• Macromolecular Research
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• v.13 no.5
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• pp.391-396
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• 2005

The polymerization of methyl methacrylate (MMA) was carried out using CuBr/bidentate phosphorus ligand catalyst systems. MMA polymerization with CuBr/phosphine-phosphinidene (PP) exhibited high conversion ($\~80\%$) in 5 h at $90^{\circ}C$ along with a linear increase of ln($[M]_0/[M]$) versus time, indicating constant concentration of the propagating radicals during the polymerization. The molecular weight of the prepared PMMA tended to increase with conversion, suggesting the living polymerization characteristic of the system. On the other hand, a large difference between the measured and theoretical molecular weight and a broad molecular weight distribution were observed, implicating possible incomplete control over the polymerization. This may have been caused by the low deactivation rate constant ($\kappa_{deact}$) of the system. The low $\kappa_{deact}$, would result in irreversible generation of radicals instead of reversible activation/deactivation process of ATRP. Polymerizations performed at different ligand to CuBr ratios and different monomer to initiator ratios did not afford better control over the polymerization, suggesting that the controllability of CuBr/phosphorus ligand system for ATRP is inherently limited.

• Geomechanics and Engineering
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• v.24 no.2
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• pp.157-166
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• 2021

This paper aims at the temperature and slenderness ratio effects on physical and mechanical properties of Beishan granite. A series of uniaxial compression tests with various slenderness ratios and temperatures were carried out, and the acoustic emission signal was also collected. As the temperature increases, the fracture aperture of intercrystalline cracks gradually increases, and obvious transcrystalline cracks occurs when T > 600℃. The failure patterns change from tensile failure mode to ductile failure mode with the increasing temperature. The elastic modulus decreases with the temperature and increases with slenderness ratio, then tends to be a constant value when T = 1000℃. However, the peak strain has the opposite evolution as the elastic modulus under the effects of temperature and slenderness ratio. The uniaxial compression strength (UCS) changes a little for the low-temperature specimens of T < 400℃, but a significant decrease happens when T = 400℃ and 800℃ due to phase transitions of mineral. The evolution denotes that the critical brittle-ductile transition temperature increases with slenderness ratio, and the critical slenderness ratio corresponding to the characteristic mechanical behavior tends to be smaller with the increasing temperature. Additionally, the AE quantity also increases with temperature in an exponential function.

• Structural Engineering and Mechanics
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• v.87 no.5
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• pp.405-418
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• 2023

This study focused on the effectiveness of seismic isolation technique in case of a reinforced concrete structure with soft story defined as the stiffness irregularity between adjacent stories. In this context, a seismically isolated 3-story reinforced concrete structure was analyzed by gradually increasing the first story height (3.0, 4.5, and 6.0 m). The seismic isolation system of the structure is assumed to be composed of lead rubber bearings (LRB). In the analyses, isolators were modeled by both deteriorating (temperature-dependent analyses) and non-deteriorating (bounding analyses) hysteretic representations. The deterioration in strength of isolator is due to temperature rise in the lead core during cyclic motion. The ground motion pairs used in bi-directional nonlinear dynamic analyses were selected and scaled according to codified procedures. In the analyses, different isolation periods (Tiso) and characteristic strength to weight ratios (Q/W) were considered in order to determine the sensitivity of structural response to the isolator properties. Response quantities under consideration are floor accelerations, and interstory drift ratios. Analyses results are compared for both hysteretic representations of LRBs. Results are also used to assess the significance of the ratio between the horizontal stiffnesses of soft story and isolation system. It is revealed that seismic isolation is a viable method to reduce structural damage in structures with soft story.

• Economic and Environmental Geology
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• v.13 no.3
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• pp.159-166
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• 1980

A model study was conducted for the investigation of apparent resistivity variation along with electric resistivity variation of host rock and dip variation of bed. Experiments were carried out for the cases of horizontal and dipping beds in a water tank by using Wenner and Schlumberger arrays and by changing salinity of water. The ratios of resistivity values of the bed to that of brine were 1 : 10, 1 : 50, 1 : 100 and 1 : 500. Natural coally-shale of $55cm{\times}35cm{\times}3.5cm$ was used as a bed for experimental model, and brine as a host rock. Equi-resistivity curves and characteristic curves were obtained for each case of the experiment. The equi-resistivity curve was drawn both on the cross section parallel to strike of bed and longitudinal section perpendicular to it. The characteristic curve was drawn on the cross section. In the case of dipping bed of different dips, the curves are parallel to the boundary of the bed in the upper part of the bed, and are inclined to the opposite direction with the same angle of the dip of bed in the lower part. We can deduce, from the equi-resistivity curves, the location, shape and dip of the bed. It is shown in the characteristic curves that when the ratio of resistivity value of bed to that of host rock increases, the slope of curves becomes steeper, location of low-resistivity zone lower, and the width of it narrower. The slope of curves also becomes steeper when dip of bed increases. We can deduce, from the characteristic curves, the ratio of resistivity values between adjacent beds. It was found out from the experiments that electric resistivity method could be applicable to prospecting for underground geology with an electric resistivity contrast of 1 : 10. This fact strongly suggests that distinction of coal from coally-shale could be possible in a certain field condition.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.20 no.6
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• pp.509-515
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• 2009

In this paper, we analyzed and evaluated noise suppression characteristic of EM wave absorber. We fabricated several absorber samples in different ratios of Sendust and Amorphous with CPE(Chlorinated Ploy-ethylene) as binder and calculated material constants by measured S-parameter. Then, we confirmed that the noise suppression characteristic of EM wave absorbers using microstrip line. A microstrip line with EM wave absorber placed on its top was used to evaluate the conduction noise suppression. As a result, noise suppression effect show different charateristic by changing relative permeability. Therefore, EM wave absorber using Sendust show excellent characteristic. In particular the maximum power absorption over 90 % in 1.7 GHz to over 6 GHz has obtained when composition of Sendust:CPE=80:20wt.%.

• Journal of Sasang Constitutional Medicine
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• v.18 no.1
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• pp.54-61
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• 2006

1. Objectives The body shape is an important standard for the classification of Sasang Constitutions. Using physical measure­ments and statistical analysis we can understand it's characteristic objectively. 2. Methods In this study, we have measured body circumferences and widths of 562 patients who were treated with Sasang Constitutional medicine. Their anthropometric data were transformed into the ratio based on Sasang Constitutional medicine. 3. Results (1) Taeyangin female's ratio of iliac width to chest width was most large, but Taeyangin male's was most small. (2) Soyangin's ratios of axillary width to waist width and chest width to iliac width were large. that is, their uppor body was large and lower body was small. (3) Taeumin's ratios of head and neck circumference to body circumference were small. the ratio of waist width to axillary width was most large. (4) Soeumin's ratio of head circumference to waist circumference was most large. and their uppor and lower body was larger than middle body. (5) Irrespective of Sasang Constitutions, male's ratios of axillary width to waist width and chest width to iliac width were larger than female's. 4. Conclusions From the above results, when we classify Sasang Constitutions using physical measurements we must consider gender differences and characteristics of Sasang Constitutional body shape.

• Nuclear Engineering and Technology
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• v.52 no.7
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• pp.1532-1536
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• 2020

For ensuring nuclear safeguards, we report the analytical signal-detection performance of thermal ionization mass spectrometry (TIMS) with continuous heating for the measurement of isotopic ratios in samples containing ultra-trace amounts of uranium. As methods for detecting uranium signals, peak-jumping mode using a single detector and static mode using multiple detectors were examined with U100 (10% ²³⁵U-enriched) uranium standard samples in the femtogram-to-picogram range. Uranium isotope ratios, n(²³⁵U)/n(²³⁸U), were measured down to levels of 1 fg and 3 fg in static and peak-jumping modes, respectively, while n(²³⁴U)/n(²³⁸U) and n(²³⁶U)/n(²³⁸U) values were measured down to levels of 100 fg in both modes. In addition, the dependency of the ²³⁸U signal intensity on sample quantity exhibited similar tendencies in both modes. The precisions of the isotope ratios obtained in the static mode over all sample ranges used in this study were overall slightly higher than those obtained in peak-jumping mode. These results indicate that isotope ratio measurements by TIMS with continuous heating are almost independent of the detection method, i.e., peak-jumping mode or static mode, which is characteristic of isotope-ratio measurements using the TIMS method with continuous heating. TIMS with continuous heating is advantageous as it exhibits the properties of multiple detectors within a single detector, and is expected to be used in various fields in addition to ensuring nuclear safeguards.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.3
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• pp.274-284
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• 2012

Recently, gasification technology for coal blended with biomass has been an issue. Especially, An advantages of coal blended with biomass are 1) obtaining high cold gas efficiency, 2) obtaining syn-gas of high-high heating value (HHV), and 3) controlling occurrence of $CO_2$. In this study, the efficiency and characteristic of 300 MW Shell type gasifier were predicted using CFD simulation. The CFD simulation was performed for biomass coal blending ratios of 0~0.2, 0.5, 1 and $O_2$/fuel ratios of 0.5~0.84. Kinetic parameters (A, $E_a$) obtained by $CO_2$ gasification experiment were used as inputs for the simulation. In results of CFD simulation, residence times of particle in 300MW Shell type gasifer presented as 7.39 sec ~ 13.65 sec. Temperature of exit increased with $O_2$/fuel ratio as 1400 K ~ 2800 K, while there is not an effects of biomass coal blending ratios. Considering both aspects of temperature for causing wall slagging and high cold gas efficiency, the optimal $O_2$/fuel ratio and blending ratio were found to be 0.585 and 0.05, respectively.

• Korean journal of food and cookery science
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• v.19 no.5
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• pp.571-580
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• 2003

The purpose of this study was to assess the optimum coating ratio for rice, using various ratios of mulberry leaves extract, 1.0, 1.5, and 2.0%, and to determine the optimum ratio of added water, in proportion to the total weight of mulberry rice. The moisture content of the soaked rice, and the optimum water uptake rate, moisture content of the cooked rice, as well as its blue and color values, mechanical characteristics, internal structure and sensory evaluation, were analyzed. The statistical data analyses were completed using the SAS program. The results are summarized as follows: The moisture content of mulberry rice was less than that of raw rice. The average optimum water uptake of the soaked mulberry rice at the different water temperatures, 10, 20 and 30, was 20% of the total weight of the raw mulberry rice. As for the results of the sensory evaluation,; 140% water, in proportion to the total weight of raw mulberry rice, was judged to be the optimum. The average moisture content of the cooked mulberry rice was 45∼50%, but there was no significant difference in the various coating ratios. The blue value of the cooked mulberry rice awas highest on the first day of cooking. The L- and a-values decreased with increasing coating ratio, but the b-value increased under the same conditions. As for the mechanical characteristics,; the adhesiveness, hardness and springiness decreased during 2 days of storage. The internal structure of the mulberry rice, observed by SEM, showed a close structure on increasing the coating ratios of mulberry leaves extracts. It was concluded that the optimum coating ratio of mulberry rice and ratio of added water for cooking wereas 1.5 and 140%, respectively, in proportion to the total weight of raw mulberry rice.

• Advances in environmental research
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• v.3 no.2
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• pp.107-116
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• 2014

This study aimed to synthesize dispersed and reactive nanoscale zero-valent iron (nZVI) with poly(1-vinylpyrrolidone-co-vinyl acetate) (PVP/VA), nontoxic and biodegradable stabilizer. The nZVI used for the experiments was prepared by reduction of ferric solution in the presence of PVP/VA with specific weight ratios to iron contents. Colloidal stability was investigated based on the rate of sedimentation, hydrodynamic radius and zeta potential measurement. The characteristic time, which demonstrated dispersivity of particles resisting aggregation, increased from 21.2 min (bare nZVI) to 97.8 min with increasing amount of PVP/VA (the ratios of 2). For the most stable nZVI coated by PVP/VA, its reactivity was examined by nitrate reduction in a closed batch system. The pseudo-first-order kinetic rate constants for the nitrate reduction by the nanoparticles with PVP/VA ratios of 0 and 2 were 0.1633 and $0.1395min^{-1}$ respectively. A nitrogen mass balance, established by quantitative analysis of aqueous nitrogen species, showed that the addition of PVP/VA to nZVI can change the reduction capacity of the nanoparticles.