• Corrosion Science and Technology
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• 제16권6호
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• pp.317-327
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• 2017

The change in the oxidation behavior of three types of B-added ultrahigh strength martensitic steels containing Ti and Nb induced by applying constant cathodic current was investigated. In a 3% NaCl+0.3% $NH_4SCN$ solution, the overall polarization behavior of the three alloys was similar, and degradation of the oxide film was observed in the three alloys after applying constant cathodic current. A significant increase in the anodic current density was observed in the Nb-added alloy, while it was diminished in the Ti-added alloy. Both Ti and Nb alloying decreased the hydrogen overpotential by forming NbC and TiC particles. In addition, the thickest oxide film was formed on the Ti-added alloy, but the addition of Nb decreased the film thickness. Therefore, it was concluded that the remarkable increase in the anodic current density of Nb-added alloy induced by applying constant cathodic current density was attributed to the formation of the thinnest oxide film less protective to hydrogen absorption, and the addition of Ti effectively blocked the hydrogen absorption by forming TiC particles and a relatively thick oxide film.

• 전력전자학회논문지
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• 제16권6호
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• pp.587-593
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• 2011

본 논문에서는 고 전력밀도 및 저가형으로 구성 가능한 새로운 구조의 계통 연계형 태양광 인버터 시스템을 제안한다. 제안 시스템은 태양전지의 최대 전력점 추종기능과 배터리의 충 방전 기능을 단일 전력단으로 구성함으로써, 고 전력밀도 및 저가격형 시스템 구성이 가능하다. 또한, 제안 시스템은 배터리를 링크 캐패시터에 직렬 연결함으로써 링크 캐패시터의 전압 스트레스를 배터리 전압만큼 저감할 수 있으므로 가격저감 효과가 크다. 최종적으로 제안 시스템의 우수성과 신뢰성 검증을 위하여 1.5kW급 태양광 인버터 시스템의 시작품을 제작하였고, 이를 이용한 실험결과를 바탕으로 제안 시스템의 타당성을 검증한다.

• 에너지공학
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• 제20권3호
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• pp.178-184
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• 2011

압축공기저장(CAES) 발전은 가스터빈에 필요한 압축공기를 야간이나 비첨두 시간에 저렴한 전기로 미리 압축해서 저장하였다가 주간에 활용하는 것으로 전력 저장과 발전의 하이브리드 기술이라고 할 수 있다. 그러나 기존 압축공기저장 발전의 경우 심야에 압축공기를 일정부피의 압축공기 저장조에 충전하게 되면 저장조내의 압력은 점점 증가하게 되고, 반대로 주간에 발전을 위해 압축공기를 방출하게 되면 저장조내의 압력은 감소하게 된다. 이와 같이 운전 압력비 조건이 넓은 범위로 변화하여 설계 압력비에서 벗어나게 되는 것은 압축 및 팽창효율이 크게 감소하게 되는 원인이 된다. 본 논문에서는 이러한 기존의 변압식 압축공기저장 발전 방식의 문제점을 해결하기 위해 새로운 방식의 정압식 압축공기저장 발전 방식을 제시하고 있으며, 엑서지 개념을 포함한 에너지 분석을 통해 에너지 밀도 증가와 효율 향상 효과를 예측하였다. 새로운 방식의 정압식 압축공기 저장 발전 방식은 정압식 압축공기 저장 발전과 공압식 양수발전의 하이브리드 개념으로 기존 변압식 압축공기저장 발전 방식에 비해 정압 운전에 의한 효율향상과 에너지 밀도 증가로 압축공기 저장조의 크기를 50%이상 줄일 수 있는 장점을 가지고 있다.

• Asian Journal of Atmospheric Environment
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• 제9권4호
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• pp.288-297
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• 2015

In this study, wind conditions and its energy potential have been assessed by conducting a Weibull analysis of the wind speed data (over the period of 2002-2011) measured from a port city (Mongla) and an isolated island (Sandwip) in Bangladesh. The monthly mean wind speed at Mongla ranged from 1.60 m/s (December) to 2.47 m/s (April). The monthly values of Weibull shape parameter (k) were from 1.27 to 2.53. In addition, the values of the scale parameter (c) and the monthly wind power density ranged from 1.76 to 2.79 m/s and 3.95 to $17.45W/m^2$, respectively. The seasonal mean wind speed data varied from 1.72 (fall) to 2.29 m/s (spring) with the wind power density from 5.33 (fall) to $14.26W/m^2$ (spring). In the case of Sandwip, the results were comparable to those of Mongla, but moderate reductions in all the comparable variables were observed. The wind data results of these two areas have been compared with those of eight other locations in the world with respect to wind power generation scale. According to this comparison, the wind power generation scale for Mongla and Sandwip was adequate for stand-alone small/micro-scale applications such as local household consumption, solar-wind hybrid irrigation pumps, and battery charging.

• 한국자동차공학회논문집
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• 제23권2호
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• pp.199-207
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• 2015

Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

• 전기학회논문지
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• 제66권2호
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• pp.357-362
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• 2017

Among the lithium metal oxides for asymmetric hybrid supercapacitor, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. The pulverized LTO powder was observed to show the enhanced capacity from 120 mAh/g to 156 mAh/g at C-rate (10, 100 C). Hybrid supercapacitor module(48V, 416F) was fabricated using an asymmetric hybrid capacitor with a capacitance of 7500F. As a result of the measurement of C-rate characteristics, the module shows that the discharge time is drastically reduced at more than 50C, and the ESR and voltage drop characteristics are increased. The energy density and power density were reduced under high C-rate conditions. When designing asymmetric hybrid supercapacitor module, the C-rate and ESR should be considered As a result of measuring the 5 kw UPS, it was discharged at the current of 116A~170A during the discharge in the voltage range of 48V~30V, and the compensation time at discharge was measured to be about 33.2s. Experimental results show that it can be applied to applications related to stabilization of power quality by applying hybrid supercapacitor module.

• 자원리싸이클링
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• 제18권2호
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• pp.30-38
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• 2009

습식 비중선별에서 sink products로 회수된 종말품 고비중 폐플라스틱 산물의 재활용을 위한 마찰하전정전선별 실증화 연구를 수행하였다. 종말품 고비중 폐플라스틱의 재질분리에 있어 적합한 하전물질 선정을 위한 하전특성 연구결과, high density polyethylene (HDPE)재질이 가장 효과적인 하전물질로 규명되어, 이 재질을 이용하여 하전장치를 제작하였다. 실험결과 최적조건인 전극의 전기장 250 kV/m, 분리대의 위치 (-) 8 cm, 그리고 상대습도 40%이하에서 PET, PS and others 산물의 품위와 회수율이 각각 99.1%와 86.0%인 결과를 얻었다. 또한 300 kg/h 규모의 대량처리 기술을 개발하여 종말품 폐플라스틱을 2등급 이상의 RPF나 RDF로 재활용할 수 있는 즉, PVC를 1% 미만을 줄일 수 있는 선별기술을 개발하였다.

• 한국가스학회지
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• 제24권6호
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• pp.61-69
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• 2020

본 논문은 압력과 온도조건에 따라 수소저장용기 TYPE 1에서 발생하는 거동특성을 FEM(Finite Element Method)으로 연구한 것이다. 용기의 구조안전성 평가를 위해 최고압력에서 발생한 VMS(Von Mises stress)을 소재의 YS(Yield Strength)를 비교하였고, 수명예측을 위한 기초데이터로써 PSED(Plastic Strain Energy Density) 결과를 분석하였다. 해석결과에 의하면 최고압력 40 Mpa 이상의 가스압에서 저장용기의 바닥면에 항복강도보다 높은 VMS가 발생하여 수소가스 저장용기의 안전성은 확보되지 않았다고 판단된다. 또한, 온도조건에 의해 발생한 VMS의 결과는 대단히 낮아서 온도에 의한 거동은 영향을 무시할 수 있다. VMS/YS이 1이하가 되는 최고압력은 약 30Mpa으로 계산되어 본 논문의 대상이 되는 수소저장용기는 30 Mpa이하의 가스충전압력으로 관리되어야 함을 알 수 있다.

• 한국세라믹학회지
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• 제22권6호
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• pp.5-8
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• 1985

Graphite has been oxidized to graphite hydrogen sulfate in concentrated $H_2SO_4$. Anodic oxidation and chemical oxidation of graphite in $H_2SO_4$ generally leads to the formation of intercalation compounds of the ionic salt type through incorporation of $H_2SO_4^-$ions and $H_2SO_4$ molecules into the graphite. Several other reactions also accur at various points of the charging cycle. But there is no satisfactory kinetics and mechanism of intercalationin graphite. We have studied them with anodic oxidation and chemical oxidation. We found six distinct phenomena between 2nd stage and 1st stage in chemical oxidation. We examined them in detail by the following in the measurements electrical oxidation. X-ray diffractions UV-Vis spectroscopy density measurements. We could obtained a equation for kinetic according to the reaction rate from this results and mechanism of intercalation between 2nd stage and 1st stage with hydrogen sulfate in graphite. Three thesis were written for the mechanism of intercalation compounds in graphite with hydrogen sulfate ; first thesis is anodic oxidation second thesis is chemical oxidation and definition of transit phase between 2nd etc the third thesis is the kinetic mechanism of intercalation compounds in graphite with Hydrogen sulfate. This thesis is the first paper among three thesis as anodic oxidation.

• Journal of Multimedia Information System
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• 제5권1호
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• pp.47-52
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• 2018

We have developed an electromagnetic generator to bury in subcutaneous area or abdominal cavity of the birds. As we can't use a solar battery, it is extremely difficult to supply a power for subcutaneous implantation such as biosensors under the skin due to the darkness environment. We are aiming to test the antigen-antibody reaction to confirm an avian influenza. One solution is a very small generator with the electromagnetic induction coil. We attached the developed coil to chickens and pheasants and recorded the electric potential generated as the chicken walked and the pheasant flew. The electric potential generated with physical simulator is equal to or exceeds the 7 V peak-to-peak at maximum by 560/min of flapping of wings. Even if we account for the junction voltage of the diode (200 mV), efficient charging of the double-layer capacitor is possible with the voltage doubler rectifier. If we increase the voltage, other problems arise, including the high-voltage insulation of the double-layer capacitor. For this reason, we believe the power generated to be sufficient for subcutaneous area of birds. The efficiency, magnetic 2 mm in length and coil 15mm in length, if axial direction is rectified, the magnetic flux density given to the coil could calculated to 7.1 % and generated power average 0.47mW. The improvements in size and wire insulation are expected in the future.