• Korean Chemical Engineering Research
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• 제55권4호
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• pp.483-489
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• 2017

The loss of the sulfur cathode material through dissolution of the polysulfide into electrolyte causes a significant capacity reduction of the lithium-sulfur cell during the charge-discharge reaction, thereby debilitating the electrochemical performance of the cell. We addressed this problem by using a chemical and physical approach called reduction of polysulfide dissolution through direct coating functional inorganic (graphene oxide) or organic layer (polyethylene oxide) on electrode, since the deposition of external functional layer can chemically interact with polysulfide and physically prevent the leakage of lithium polysulfide out of the electrode. Through this approach, we obtained a composite electrode for a lithium-sulfur battery (sulfur: 60%) coated with uniform and thin external functional layers where the thin external layer was coated on the electrode by solution coating and drying by a subsequent heat treatment at low temperature (${\sim}80^{\circ}C$). The external functional layer, such as inorganic or organic layer, not only alleviates the dissolution of the polysulfide electrolyte during the charging/discharging through physical layer formation, but also makes a chemical interaction between the polysulfide and the functional layer. As-formed lithium-sulfur battery exhibits stable cycling electrochemical performance during charging and discharging at a reversible capacity of 700~1187 mAh/g at 0.1 C (1 C = 1675 mA/g) for 30 cycles or more.

• 세라미스트
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• 제22권4호
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• pp.402-416
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• 2019

The development of next-generation secondary batteries, including lithium-ion batteries (LIB), requires performance enhancements such as high energy/high power density, low cost, long life, and excellent safety. The discovery of new materials with such requirements is a challenging and time-consuming process with great difficulty. To pursue this challenging endeavor, it is pivotal to understand the structure and interface of electrode materials in a multiscale level at the atomic, molecular, macro-scale during charging / discharging. In this regard, various advanced material characterization tools, including the first-principle calculation, high-resolution electron microscopy, and synchrotron-based X-ray techniques, have been actively employed to understand the charge storage- and degradation-mechanisms of various electrode materials. In this article, we introduce and review recent advances in in-situ synchrotron-based x-ray techniques to study electrode materials for LIBs during thermal degradation and charging/discharging. We show that the fundamental understanding of the structure and interface of the battery materials gained through these advanced in-situ investigations provides valuable insight into designing next-generation electrode materials with significantly improved performance in terms of high energy/high power density, low cost, long life, and excellent safety.

• 전력전자학회논문지
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• 제15권6호
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• pp.441-450
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• 2010

리튬전지는 다양한 전자기기의 구동전원으로 널리 사용되고 있으며, 충전과 방전 동작을 수차례 반복하는 화성공정은 이러한 리튬전지의 생산에 필수적이다. 본 논문에서는 충전동작과 방전동작을 하나의 장치로 수행할 수 있는 리튬전지 충방전용 직류-직류 변환기를 제안하고 설계한다. 제안한 변환기는 리튬전지의 충방전 특성을 고려하여 설계하였으며, 충전모드에서는 포워드 변환기로 동작하고 방전모드에서는 절연된 부스트 변환기로 동작한다. 해석을 바탕으로 설계조건에 부합하는 변압기의 권선 수, 인덕터, 커패시터 및 스위칭 소자를 설계하였다. 끝으로 설계한 변수를 적용한 시뮬레이션과 실험을 통하여 본 논문에서 제안한 변환기 설계의 타당성을 입증하였다.

• 대한안전경영과학회지
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• 제4권4호
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• pp.137-146
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• 2002

In order to investigate the effect of irradiation by $^{60}Co-\gamma$rays as well as the e thermal treatment on the dielectric deterioration in ethylene propylene rubber, insulating material for electric cables used in atomic power plants, charging discharging current, residual built- up voltage and dielectric properties are measu discussed in this study. Variance in the characteristic of relative dielectric constant as a function of tem was observed in relatively high dose of irradiation. Since glass transition tem appeared at tens of degree Celsius below zero, the characteristic is attributed orientation polarization. Dielectric loss is generally increased, with increasing d irradiation in the characteristic of dielectric loss as a function of temperature, No d loss by thermal treatment was observed. Dielectric resistance decreases with increa of irradiation in the characteristic of charging current as a function of temperature be considered that dielectric resistance seems to be recovered by thermal treatm characteristic of discharging current as a function of time in the specimen less ir become similar to that of the unirradiated, when thermal treated. A peak is shown residual built- up voltage as a function of time, and the corresponding time of the shorten as increasing dose of irradiation. It is also observed that the corresponding the peak is lengthened by thermal treatment.

• 전기학회논문지
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• 제62권1호
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• pp.21-28
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• 2013

The paper proposes an optimal sizing method of a customer's battery energy storage system (BESS) which aims at managing the electricity demand of the customer to minimize electricity cost under the time of use(TOU) pricing. Peak load limit of the customer and charging and discharging schedules of the BESS are optimized on annual basis to minimize annual electricity cost, which consists of peak load related basic cost and actual usage cost. The optimal scheduling is used to assess the maximum cost savings for all sets of candidate capacities of BESS. An optimal size of BESS is determined from the cost saving curves via capacity of BESS. Case study uses real data from an apartment-type factory customer and shows how the proposed method can be employed to optimally design the size of BESS for customer demand management.

• Journal of Electrical Engineering and Technology
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• 제13권4호
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• pp.1759-1768
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• 2018

The energy density, power density and ohm resistance of battery change significantly as results of battery aging, which lead to decrease in the accuracy of the equivalent model. A parameter identification method of the equivale6nt circuit model with 3 R-C branches based on the test database of battery life cycle is proposed in this paper. This database is built on the basis of experiments such as updating of available capacity, charging and discharging tests at different rates and relaxation characteristics tests. It can realize regular update and calibration of key parameters like SOH, so as to ensure the reliability of parameters identified. Taking SOH, SOC and T as independent variables, lookup table method is adopted to set initial value for the parameter matrix. Meanwhile, in order to ensure the validity of the model, the least square method based on variable forgetting factor is adopted for optimizing to complete the identification of equivalent model parameters. By comparing the simulation data with measured data for charging and discharging experiments of Li-ion battery, the effectiveness of the full life cycle database and the model are verified.

• 한국표면공학회지
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• 제49권2호
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• pp.191-195
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• 2016

Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

• 조명전기설비학회논문지
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• 제29권2호
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• pp.82-90
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• 2015

This paper proposes an efficient bi-directional DC/DC converter topology using multi-phase interleaved method for power storage system. The proposed converter topology is used for a power storage system using a vanadium redox flow battery(VRFB) and is configured to enable bidirectional power flow for charging and discharging of VRFB. Proposed DC/DC converter of the 4 leg method is reduced to 1/4 times the rating of the reactor and the power semiconductor device so can be reduce the system size. Also, proposed topology is obtained the effect of four times the switching frequency as compared to the conventional converter in each leg with a 90 degree phase shift 4 leg method. This can suppress the reduction of the life of the secondary battery because it is possible to reduce the current ripple in accordance with the charging and discharging of VRFB and may increase the efficiency of the entire system. In this paper, it proposed bidirectional high-efficiency DC/DC converter topology Using multi-phase interleaved method and proved the validity through simulations and experiments.

• 전력전자학회논문지
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• 제24권2호
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• pp.134-137
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• 2019

A wide-bandwidth current controller is required for fast charging/discharging of super capacitor applications. Peak current mode is generally used to accomplish fast charging/discharging because this mode has fast response characteristics. However, the peak current mode control must have a slope compensation function to restrain sub-harmonics oscillation. The slope must be changed accordingly if the controlled output voltage is varied. However, changing the slope for every changed output voltage is not easy. The other solution, selecting the slope as the maximum value, causes a slow response problem to occur. Therefore, we propose a hybrid mode controller that uses a peak current and a newly specified valley current. Through the proposed hybrid mode control, the sub-harmonic oscillation does not occur when the duty is larger than 0.5 because of the fast response.

• 한국기계가공학회지
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• 제21권3호
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• pp.49-55
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• 2022

The design of a battery package and a BMS module for applications using seawater rechargeable batteries, which are known as next-generation energy storage devices, is proposed herein. Seawater rechargeable batteries, which are currently in the initial stage of research, comprise primarily components such as anode and cathode materials. Their application is challenging owing to their low charge capacity and limited charge/discharge voltage and current. Therefore, we design a method for packaging multiple cells and a BMS module for the safe charging and discharging of seawater rechargeable batteries. In addition, a prototype seawater rechargeable battery package and BMS module are manufactured, and their performances are verified by evaluating the prevention of overcharge, overdischarge, overcurrent, and short circuit during charging and discharging.