/키워드: chemical analysis

검색결과 12,654건 처리시간 0.05초

Pore Distribution of Porous Silicon layer by Anodization Process

  • Lee, Ki-Yong;Chung, Won-Yong;Kim, Do-Hyun
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.494-496
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    • 1996
  • The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

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A Comparative Study on the Risk(Individual and Societal) Assessment for Surrounding Areas of Chemical Processes (화학공정 주변지역에 미치는 위험성(사회적 위험성 및 개인적 위험성) 평가방법에 관한 비교 연구)

  • 김윤화;엄성인;고재욱
    • Journal of the Korean Society of Safety
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    • 제10권1호
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    • pp.56-63
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    • 1995
  • Two methods of the numerical method of CPQRA(Chemical Process Quantitative Risk Analysis) and the manual method of IAEA(International Atomic Energy Agency) were used to estimate the individual risk and societal risk around the chemical plant. Where, the CPQRA is introduced to verify the theoritical background of the manual of international atomic energy agency. The Gaussian plume model which has a weather stability class D with velocity of 5m/s was applied to calculate dispersion of hazard material. Also, 8-point method was employed to the effects of accidents for wind distribution. Furthermore, historical record, FTA(Fault Tree Analysis) and ETA(Event Tree Analysis) were used to estimate the probability or frequency of accidents. Eventually, the individual risk shows isorisk contour and the societal risk shows F-N curve around hazard facility, especially in chemical plants. Caulculated results, which both individual and societal risk, by using IAEA manual show simillar results to those of calculation by numerical method of CPQRA.

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Chemical Analysis of Woody Resource Seperated from Municipal Soild Waste (도시 고체 폐기물에서 분리한 목질계 자원의 화학적 분석)

  • Shin, Soo-Jeong;Park, Jong-Moon;Choi, Tea-Ho;Kim, Byung-Ro;Cho, Dae-Haeng;Kim, Yong-Hwan
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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    • pp.43-47
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    • 2011
  • In woody waste separated from municipal solid waste, medium density fiberboard was major contributors with particleboard, paper, plywood and log, with different composition based on collected period. In chemical compositional analysis of woody waste, it was similar to softwood based on carbohydrate composition analysis. Based on the carbohydrate composition, saccharified solution from MWW could be good resource for biorefinery.

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Analysis of Chemical Components and Microstructure Characteristics of CBS Dust (CBS-Dust의 화학성분 및 미세구조 특성 분석)

  • Han, Jun-Hui;Lee, Young-Jun;Hyun, Seung-Yong;Lee, Dong-Joo;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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    • pp.180-181
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    • 2019
  • In this study, in order to find new uses for CBS dust, the chemical components of CBS dust were analyzed and effectively proposed a method. Chemical analysis shows that CBS dust contains a large amount of alkali in addition to chloride therefore, if CBS dust is used for secondary concrete products that use high amounts of mixed materials without rebars, it will be found that it can be used effectively for enhancing strength by active alkali.

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Pozzolanicity identification in mortars by computational analysis of micrographs

  • Filho, Rafael G.D. Molin;Rosso, Jaciele M.;Volnistem, Eduardo A.;Vanderlei, Romel D.;Longhi, Daniel A.;de Souza, Rodrigo C.T.;Paraiso, Paulo R.;Jorge, Luiz M. de M.
    • Computers and Concrete
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    • 제27권2호
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    • pp.175-184
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    • 2021
  • The incorporation of pozzolans to Portland cement pastes adds value in the development of new materials for the construction industry. This study presents a new computational method, complementary to the pozzolanic identification by compressive strength at 28 days method, for supporting the validation of pozzolanic mortars for non-structural purposes. An algorithm capable of classifying the pixels of micrographs of specimens fragments was developed. Therefore, comparative analyses were generated from fractional Gaussian representations in four intervals of the same amplitude that indicated the predispositions to form larger void indices (intervals 1 and 2). The results showed that the computational method indicators are in accordance with the physical and chemical indicators.

A Study on the Quality Assuranc of Chemical Analysis Data of Precipitation Samples (강수 분석자료의 신뢰성 검토에 관한 연구)

  • 강공언
    • Journal of environmental and Sanitary engineering
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    • 제10권3호
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    • pp.85-98
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    • 1995
  • In order to ensure that all major cations and anions were accurately measured, the quality assurance checks of chemical analysis data by considering ion and conductivity balance of each precipitation sample were performed. To check the quality assurance of chemical analysis data, precipitation samples were collected by wet- only precipitation sampler at Seoul site and their chemical components were analyzed. By checking the problems for the screening methods of chemical analysis data used until recently, the f value expressed as the ratio of the sum of cations and anions equivalent concentration( $\Sigma $C/$\Sigma $A ) was found to be not ap priorate for data screening. Also, the scattering plot between cation and anion equivalent concentrations in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a set of samples of various concentration levels.4 more appropriate value was therefore required, h value is defined as (A-C)/C for C≥A and ( A-C)/A for C<4. This value was showed to check the ion balance in a viewpoint of quantitative as well as qualitative and to be useful in applying this expression to a measurement data set. However, the standard o( data screening must vary in response to the ion concentration of sample. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance evaluating by h value and the electrical conductivity. As these quality assurance checks were applied to Seoul data serf 67 valid samples were obtained. The result of statistical summary in the analytical parameter of precipitation samples collected for a certain period was found to be computed in the precipitation volume- weighted mean( VWM) rather than the arithmetic mean( AM), but PH In the VWM of hydrogen ion concentration. The annual VWM of pH values was 5.0(4.9 ∼ 5.1).

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Analysis of the hazardous RoHS materials in polyethylene and polypropylene samples by bench-top and portable XRF methods (탁상형 및 휴대형 X-선 형광 분석기를 이용한 폴리에틸렌 및 폴리프로필렌 시료 중 RoHS 규제 물질의 비교 분석)

  • Choi, Soo-Jung;Kim, Chong-Hyeak;Lee, Sueg-Geun;Kang, In-Sung
    • Analytical Science and Technology
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    • 제23권1호
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    • pp.74-82
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    • 2010
  • As a basic research for development of the domestic portable XRF spectrometer, we discussed the analytical results of bench-top and portable XRF methods for RoHS materials of the Cd, Pb, Hg, Cr(IV), polybrominated biphenyls(PBB) and polybrominated diphenyl ehters(PBDE). The instrumental parameters such as measurement time of bench-top and portable XRF were optimized using certified reference materials of polyethylene and polypropylene with 5 hazardous materials of 0~1,200 mg/kg. The quantitative analysis of total-Cr, total-Br, Cd, Hg and Pb in certified reference materials and plastic samples were compared by empirical method, fundamental parameter method of bench-top XRF and portable XRF.

Thermochemical Performance Analysis of Liquid Rocket Nozzle (액체로켓 노즐의 열화학적 성능 해석)

  • Choe,Jeong-Yeol;Choe,Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • 제31권1호
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    • pp.85-96
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    • 2003
  • For a design of rocket engine nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be used as an efficient design tool for predicting maximum thermodynamic performance of the nozzle. 10 this study, a chemical equilibrium flow analysis code was developed for the design of hydrocarbon fueled rocket engines. 10 oder to understand the thermochemical characteristics occurring in a nozzle through the expansion process, such as recombination of chemical components and the accompanying energy recovery, chemical equilibrium flow analysis was carried out for the KSR-III rocket engine nozzles together with frozen flow and non-equilibrium flow analyses. The performance evaluation based on the present KSR-III nozzle flow analyses has provided an understanding of the thermochemical process in the nozzle and additionally, it has confirmed that the newly designed nozzle shape modified to have a reduced exit area ratio is an adequate design for obtaining an increased ground thrust.

Qualitative Hazard Analysis for a Batch Radical Reaction Process using HAZOP Method (HAZOP 기법을 이용한 회분식 라디칼 반응 공정에 대한 정성적 위험성 평가 방법 연구)

  • Park, KyungMin;Lee, DongKyu;Lee, JoonMan;Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • 제20권2호
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    • pp.385-393
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    • 2019
  • Potential fire, explosion and safety hazards exist in medium- or small-scale chemical plants using radical batch reaction processes due to the various conditions of materials, works or products. To minimize the potential damage, a study was conducted on qualitative hazard analysis using the HAZOP technique, which is a typical method for a qualitative risk assessment and analysis of the potential risks encountered in these chemical plants. For this purpose, a domestic chemical plant, which produces the acrylic resin by a radical batch reaction process, was selected and a risk assessment and analysis according to the procedure of HAZOP method was performed for the process. As the result of the study, to prevent the hazard, the input of inert gas and the installation of a pressure gauge were indispensable. In addition, the initiator and monomer should also be separated, and inhibiting substances and equipment are also necessary to prevent a runaway reaction.

Comparison of the Heavy Metal Analysis in Soil Samples by Bench-Top ED-XRF and Field-Portable XRF (Bench-Top ED-XRF 및 휴대용 XRF를 이용한 토양 시료 중의 중금속 비교 분석)

  • Choi, Soo-Jung;Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • 제22권4호
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    • pp.293-301
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    • 2009
  • As a basic research for development of the domestic field-portable XRF spectrometer, we discussed the analytical results of bench-top ED-XRF and field-portable XRF method for polluted heavy metals such as Cr, As, Se, Hg, Pb, Cd in soil samples. To obtain the best performance of the XRF spectrometer, the instrumental parameters of X-ray tube-voltage and measurement time were optimized for 6 heavy-metal elements in soil using certified reference material. The quantitative analysis of Cr, As, Se, Hg, Pb, Cd concentration in certified reference materials and soil samples were compared by empirical method and fundamental parameter method.