• Title/Summary/Keyword: chemical age

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Cell Age Optimization for Hydrogen Production Induced by Sulfur Deprivation Using a Green Alga Chlamydomonas reinhardtii UTEX 90

  • KIM , JUN-PYO;KANG, CHANG-DUK;SIM, SANG-JUN;KIM, MI-SUN;PARK, TAI-HYUN;LEE, DONG-HYUN;KIM, DUK-JOON;KIM, JI-HEUNG;LEE, YOUNG-KWAN;PAK, DAE-WON
    • Journal of Microbiology and Biotechnology
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    • v.15 no.1
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    • pp.131-135
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    • 2005
  • Under sulfur deprived conditions, PS II and photosynthetic $O_2$ evolution by Chlamydomonas reinhardtii UTEX 90 are inactivated, resulting in shift from aerobic to anaerobic condition. This is followed by hydrogen production catalyzed by hydrogenase. We hypothesized that the photosynthetic capacity and the accumulation of endogenous substrates such as starch for hydrogen production might be different according to cell age. Accordingly, we investigated (a) the relationships between hydrogen production, induction time of sulfur deprivation, increase of chlorophyll after sulfur deprivation, and residual PS II activity, and (b) the effect of initial cell density upon sulfur deprivation. The maximum production volume of hydrogen was 151 ml $H_2$/l with 0.91 g/l of cell density in the late-exponential phase. We suggest that the effects of induction time and initial cell density at sulfur deprivation on hydrogen production, up to an optimal concentration, are due to an increase of chlorophyll under sulfur deprivation.

Convergence Education Modeling for Teaching Integration of IoT with 3D Printing Based on Manufacturing Chemical Product by Production Companies

  • Kim, Chigon;Park, Jong-Youel;Park, Dea-Woo
    • International Journal of Internet, Broadcasting and Communication
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    • v.12 no.4
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    • pp.55-60
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    • 2020
  • This study aims to apply Arduino and 3D printing technology considered as a key subject in the age of 4th industrial revolution which is a step 1 for customizing and applying the process of production by chemical molding companies producing environment-friendly biodegradable packaging materials to the 3D printing teaching in universities. Step 3 is applied to IoT for Arduino application, and 3D printing technology is also used on the basis of teaching creative integrated human resource. Integration of Arduino with 3D printers is based on the assumption that middle- and high-school students can learn it step by step to higher levels and university students majoring or not majoring in computing science can also have computing skills for solving 3D printing-based problems. For IoT application in this study, the 3D printing technology is applied to the external shape of products for producing an Arduino-based lighting fixture. The applied 3D printing technology is further extended to teaching modeling of producing packaging materials by chemical product molding companies in the age of 4th industrial revolution.

An Integrated System to Predict Early-Age Properties and Durability Performance of Concrete Structures

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.465-466
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    • 2010
  • In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

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A Study on the Characteristics and Burial Age of Sediment Layers at Bukpyeong myeon, Haenam gun (해남 북평면 퇴적층의 특성과 매몰 연대에 대한 연구)

  • Shin, Won Jeong;Yang, Dong Yoon;Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.3
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    • pp.41-55
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    • 2016
  • The granulometric characteristics and chemical composition of the samples from the Bukpyeong myeon, Hainam gun, Jeollanam do were analyzed in this study. The samples were collected from the outcrop of coastal area where the height is about 30m. The burial age of the sediments also estimated by OSL(Optically Stimulated Luminescence) method. The origin and forming processes of the samples are not clear in this stage as limited number of evidences can be found. However it is suggested that the samples are not aeolian deposits originated from chinese loess by the chemical analysis. The mean diameter of samples were $5{\sim}6{\varphi}(silt)$ and are increased slightly downwards. The samples also well sorted. The samples have been heavily weathered by the chemical alteration index. The value of CIA increase downward rapidly at the upper part of outcrop, then stabilized afterwards. The vertical concentration changes ratio of cations varies; Si increases downwards while Fe, Ti, K and Mg decrease. There are fluctuation in concentration ratio of Na and Ca with increasing depth. The burial age of sample from upper part are estimated as $104.52{\pm}4.45ka\;BP$, while that of lower part are $136.10{\pm}6.52ka\;BP$, and they fall in to last part of MS6. The deposition rate for this site is found about 0.017mm/year. The uplift rate of the site is supposed to be 0.24~0.26m/ka with assumption of palaeo-sea level of +6m. However the origin of the sediment deposits should be explored and cleared.

Clitoria ternatea L. as a Potential High Quality Forage Legume

  • Abreu, Matheus Lima Correa;Vieira, Ricardo Augusto Mendonca;Rocha, Norberto Silva;Araujo, Raphael Pavesi;Gloria, Leonardo Siqueira;Fernandes, Alberto Magno;Lacerda, Paulo Drude De;Junior, Antonio Gesualdi
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.2
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    • pp.169-178
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    • 2014
  • Samples of Clitoria ternatea L. (Cunh$\tilde{a}$) were harvested at 35, 50, 70, and 90 d after a uniformity harvest in a field study designed as a completely randomized design with a total of 18 experimental plots. The dry matter yield of the whole plant was separated quantitatively into leaves, stems, and pods at each harvesting age. Chemical analyses and in vitro gas production kinetics were performed to assess the quality of the plant parts. Yields, chemical composition, and estimates of gas production parameters were analyzed by fitting a mixed statistical model with two types of covariance structures as follows: variance components and an unrestricted structure with heterogeneous variances. Fast and slow gas yielding pools were detected for both leaves and stems, but only a single pool was detected for pods. The homoscedasticity assumption was more likely for all variables, except for some parameters of the gas production kinetics of leaves and stems. There was no presence of typical pods at 35 and 50 d. In the leaves, the fibrous fractions were affected, whereas the non-fibrous fractions were unaffected by the harvesting age. The harvesting age affected the majority of the chemical constituents and gas kinetic parameters related to the stems. The leaves of this legume were the least affected part by the aging process.

Influence of Slaughter Age on the Occurrence and Quality Characteristics of White Striping and Wooden Muscle Abnormalities

  • Mudalal, Samer;Zaazaa, Ahmed
    • Food Science of Animal Resources
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    • v.42 no.3
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    • pp.455-466
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    • 2022
  • The aim of this study was to assess the occurrence of white striping (WS), wooden breast (WB), and WS combined with WS/WB muscle abnormalities in broilers (Ross 500) at different slaughter ages (34, 41, and 48 d). In addition, the influence of these muscle abnormalities at different slaughter ages on quality characteristics (physical dimensions, pH, color index, and chemical composition) was studied. Overall occurrence of muscle abnormalities was 45%, 92%, and 100% at slaughter ages of 34, 41, and 48 d, respectively. It was found that about 39% from the occurrence of muscle abnormalities was not similar in the same bird (left and right fillets). Breast fillets affected by muscle abnormalities had significantly (p<0.05) higher weight than normal fillets. At slaughter age of 34 d, normal fillets had significantly higher L* (67.37 vs. 61.73 and 63.05, p<0.05), lower a* (3.25 vs. 4.87 and 5.18, p<0.05) and b* (4.02 vs. 5.20 and 5.99, p<0.05) than WS and WS combined with WB fillets; respectively. The changes in chemical composition due to muscle abnormalities were more significant at high slaughter age than at low slaughter age. In conclusion, the occurrence of muscle abnormalities was strongly influenced by slaughter age. Moreover, breast fillets affected by muscle abnormalities had different quality characteristics (proximate composition, color traits, and dimensions) in comparison to normal fillets.

Health Risk Assessment for Residents after Exposure to Chemical Accidents: Formaldehyde (화학사고물질 노출에 따른 피해지역 주민 건강위해성평가: 폼알데하이드 사례를 중심으로)

  • Park, Sihyun;Cho, Yong-Sung;Lim, Huibeen;Park, Jihoon;Lee, Cheolmin;Hwang, Seung-Ryul;Lee, Chungsoo
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.155-165
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    • 2021
  • Objectives: Acute exposure to high concentrations of chemicals can occur when a chemical accident takes place. As such exposure can cause ongoing environmental pollution, such as in the soil and groundwater, there is a need for a tool that can assess health effects in the long term. The purpose of this study was assessing the health risks of residents living near a chemical accident site due to long-term exposure while considering the temporal concentration changes of the toxic chemicals leaked during the accident until their extinction in the environment using a multimedia environmental dynamics model. Methods: A health risk assessment was conducted on three cases of formaldehyde chemical accidents. In this study, health risk assessment was performed using a multimedia environmental dynamics model that considers the behavior of the atmosphere, soil, and water. In addition, the extinction period of formaldehyde in the environment was regarded as extinction in the environment when the concentration in the air and soil fell below the background concentration prior to the accident. The subjects of health risk assessment were classified into four groups according to age: 0-9 years old, 10-18 years old, 19-64 years old, and over 65 years old. Carcinogenic risk assessment by respiratory exposure and non-carcinogenic risk assessment by soil intake were conducted as well. Results: In the assessment of carcinogenic risk due to respiratory exposure, the excess carcinogenic risk did not exceed 1.0×10-6 in all three chemical accidents, so there was no health effect due to the formaldehyde chemical accident. As a result of the evaluation of non-carcinogenic risk due to soil intake, none of the three chemical accidents had a risk index of 1, so there was no health effect. For all three chemical accidents, the excess cancer risk and hazard index were the highest in the age group 0-9. Next, 10-18 years old, 65 years old or older, and 19-64 years old showed the highest risk. Conclusion: This study considers environmental changes after a chemical accident occurs and until the substance disappears from the environment. It also conducts a health risk assessment by reflecting the characteristics of the long-term persistence and concentration change over time. It is thought that it is of significance as a health risk assessment study reflecting the exposure characteristics of the accident substance for an actual chemical accident.

Variation of Disinfection-by-Prodcut in Distribution System and Evaluation of Correlation between Disinfection-by-Product and Physico-Chemical Parameters (관망에서의 소독부산물 변화와 관련 영향인자들의 상관관계 분석)

  • Song, Young Il;Ann, Suna;Ann, Seoungyun;Seo, Daeguen;Cho, Hyukjin;Lee, Jaesung;Choi, Ilwhan;Shin, Changsoo;Lee, Hee Suk
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.2
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    • pp.63-70
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    • 2016
  • The distributed systems managed by K-water were surveyed to study the characteristic of disinfection-by-product (Trihalomethans & Haloacetic acids) formation and the correlations between the concentrations of disinfection-by-product and physico-chemical parameters. Five distribted system were selected according to their water ages and the degree of deterioration of their pipelines. Total seven items including Trihalomethans (THMs), Haloacetic acids (HAAs), BDOC, DOC, pH, chlorine residual, and temperature were analysed in monthly basis. The concentration of organic matter were increased according to water age and pipeline deterioration in this study. The coefficient of determination between the decline of residual chlorine and the increase of water age was revealed as high. Also, the coefficient of determination between the decline rate of residual chlorine and the increase of the Trihalomethans concentration were studied as high. Furthermore the longer water age is the bigger the effect on Trihalomethans formation and temperature. However, the coefficient of determination between the concentraion of Haloacetic acid and water age, residual chlorine, and temperature were revealed as low in this study.

Chemical Resistance of Low Heat Cement Concrete Used in Wastewater Treatment Structures Built on Reclaimed Land (해안매립지 하수처리시설물에 적용한 저발열시멘트 콘크리트의 내화학성 평가)

  • Chung, Yongtaek;Lee, Byungjae;Kim, Yunyong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.113-119
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    • 2019
  • Concrete structures built on reclaimed land are combined with chemical erosion such as chlorine and sulfate ions from seawater. Chloride attack deteriorates the performance of the structure by corroding reinforcing bars. In addition, the waste water treatment structure has a problem that the concrete is deteriorated by the sulfate generated inside. Therefore, in this study, the characteristics and chemical resistance of low heat cement concrete used in wastewater treatment structures constructed on reclaimed land were evaluated. As a result of the experiment, the target slump and air content were satisfied under all the mixing conditions. The slump of low heat cement (LHC) concrete was higher than that of ordinary portland cement (OPC) concrete, while the air content of LHC concrete was smaller than that of OPC concrete with the same mix proportion. As a result of compressive strength test, OPC concrete showed higher strength at younger age compared to 28 days. In contrast, LHC concrete exhibited higher strength than OPC concrete at the age of 56 days. As a result of chlorine ion penetration tests, LHC-B concrete showed chlorine ion penetration resistance performance of the "very low" level at the age of 56 days. As a result of chemical resistance evaluation, when the LHC concrete is applied without epoxy treatment, chemical resistance is improved by about 18% compared to OPC concrete. In testing chemical resistance, the epoxy coated concrete exhibited less than 5% strength reduction when compared to sound concrete.

Effect of Stage of Growth and Cultivar on Chemical Composition of Whole Maize Plant and Its Morphological Fractions

  • Firdous, R.;Gilani, A.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.3
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    • pp.366-370
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    • 1999
  • Samples of whole plant, leaf and stem of Akbar, Neelum, UM-81 and lZ-31 cultivars of maize fodder harvested up to 14 weeks at different growth stages were drawn and analysed for dry matter contents and various cell wall constituents such as NDF, ADF, hemicellulose, cellulose, lignin, cutin and silica. The dry matter contents of whole maize plant, leaf and stem increased significantly (p<0.01) with advancing plant age. Maximum dry matter was found in the leaf fraction of the plant. The cell wall components continued to increase significantly (p<0.001) in whole maize plant and its morphological fractions as the age advanced. Maximum values for NDF, ADF, cellulose and lignin were observed in stem followed by whole plant and leaf, whereas hemicellulose, cutin and silica contents were higher in leaf fraction of the plant. The cultivars were observed to have some effects on chemical composition of all plant fraction. The results indicated that maturity had a much greater effect on the concentration of all the structural components than did the cultivars. It was concluded that maize fodder should be cut preferably between 8th to 9th week of age (flowering stage) to obtain more nutritious and digestible feed for livestock. Among the maize cultivars, Neelum proved to be the best, due to its higher dry matter contents and lower lignin concentration.