• 제목/요약/키워드: chemical agents

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지표면 화학작용제 비접촉 탐지를 위한 단자외선 라만분광법 연구 (Deep UV Raman Spectroscopic Study for the Standoff Detection of Chemical Warfare Agents from the Agent-Contaminated Ground Surface)

  • 최선경;정영수;이재환;하연철
    • 한국군사과학기술학회지
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    • 제18권5호
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    • pp.612-620
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    • 2015
  • Short-range detection of chemical agents deposited on ground surface using a standoff Raman system employing a pulsed laser at 248 nm is described. Mounted in a vehicle such as an NBC reconnaissance vehicle, the system is protected against toxic chemicals. As most chemicals including chemical warfare agents have unique Raman spectra, the spectra can be used for detecting toxic chemicals contaminated on the ground. This article describes the design of the Raman spectroscopic system and its performance on several chemicals contaminated on asphalt, concrete, sand, etc.

양식산 무지개송어에서의 항생제와 말라카이트 그린 잔류량 조사 (The Residues of Antibiotics (Tetracycline, Oxolinic Acid and Ciplofloxacin) and Malachite Green in Cultured Rainbow Trout)

  • 김영목;이명숙;정용현
    • 수산해양교육연구
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    • 제25권4호
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    • pp.828-835
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    • 2013
  • Products from aquaculture have sometimes been focused on the problems caused by the contamination of chemical agents as the use of chemical agents in aquaculture has been annually increased. The risk of contamination of products by chemical agents is greater in freshwater than in seawater. In order to evaluate the food safety of a fish grown in freshwater, we investigated the residues of antibiotics (tetracycline, oxolinic acid and ciplofloxacin) and malachite green in cultured rainbow trout, Oncorhynchus mykiss. Malachite green, which was prohibited in the application of aquaculture, was not detected in samples tested in this study. The residual content of tetracycline was determined to be less than the permissible amount, <0.2 mg/kg. The contents of ciplofloxacin was also less than the permissible amount, <0.1 mg/kg. However, in case of oxolinic acid, one of samples was only exhibited higher content than the permissible amount (<0.1 mg/kg). The results obtained in this study suggested that the control and regulation of chemical agents such as antibiotics was important to maintain a safe and worry-free seafood supply.

화학적 발포와 레이저 하이브리드 공정을 이용한 마이크로 셀루러 폴리이미드 필름 제조 (Fabrication of Microcellular Polyimide Film using Hybrid Laser Process with Chemical Blowing Agents)

  • 마용원;강문석;오재용;신보성
    • 한국기계가공학회지
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    • 제12권6호
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    • pp.17-22
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    • 2013
  • Recently, microcellular polymer films have been widely used as absorbents, support cells, and sensors in the industrial fields of IT, NT, BT, and ST. The conventional fabrication methods of microcellular polymer films are not only more complicated than those of non-microcellular polymer films, but also require a longer production time. In this paper, we propose a new hybrid fabrication method for microcellular polymer films; films can be rapidly made using UV laser processing with chemical blowing agents. The experimental results show that the number of the micropores increased with respect to the laser fluence and the concentration of the chemical blowing agents.

화학 팽창제의 가스 발생과 쿠키의 텍스쳐 비교 (Gas Production of Chemical Leavening Agents and Effects on Textures of Cookies)

  • 양성연;김상용;장규섭;오덕근
    • 한국식품과학회지
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    • 제29권6호
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    • pp.1131-1137
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    • 1997
  • 팽창제 종류에 따른 시간별 가스 발생 속도 및 쿠키 텍스쳐에 대하여 살펴보았다. 본 실험에 사용된 가스 발생 장치에 의해서도 가스 발생 속도에 따라 크게 3타입으로 구분할 수 있었으며 이는 소암모늄명반을 제외하고는 문헌의 결과와 일치하였다. 속효성 평창제로는 주석산, 주석영, 후말산, 소암모늄명반이었고 이단 반응성 팽창제로는 산성피로인산나트륨, 무수모노인산칼슘, 소명반이었으며, 지효성 팽창제로는 중탄산암모늄, 중탄산나트륨, 글루코노-델타-락톤, 염화암모늄 등이었다. 제품 팽창률이 가장 높았던 것은 중탄산암모늄이었고 후미 면에서 가장 깨끗한 것은 글루코노-델타-락톤이었다. 팽창률이 높을수록 texture profile graph상에서 multi-peak를 나타내어 brittleness가 뛰어났으며 단순회귀분석에 의해, 팽창률과 brittleness간에 상관관계가 있음을 입증하였다$(r^2=0.8176)$. 중탄산암모늄을 사용한 쿠키 제품의 brittleness가 가장 높았다.

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PVC-Ni 복합재의 전기적 ${\cdot}$ 기계적 성질에 미치는 Titanate Coupling Agent 의 영향 (The Effect of Titanate Coupling Agents on the Electrical and Mechanical Properties of PVC-Ni Composite Systems)

  • 문탁진;이미경;김선호
    • 대한화학회지
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    • 제29권3호
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    • pp.319-327
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    • 1985
  • 충진제의 함량, titanate계 coupling agent의 종류, 처리량에 따른 PVC-Ni 복합재의 전기적.기계적 성질을 연구하였다. coupling agents처리에 의해 충진제의 분산상태가 양호해지고, 충진제 표면의 불순물이 대체되어 복합재의 전기저항은 감소되며 기계적 성질을 연구하였다. coupling agent처리에 의해 충진제의 분산상태가 양호해지고, 충진제 표면의 불순물이 대체되어 복합재의 전기저항은 감소되며 기계적 성질들은 향상되나 과량의 coupling agent의 처리는 이들 효과를 상쇄함을 보였다.

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Improvement of Biocontrol of Damping-off and Root Rot/Wilt of Faba Bean by Salicylic Acid and Hydrogen Peroxide

  • Abdel-Monaim, Montaser Fawzy
    • Mycobiology
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    • 제41권1호
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    • pp.47-55
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    • 2013
  • Rhizoctonia solani, Fusarium solani, F. oxysporum, and Macrophomina phaseolina were found to be associated with root rott and wilt symptoms of faba bean plants collected from different fieldes in New Valley governorate, Egypt. All the obtained isolates were able to attack faba bean plants (cv. Giza 40) causing damping-off and root rot/wilt diseases. R. solani isolates 2 and 5, F. solani isolate 8, F. oxysporum isolate 12 and M. phaseolina isolate 14 were the more virulent ones in the pathogenicity tests. Biocontrol agents (Trichoderma viride and Bacillus megaterium) and chemical inducers (salicylic acid [SA] and hydrogen peroxide) individually or in combination were examined for biological control of damping-off and root rot/wilt and growth promoting of faba bean plants in vitro and in vivo. Both antagonistic biocontrol agents and chemical inducers either individually or in combination inhibited growth of the tested pathogenic fungi. Biocontrol agents combined with chemical inducers recorded the highest inhibited growth especially in case SA + T. viride and SA + B. megaterium. Under green house and field conditions, all treatments significantly reduced damping-off and root rot/wilt severity and increased of survival plants. Also, these treatments increased fresh and weights of the survival plants in pots compared with control. The combination between biocontrol agents and chemical inducers were more effective than used of them individually and SA + T. viride was the best treatment in this respect. Also, under field conditions, all these treatments significantly increased growth parameters (plant height and number of branches per plant) and yield components (number of pods per plant and number of seeds per plant, weight of 100 seeds and total yield per feddan) and protein content in both seasons (2010~2011 and 2011~2012). Faba bean seeds soaked in SA + T. viride and SA + B. megaterium were recorded the highest growth parameters and yield components. Generally, the combination between biocontrol agents and chemical inducers recorded the best results for controlling damping-off and root rot/wilt diseases in greenhouse and field with addition improved plant growth and increased yield components in field.

Effects of Organoclay on the Thermal Insulating Properties of Rigid Polyurethane Foams Blown by Environmentally Friendly Blowing Agents

  • Kim, Youn-Hee;Choi, Seok-Jin;Kim, Ji-Mun;Han, Mi-Sun;Kim, Woo-Nyon;Bang, Kyu-Tae
    • Macromolecular Research
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    • 제15권7호
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    • pp.676-681
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    • 2007
  • A process designed to synthesize rigid polyurethane foam (PUF) with insulative properties via the modulation of PUF cell size via the addition of clay and the application of ultrasound was assessed. The blowing agents utilized in this study include water, cyclopentane, and HFC-365mfc, all of which are known to be environmentally-friendly blowing agents. The rigid PUFs were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI) and polyether polyol with a density of $50kg/m^3$. In addition, rigid PUFs/clay nanocomposites were synthesized with clay modified by PMDI with and without the application of ultrasound. The PUF generated using water as a blowing agent evidenced the highest tensile strength. The tensile strength of the PUF/nanocomposites was higher than that of the neat PUF and the strength was even higher with the application of ultrasound. The cell size of the PUF/clay nanocomposites was less than that of the neat PUF, regardless of the type of blowing agent utilized. It appears that the higher tensile strength and lower cell size of the PUF/clay nanocomposites may be attributable to the uniform dispersion of the clay via ultrasonic agitation. The thermal conductivity of the PUF/clay nanocomposites generated with HCFC-141b evidenced the lowest value when PUF/clay nanocomposites were compared with other blowing agents, including HFC-365mfc, cyclopentane, and water. Ultrasound has also proven effective with regard to the reduction of the thermal conductivity of the PUF/clay nanocomposites with any of the blowing agents employed in this study. It has also been suggested that the uniformly dispersed clay particles in the PUF matrix function as diffusion barriers, which prevent the amelioration of the thermal insulation property.

신문지 생산공정의 Deposit 제어를 위한 Fixing Agent의 선정에 관한 연구 (Studies on the Screening of Fixing agent for Deposit Control of ONP Stock)

  • 이광표;류정용;송봉근;정성현;박종문
    • 펄프종이기술
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    • 제42권3호
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    • pp.1-6
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    • 2010
  • A new testing method named pitch deposit tester (PDT) was developed by KRICT in order to evaluate the deposit potential of micro-stickies. The new method involves depositing the potential pitch particles on the air bubble covered plastic film set in the pitch deposit tester (PDT) and analysing the deposited area by an image analyzer. In this study, the effect of fixing agents on potential pitch deposition was elucidated. The effects of some fixing agents (polyamine and polyethyleneimine) on pitch control were investigated by the PDT test of 100% recycled newsprint stock. The study suggested that proper use of the PEI can lead to better pitch control than that of polyamine. The efficiency of novel screening method using the PDT and retention and drainage analyser (RDA) for fixing agents in terms of retention and deposit contamination could be confirmed by above mentioned results.

The Effect of Leveling Agents in the ULLR of Cotton

  • Kim, Tae-Kyung;Kim, Jin-Soo;Park, Hee-Moon
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2009년도 학술발표대회
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    • pp.175-176
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    • 2009
  • Energy saving and environment-friendly dyeing method of cotton with reactive dyes is the ultra low liquor ratio dyeing because it reduces the total quantity of water, dye, salt and alkali during the dyeing process in the effluent as well as the energy consumption. However, this method may not guarantee the quality of the dyeing results due to the specs or unlevel dyeing depending upon the dyes used. The study has focused on the effect of leveling agents in the dyeing of cotton with reactive dyes under the ultra low liquor ratio (1:5). Especially Sunfix N/B MF-D which was selected for ULLR showed low-leveled dyeing comparing with the other MF-D series. A leveling agent having polycarbonate structure increased LDF values of Sunfix N/B MF-D without changing of dyeing fastness. We recommend some leveling agents to improve the leveling behavior for ULLR dyeing.

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