• Carbon letters
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• 제9권3호
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• pp.210-217
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• 2008

Petroleum pitch and coke with wet mixture method or with dry mixture method were investigated to develop the composite anodic carbon material of high power lithium ion battery. Cokes coated with pitch were obtained by the heat treatment of mixture of cokes and pitch with different weight ratios at $800{\sim}1200^{\circ}C$. The charge and discharge characteristic of the consequent composite anodic carbon material assembled in batteries was tested. Cokes with wet mixture method have a smooth surface and their capacity changed little with changing temperature and content as compared to the cokes with dry mixture method. Although the reversible capacities showed different values by the anode manufacturing method, the composite anode with the mixture of 20 wt% of petroleum pitch and 80 wt% of coke showed the higher power capability and initial efficiency than the pitch based anode. However, the reversible capacity of the composite anode showed the reduced value as compared with the pitch based anode.

• Carbon letters
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• 제27권
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• pp.98-107
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• 2018

Free-standing electrodes of CuO nanorods in carbon nanotubes (CNTs) are developed by synthesizing porous CuO nanorods throughout CNT webs. The electrochemical performance of the free-standing electrodes is evaluated for their use in flexible lithium ion batteries (LIBs). The electrodes comprising CuO@CNT nanocomposites (NCs) were characterized by charge-discharge testing, cyclic voltammetry, and impedance measurement. These structures are capable of accommodating a high number of lithium ions as well as increasing stability; thus, an increase of capacity in long-term cycling and a good rate capability is achieved. We demonstrate a simple process of fabricating free-standing electrodes of CuO@CNT NCs that can be utilized in flexible LIBs with high performance in terms of capacity and cycling stability.

• 한국군사과학기술학회지
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• 제15권4호
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• pp.519-526
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• 2012

Recently fuel cell is considered to be a new technology that can substitute the ICE(Internal Combustion Engine) as well as overcome environmental issues. In military applications, fuel cell has an unique advantages, which are quietness, namely, stealth. The environmental requirement such as shock and vibration in military application, however, is very severe comparing to civilian demand. Especially, the safety concerning hydrogen storage is the most important problem. Among the candidate methods to store hydrogen, the metal hydride storage is promising method owing to the storage mechanism of chemical absorption of hydrogen to metal hydrides. In this study, the new composition of Ti-Zr type metal hydride(A composition) was suggested and investigated to increase the hydrogen storage capacity. For comparison, the hydrogen charge-discharge properties were investigated with the commercialized Ti-Zr type metal hydride(B composition) using PCT(Pressure-Composition-Temperature) measurement. Also two hydrogen storage cylinders were loaded with each metal hydride and their hydrogen charging and discharging characteristics were investigated. As a result, it was found that the new Ti-Zr type metal hydride has a slightly higher hydrogen storage capacity compared to commercial Ti-Zr type metal hydride.

• 전기학회논문지
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• 제67권9호
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• pp.1174-1180
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• 2018

In December 2017, the government announced plans to increase the current proportion of renewable energy from 7% to 20% by 2030 through a plan called the Renewable Energy 3020 Implementation Plan. Therefore, the demand for installation of photovoltaic(PV), wind turbine(WT) and battery energy storage system(BESS) is expected to increase. In particular, the system combined with energy storage system(ESS) is expected to take up a large portion since PV and WT can receive high renewable energy certificates(REC) weights when combined with ESS. In this study, we calculate the optimal capacity of the power conditioning system(PCS) and the BESS by comparing the economical efficiency and maximize the efficiency of the PV-BESS system in which the PV and the BESS are connected. By analyzing the system marginal price(SMP) and REC, it maximize profits through application of REC weight 5.0 and optimal charge-discharge scheduling according to the SMP changes.

• Corrosion Science and Technology
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• 제20권1호
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• pp.15-21
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• 2021

Through a simple filtration process, followed by carbonization within a reductive environment, coffee waste grounds can be transformed into a non-porous hard carbon for use in multiple contexts. This resulting coffee-waste carbon has been evaluated as an eco-friendly and cost-effective replacement for conventional graphite. When compared with different types of carbon, our study found that the coffee-waste carbon fell into the category of hard carbon, as verified from the galvanostatic charge/discharge profiles. The coffee-waste carbon showed a superior rate capability when compared to that of graphite, while compromising smaller capacity at low C rates. During electrochemical reactions, it was also found that the coffee-waste carbon is well exposed to electrolytes, and its disordered characteristic is advantageous for ionic transport which leads to the low tortuosity of Li ions. Finally, the high irreversible capacity (low initial Coulombic efficiency) of the coffee-waste carbon, which if also often observed in amorphous carbon, can be adequately resolved through a solution-based prelithiation process, thereby proving that the coffee-waste carbon material is quite suitable for commercial use as an anode material for quickly-chargeable electrodes.

• 전력전자학회논문지
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• 제26권3호
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• pp.167-175
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• 2021

Reusing electric vehicle batteries after they have been retired from mobile applications is considered a feasible solution to reduce the demand for new material and electric vehicle costs. However, the evaluation of the value and the performance of second-life batteries remain a problem that should be solved for the successful application of such batteries. The present work aims to estimate the remaining useful life of Li-ion batteries through the neuro-fuzzy system with the equivalent circuit parameters obtained by Electrochemical Impedance Spectroscopy (EIS). To obtain the impedance spectra of the Li-ion battery over the life, a 18650 cylindrical cell has been aged by 1035 charge/discharge cycles. Moreover, the capacity and the parameters of the equivalent circuit of a Li-ion battery have been recorded. Then, the data are used to establish a neuro-fuzzy system to estimate the remaining useful life of the battery. The experimental results show that the developed algorithm can estimate the remaining capacity of the battery with an RMSE error of 0.841%.

• Corrosion Science and Technology
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• 제22권4호
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• pp.287-296
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• 2023

Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.

• 한국산업융합학회 논문집
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• 제26권6_2호
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• pp.1117-1125
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• 2023

The DC part of the DC microgrid power conversion system uses capacitors for buffers of charge and discharge energy for smoothing voltage and plays important roles such as high frequency component absorption, power balancing, and voltage ripple reduction. The capacitor uses an aluminum electrolytic capacitor, which has advantages of capacity, low price, and relatively fast charging/discharging characteristics. Aluminum electrolytic capacitors(AEC) have previous advantages, but over time, the capacity of the capacitors decreases due to deterioration and an increase in internal temperature, resulting in a decrease in use efficiency or an accident such as steam extraction due to electrolyte evaporation. It is necessary to take measures to prevent accidents because the failure diagnosis and detection of such capacitors are a very important part of the long-term operation, safety of use, and reliability of the power conversion system because the failure of the capacitor leads to not only a single problem but also a short circuit accident of the power conversion system.

• 설비공학논문집
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• 제24권5호
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• pp.391-400
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• 2012

In this study, performance of HFC32/HFC152a mixture is measured in the composition range of 20 to 50% R32 with an interval of 10% for the comparison with the conventional HCFC22 in water-source heat pumps. Tests are carried out under the same capacity in a heat pump bench tester equipped with a variable speed compressor at the evaporation and condensation temperatures of 7/$45^{\circ}C$ and -7/$41^{\circ}C$ for summer and winter conditions, respectively. Test results show that the compressor power of the HFC32/HFC152a mixture is 13.7% lower than that of HCFC22 while the coefficient of performance(COP) the HFC32/HFC152a mixture is 15.8% higher than that of HCFC22. Hence, from the view point of energy efficiency, the HFC32/HFC152a mixture is excellent as compared to HCFC22. Compressor discharge temperatures of HFC32/HFC152a mixture are increased up to $15.4^{\circ}C$ as compared to that of HCFC22. The amount of charge for HFC32/HFC152 mixture decrease up to 27% as compared to that of HCFC22. Overall, HFC32/ HFC152a mixture is an excellent long term candidate to replace HCFC22 in water-source heat pumps.

• 조명전기설비학회논문지
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• 제20권2호
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• pp.24-28
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• 2006

본 논문은 마이크로 전극 측정 시스템을 사용하여 차세대 신동력 산업인 HEV(Hybrid Electric Vehicle) 및 수소연료전지(PEMFC) 차량용 니켈 수소전지의 전극소재로 사용되고 있는 수소저장합금(Mm : misch metal, $MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$)의 단일 입자에 대해 전기화학적 수소 흡방출 특성 평가를 수행 하였다. 즉 Carbon fiber 마이크로 전극을 합금 입자 한개 위에 전기적인 접촉을 이루도록 조정하고, Cyclic Voltammetry 및 Galvanostatic 충방전 실험을 수행하였다. 그 결과 단일 입자의 방전용량은 약 280[mAh/g]로 이론용량의 약 90[%]의 특성을 보여 주었다. 데이터는. 실제 Ni-MH전지를 구성하는 합금입자 그리고 폴리머 바인더로 구성된 Composite film 전극과 비교 하였다. 추가적으로 합금의 단일 입자에 있어 in situ 미분화 현상을 관찰하였다. 마이크로 전극 측정 시스템에 의한 단일 입자의 전기화학적 평가는 기존의 Composite Film 전극에 비해 수소저장합금에 대해 보다 상세하고 정확한 정보를 쉽게 얻을 수 있었다.