• 제목/요약/키워드: chain elongation

검색결과 108건 처리시간 0.023초

전력케이블용 XLPE/반도전층의 기계적 및 열분석 특성 (Mechanical and Thermal Characteristics of XLPE/Semiconductor Sheet in Power Cables)

  • 이관우;이경용;최용성;박대희
    • 한국전기전자재료학회논문지
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    • 제17권8호
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    • pp.893-897
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    • 2004
  • In this paper, we studied the mechanical and thermal properties on slice XLPE sheet from 22 kV and 154 kV power cables. Interface structures are XLPE/semiconductor and XLPE/water/semiconductor. We evaluated mechanical property, thermal analysis, moisture analysis. Based on mechanical and thermal properties of the 22 kV XLPE sheet, elongation, mechanical strength, and melting point were evaluated to be 485.48 %, 1.74 kgf/$\textrm{mm}^2$ and $102.48^{\circ}C$, respectively. It was also evaluated from the mechanical and thermal properties of 154 kV XLPE sheet that elongation, mechanical strength, and melting point are 507.81 %, 1.8 kgf/$\textrm{mm}^2$, $106.9^{\circ}C$, respectively. A region shows a rapid increase in tension strength, and B region only shows increase in elongation under 1.0 kgf/$\textrm{mm}^2$, C region shows increase in both elongation and tension strength. Difference of melting point came from the chain of XLPE polymer and the difference of crystallization. Moisture density of semiconductor showed 800 ∼ 1200 ppm before extrude, 14000 ∼24000 ppm after extrude. These values were higher than the moisture density of XLPE (300∼560) ppm.

기계 산업용 작업복 의복구성요인과 봉제성능 분석 - 소재 및 솔기별 봉합강도와 봉합신도 중심으로 - (The Analysis on the Clothing Construction Factors and the Sewability of the Mechanical Industry Working Clothes - With Reference to the Seam Strength and Seam Elongation According to the Material and Seam Types -)

  • 박진아
    • 패션비즈니스
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    • 제14권2호
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    • pp.57-72
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    • 2010
  • The purposes of the research were to find out the clothing construction factors of the mechanical industry working clothes by analyzing the working clothes supplied to 5 subject companies; and to suggest the optimized sewing conditions and the seam strength and elongation experimental data according to the clothing material and seam types implied to the working clothes collected. The fabric types and trimmings used for the mechanical manufacturing working clothes were Polyester/Cotton(65/35%), Polyester/Rayon(65/35%), Cotton(100%); and linings, interlining, various fastenings etc. 2 stitch types, i.e. lock and two-thread chain stitches were applied to the construction of the flat, lap felled, French, superimposed, lapped and bound seams for the seam strength and elongation experiment. The results derived from the experiment were as follows. (1) The seam strength results according to the seam types were high in the order of lap felled>lapped>flat, superimposed and French seams. (2) Considering the features of the seam construction, as the number of fabric layers at the seam line increased the seam strength also increased. (3) Apart from the highest seam strength from the experiment using the net lining with the main fabric, the seam construction consisting of two fabric layers with the interlining showed relatively high seam strength results. (4) The seam elongations according to the stitch types were high in the order of two-thread chain>lock stitches.

고분자 사슬연장제를 이용한 폴리유산 / 폴리부틸렌 아디페이트테레프탈레이트 복합필름의 제조 및 특성 분석 (Study on Characteristics of PLA/PBAT Composite Film with Various Chain Extenders)

  • 김선종;조현승;이재환;유명제;엄유준;박수일
    • 한국포장학회지
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    • 제23권2호
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    • pp.61-66
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    • 2017
  • 고분자 사슬연장제(Chain extender)를 적정 함량별로 넣어 PLA와 PBAT 생분해성 복합 필름을 제조하였으며 제조된 필름의 기계적 특성 및 열적 특성을 분석하였다. 고분자 사슬연장제인 $Joncryl^{(R)}$과 헥사메틸렌 디이시소시아네이트(HDI, Hexamethylene Diisocyanate)를 각각 단일로 넣었을 경우, 고분자 사슬연장제의 함량 증가에 따라 인장강도(Tensile strength)가 함량에 비례하여 소폭 증가하는 영향을 주는 것으로 나타났으나, 연신율에 있어서는 비례적인 차이를 나타내지 않았다. 하지만 두 종류의 사슬연장제를 적정비율로 같이 넣어 압출한 결과 인장강도가 40 MPa에 이르는 것으로 나타나 대조구의 인장강도 25 MPa보다 약 15 MPa 정도 증가하여 강도개선의 효과가 있는것으로 나타났으며 연신율의 경우 대조구보다 개선된 것으로 나타났다.

Overexpression of ginseng patatin-related phospholipase pPLAIIIβ alters the polarity of cell growth and decreases lignin content in Arabidopsis

  • Jang, Jin Hoon;Lee, Ok Ran
    • Journal of Ginseng Research
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    • 제44권2호
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    • pp.321-331
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    • 2020
  • Background: The patatin-related phospholipase AIII family (pPLAIIIs) genes alter cell elongation and cell wall composition in Arabidopsis and rice plant, suggesting diverse commercial purposes of the economically important medicinal ginseng plant. Herein, we show the functional characterization of a ginseng pPLAIII gene for the first time and discuss its potential applications. Methods: pPLAIIIs were identified from ginseng expressed sequence tag clones and further confirmed by search against ginseng database and polymerase chain reaction. A clone showing the highest homology with pPLAIIIβ was shown to be overexpressed in Arabidopsis using Agrobacterium. Quantitative polymerase chain reaction was performed to analyze ginseng pPLAIIIβ expression. Phenotypes were observed using a low-vacuum scanning electron microscope. Lignin was stained using phloroglucinol and quantified using acetyl bromide. Results: The PgpPLAIIIβ transcripts were observed in all organs of 2-year-old ginseng. Overexpression of ginseng pPLAIIIβ (PgpPLAIIIβ-OE) in Arabidopsis resulted in small and stunted plants. It shortened the trichomes and decreased trichome number, indicating defects in cell polarity. Furthermore, OE lines exhibited enlarged seeds with less number per silique. The YUCCA9 gene was downregulated in the OE lines, which is reported to be associated with lignification. Accordingly, lignin was stained less in the OE lines, and the expression of two transcription factors related to lignin biosynthesis was also decreased significantly. Conclusion: Overexpression of pPLAIIIβ retarded cell elongation in all the tested organs except seeds, which were longer and thicker than those of the controls. Shorter root length is related to auxinresponsive genes, and its stunted phenotype showed decreased lignin content.

수용성 폴리우레탄-아크릴 하이브리드수지의 합성 및 사슬 연장에 관한 연구 (A Study of Chain Extension and Synthesis in Waterborne Polyurethane-Acrylic Hybrid Resin)

  • 이주엽;김기준
    • 한국응용과학기술학회지
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    • 제28권2호
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    • pp.203-212
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    • 2011
  • In this study we experimented that how chain extension influences to waterborne urethane-acrylic hybrid resin for leather garment coatings. We knew that polyurethane-acrylic hybrid resins had 5 grades of solvent resistance. Tensile strength measured in the polyurethane-acrylic resin(EDA 5.37 g, 1.928 kgf/$mm^2$) had the most strong strength. Also polyurethane-acylic hybrid resin(EDA 5.37 g. 30.2 mg. loss) had better result than other hybrid resins. EDA contents higher, we obtained low elongation and low flexibility. In this result, chain extension of waterborne polyurethane-acrylic hybrid resin showed the effect in leather coating with ratio of EDA.

Investigations on the Chain Conformation of Weakly Charged Polyelectrolyte in Solvents by Using Efficient Hybrid Molecular Simulations

  • Chun, Myung-Suk;Lee, Hyun-Su
    • Macromolecular Research
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    • 제10권6호
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    • pp.297-303
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    • 2002
  • We have investigated the microstructural properties of a weakly charged polyelectrolyte modeled with both Hookean spring and Debye-Huckel potential, by employing a novel hybrid scheme of molecular dynamics (MD) and Monte Carlo (MC) simulations. Although the off-lattice pivot step facilitates the earlier computations stage, it gives rise to oscillations and hinders the stable equilibrium state. In order to overcome this problem, we adopt the MC off-lattice pivot step in early stage only, and then switch the computation to a pure MD step. The result shows that the computational speed-up compared to the previous method is entirely above 10 to 50, without loss of the accuracy. We examined the conformations of polyelectrolyte in solvents in terms of the end-to-end distance, radius of gyration, and structure factor with variations of the screening effects of solvent and the monomer charges. The emphasis can favorably be given on the elongation behavior of a polyelectrolyte chain, with observing the simultaneous snapshots.

Streptomyces sp GCA0001로부터 Cystocin의 생산 및 분리 정제 (Production and Separation of Cystocin from Streptomyces sp GCA0001)

  • 김동현;이희찬;우진석;송재경;류광경;김대희;강선엽
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2001년도 춘계학술대회 발표논문집
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    • pp.292-294
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    • 2001
  • Cystocin을 생산하는 Streptomyces sp GCA0001균주를 screenig하였으며, Streptomyces sp GCA0001를 배양하고 분리 정제를 통하여 흰색 분말의 Cystocin을 얻을 수 있었다. Cystocin은 Streptomyces alboniger에서 생산되는 Puromycin과 매우 유사한 구조의 항생물질로 확인되었다. Cystocin은 Puromycin과 마찬가지로 단백질 합성시 폴리펩티드 사슬의 elongation을 조기 종결함으로써 생체내에서 항박테리아, 항종양 및 항바이러스 활성을 나타낸다

Manufacture of Water-borne Biopolyurethane Film Based on Caster Oil and Tri Methylol Propane for Leather Coationg

  • Lee Joo-Youb
    • 한국응용과학기술학회지
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    • 제39권6호
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    • pp.924-931
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    • 2022
  • Undenatured castor oil and trimethylolpropane (TMP) were used to obtain bio-based water-based polyurethane. Isophorone diisocyanate (IPDI) was incorporated into the formulation to obtain a transparent film, and ethylenediamine (EDA) was used for chain extension. In order to measure the change in physical properties according to the contents of castor oil and TMP, each tensile strength, elongation, and abrasion resistance test was conducted. As the contents of castor oil and TMP increased, the tensile strength increased, the elongation decreased, and the surface hardened strongly as the respective contents increased.

Mechanism of E. coli RNA polymerase-promoter interactions

  • Roe, Jung-Hye;Record.Jr, M.Thomas
    • 미생물과산업
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    • 제13권1호
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    • pp.4-9
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    • 1987
  • The regulation of gene expression in procaryotes is accomplished primarily at the level of transcription. Initiation of transcription is subject to numerous promoter-specific controls which act to ensure coordinate expression of disparate genes. The kinetics of formation of a functional("open") complex at a promoter, prior to the catalytic steps of RNA chain initiation and elongation, is thought to play a major role in controlling the efficiency of transcription of that promotor, since the subsequent processes of nucleotide binding and phosphodiester bond formation are rapid and are not promoter-specific (Mangel and Chamberlin, 1974 Shimamoto et al., 1981)

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A Theoretical Synthesis of Poly(methyl methacrylate) (PMMA) by the Molecular Orbitals Calculation

  • Kim, Jong-Too;Kim, Ui-Rak;Akira Imamura
    • Macromolecular Research
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    • 제8권6호
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    • pp.292-297
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    • 2000
  • The theoretical synthesis of the isotactic and syndiotactic poly(methyl methacrylate) were carried out as a model for real polymerization reactions following the normal chain reaction processes by repeating the uniform localization of wave functions with inclusion of the interaction between the end group of the cluster and an attaching molecule by the elongation method, and then, the calculated value was compared with the usual PM$_3$ calculation. The results revealed that a reaction of cluster with monomer molecules has made it possible to calculate the electronic structure and total energy of polymer with nearly infinite length and a matrix of constant dimension. The isotactic poly(methyl methacrylate) is more stable than syndiotactic one. The same tendency have been found between the experimentally measured properties and a calculated total energy to explain the chain motion in isotatic and syndiotactic poly(methyl methacrylate).

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