• Journal of Korea Water Resources Association
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• v.53 no.8
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• pp.617-626
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• 2020

This study investigates changes of bifurcation discharge ratio, flow velocity distributions and characteristics of separation zone due to variation of bifurcation angle by using TELEMAC-2D model. When the bifurcation angle is reduced from 90° to 45° without changing the boundary conditions, the bifurcation discharge ratio increased by 1.5 times from 0.523 to 0.785 because of increasing the radius of curvatures, the inertia force of the downstream flow, and the pressure gradient by the downstream boundary conditions. The bifurcation discharge ratio increases non-linearly whenever the bifurcation angle decreases by 15° intervals from 90° to 45° in flow with the upstream Froude number of 0.45 to 0.74. In flow with a maximum Froude number of 0.74, the rate of increase for bifurcation discharge ratio is 31.1% and the minimum value. When the Froude number is 0.58, the bifurcation discharge ratio is 0.7 or less, and the maximum rate of increase for that ratio is 53.5%. As the upstream Froude number decreases less than 0.58, the bifurcation discharge ratio exceeds 0.7, and the rate of increase decreases. When the upstream Froude number is 0.4 higher, the dimensionless width and length changing ratio of the separation zone are about 2.56 and 5.5 times higher than in 0.4 or less.

• Clean Technology
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• v.24 no.1
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• pp.41-49
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• 2018

Y zeolites with different extra-framework cations, such as $Na^+$, $N^+$, $Ca^{2+}$, and $Cu^{2+}$, with different charge and ionic radius have been investigated to greatly enhance a working capacity (W) of $CO_2$ adsorption at $25^{\circ}C$ and a $CO_2/CO$ selectivity factor (S). A sample of NaY with a very small amount of 0.012% $Ca^{2+}$ was fully reversible for seven times repeated $CO_2$ adsorption/desorption cycles, thereby forming no surface carbonates unlikely earlier reports. Although at pressures above 4 bar, 2.00% CaY, 1.60% CuY and 1.87% LiY all showed a $CO_2$ adsorption very similar to that measured for NaY, they gave a significant decrease in the adsorption at lower pressures, depending on the metal ion. At 0.5 ~ 2.5 bar, the extent of $CO_2$ adsorption was in the order NaY > 1.60% CuY > 2.00% CaY > 1.87% LiY. All the $Na^+-based$ metals-exchanged zeolites have a FAU (faujasite) framework and a Si/Al value near 2.6; thus, there is no discernible difference in the framework topology, framework chemical compositions, effective aperture size, and channel structure between the zeolite samples. Therefore, the distinctive behavior in the adsorption of $CO_2$ with a character as a weak Lewis acid is associated with the site basicity of the zeolites, and the interaction potentials of the cations. Different trend was shown for a CO adsorption due to weaker quadrupole interactions. Adsorption of $CO_2$ and CO on samples of CaY with 0.012 to 5.23% Ca disclosed a significant dependence on the Ca loading. The $CO_2$ adsorption increased when the cation exists up to ca. 0.05%, while it decreased at higher Ca amounts. However, values for both W and S could greatly increase as the bare zeolite is enriched by $Ca^{2+}$ ions. The 5.23% CaY had $W=2.37mmol\;g^{-1}$ and S = 4.37, and the former value was comparable to a benchmark reported in the literature.