• 제목/요약/키워드: chain components

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고려인삼의 화학성분에 관한 고찰 (Recent Studies on the Chemical Constituents of Korean Ginseng (Panax ginseng C. A. Meyer))

  • 박종대
    • Journal of Ginseng Research
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    • 제20권4호
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    • pp.389-415
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    • 1996
  • Panax ginseng C.A. Meyer(Araliaceae) has been traditionally used as an expensive and precious medicine in oriental countries for more than 5, 000 years. Ginseng saponin isolated from the root of Panax ginseng have been regarded as the main effective components responsible for the pharmacological and biological activities. Such as antiaging effects. antidiabetic effects anticancer effects. Protection against physical and chemical stress. Analgesic and antipyretic effects. Effects on the central nervous system, tranquilizing action and others. Thirty kinds of ginsenosides have been so far isolated from ginseng saponin and their chemical structures have been elucidated since 1960's. Among which protopanaxadiol type is 19 kinds. protopanaxatriol type. 10 kinds and oleanane type, one. Since ginsenosides are generally labile under acidic conditions ordinary acid hydrolysis is always accompanied by many side reactions, such as epimerization. hydroxylation and cyclization of side chain of the sapogenins Especially. it is well known that C-20 glycosyl linkage of ginsenoside was hydrolysed on heating with acetic acid to give an equilibrated mixture of 20(S) and 20(R) epimers. And also, the chemical transformations of the secondary metabolites have appeared during the steaming process to prepare red ginseng. Indicating demalonylation of malonyl ginsenosides, elimination of glycosyl residue at C-20 and isomerization of hydroxyl configuration at C-20. But these studies have not provided a comprehensive picture in explaning how these ginsenosides showed val'iotas pharmacological activities of ginseng. Though some of them have been involved in the mechanism of pharmacological actions. Recently, non-saponin components have received a great deal of attention for their antioxidant, anticancer antidiabetic, immunomodulating. anticomplementary activities and so on. To meet the demand for such wide applications, studies on the non-saponin components play an important role in providing a good evidence of pharmacological and biol ogical activities. Among the non-saponin constituents of Korean ginseng, polyacetylenes, phenols. Sesquiterpenes, alkaloids. polysaccharides oligosaccharides, oligopeptides and aminoglycosides together with ginsenosides of terrestrial part are mainly described.

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Synthesis and Characterization of Iridium-Containing Green Phosphorescent Polymers for PLEDs

  • Xu, Fei;Kim, Hee Un;Mi, Dongbo;Lim, Jong Min;Hwang, Ju Hyun;Cho, Nam Sung;Lee, Jeong-Ik;Hwang, Do-Hoon
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.399-405
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    • 2013
  • Two series of new green phosphorescent polymers bearing a bis(2-phenyl-pyridine)iridium(III)(dibenzoylmethane) [$(ppy)_2Irdbm$] complex were designed and synthesized. Poly-carbazole (PCbz) derivative or polyfluorene with pendant carbazole groups (PFCbz) were employed as host polymers for the iridium complex. The iridium complex monomer was copolymerized with the host monomers using varying monomer ratios via a Yamamoto coupling reaction. Efficient energy transfer from host to dopant unit was observed by increasing the ratio of the iridium guest in the copolymers. Electroluminescent devices with the configuration ITO/PEDOT:PSS/polymer/BmPyPB/LiF/Al were fabricated and characterized. The phosphorescent polymers composed of the iridium complex guest and polyfluorene with carbazole pendants as a host performed better than the polymers composed of the same guest and the main chain polycarbazole host. A maximum external quantum efficiency of 0.73%, a luminous efficiency of 1.21 cd/A, and a maximum luminance of 372 $cd/m^2$ were obtained from a device fabricated using one of the synthesized copolymers.

M2M 기술을 이용한 스마트 선박 컨테이너 (Smart Ship Container With M2M Technology)

  • 로네쉬 샤르마;이성로
    • 한국통신학회논문지
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    • 제38C권3호
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    • pp.278-287
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    • 2013
  • 현대 정보 기술은 새롭고 개선된 방법으로 여러 산업들에 지속적인 제공을 하고 있다. 본 논문에서 고려한 스마트 컨테이너 공급망 관리는 사물지능(M2M)통신의 급속한 발전과 함께 고성능 센서, 컴퓨터 비전, GPS, GSM을 기반으로 형성된다. 기존 공급망관리는 실시간 컨테이너 추적에 제한이 있다는 문제점을 가지고 있다. 본 논문은 인터럽트 및 보통 정기적인 알림에 대한 컨테이너 식별 시스템과 자동 알림 시스템의 개발과 실시간 컨테이너 공급망관리의 연구 및 구현에 초점을 맞추었다. 첫째, 본 논문은 컨테이너 코드 식별 및 실시간 작업에 대해 컴퓨터 비전 라이브러리와 OCR 엔진을 비주얼 스튜디오 2010으로 구현된 식별 알고리즘을 제안하고 있다. 둘째는 실시간 컨테이너 추적 및 그 시스템의 한계에 대해 제공되는 현재 자동 알림 시스템에 대해 설명한다. 마지막으로 본 논문은 고성능 센서와 컴퓨터 비전과 함께 유비쿼터스 모바일 및 위성 네트워크와 실시간 컨테이너 추적 솔루션의 미래에 도전과 가능성을 요약하였다. 뛰어난 운영 및 보안 공급망관리의 우수한 전송을 제공하기 위해 이러한 모든 구성요소를 결합하였다.

퍼지 온톨로지를 이용한 선호도 기반 공급사슬 파트너 선정 (Preference-based Supply Chain Partner Selection Using Fuzzy Ontology)

  • 이해경;고창성;김태운
    • 지능정보연구
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    • 제17권1호
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    • pp.37-52
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    • 2011
  • 공급사슬관리(SCM)는 공급사슬의 가치를 높이고 변화하는 환경에 더 민첩하게 적응할 수 있는 전략적인 접근방식이다. 공급사슬 파트너 간에 중단 없는 파트너쉽과 가치 창출을 위해서는 정보와 지식의 공유 및 적절한 파트너 선정기준이 적용되어야 한다. 따라서 파트너 선정 기준은 제품의 품질과 신뢰도를 유지하기 위해서 아주 중요하다. 제품의 각 부품은 적절한 공급 파트너를 통해서 공급된다. 파트너를 선정하는 기준은 기술적 능력, 품질, 가격, 지속성 등 여러 요인이 있다. 실제로 파트너 선정기준은 구성부품의 특성에 따라서 변화할 수 있다. 그 부품이 핵심 구성품이면 품질이 가격에 비해서 최고 우선순위가 된다. 표준부품은 낮은 가격이 우선순위를 가진다. 간혹 긴급 주문과 같은 예기치 못한 상황이 발생하면 우선순위가 변하게 된다. 따라서 SCM 파트너 선정 기준은 구성부품의 특성과 상황에 따라서 동적으로 결정 되어진다. 이 연구의 목적은 상황과 부품의 특성에 따라서 공급사슬 파트너쉽을 위한 온톨로지 모델을 제시하고자 하는 것이다. 변수의 불확실성은 퍼지이론을 이용하여 나타내고자 하였다. 부품별 우선순위와 상황변수는 웹 온톨로지 언어(OWL : Web Ontology Language)를 이용하여 모델링 하였다. 부품의 우선순위는 퍼지로직을 이용한 퍼지소속함수로 변환 되어진다. 온톨로지의 추론을 위해서 SWRL(Semantic Web Rule Language)을 이용하였다. 제안된 모델의 구현을 위해서 자동차 구성품인 스타트모터 부품을 대상으로 온톨로지를 구축하고 구성 부품별 우선순위에 따른 공급 파트너를 선정하는 과정을 제시하였다.

등줄숭어 란유의 Nonrandom 분포를 한 왁스에스테르 조성에 관한 연구 (Nonrandom Combination of Fatty Acid and Alcohol Moieties in Wax Esters from Liza Carinata Roe)

  • 조용계;이경희;조연주
    • 한국식품과학회지
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    • 제21권5호
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    • pp.624-632
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    • 1989
  • 등줄숭어알 지질조성은 왁스에스테르(56.6-62.2%), 인지질 (19.2-18.5%), 트리글리세리드 (17.8-14.4%)의 순이었다. 왁스에스테르의 주요지방산은 C16 : 1 (25.9-27.3%)>C18 : 1(14.7-18.5%)>$C20 : 5{\omega}3$(16.3-9.6%)의 순이었으며, 알콜은 C16 : 0(57.3-53.3%)>C18 : 0(9.3-11.7%)>C18 : 1(18.9-12.7%)의 순이었다. 이중결합 2개 이상의 고도불포화 알콜은 전혀 검출되지 않았다. 홀수지방산(6.4-8.5%)과 알콜(7.4-7.5%)도 상당량 존재하였다. 수소첨가한 왁스에스테르는 탄소수별로 분리되었으나, 같은 탄소수를 가진 이성체는 분리되지 않았다. 왁스에스테르 분자종의 조성을 보면 시료 A의 경우는 C32(45.0%)>C34(19.2%)>C30(12.2%)순이었고, 시료 B의 경우는 C34(36.3%)>C32(31.4%)C36(18.1%)의 순이었다. 왁스에스테르는 구성지방산과 알콜이 nonrandom combination으로 에스테르화 되었으며, 이를 $360^{\circ}C$에서 40분간 가열하면 완전히 random화 됨을 알 수 있었다. 등줄숭어에 존재하는 왁스에스테르의 생합성에 관여하는 효소는 기질인 지방산과 알콜 탄소수에 강한 특이성을 가지고 있음을 추측할 수 있었다.

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텍스트와 그래픽으로 구성된 혼합문서 인식에 관한 연구 (A Study on the Recognition of Mixed Documents Consisting of Texts and Graphic Images)

  • 함영국;김인권;정홍규;박래홍;이창범;김상중;윤병남
    • 전자공학회논문지B
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    • 제31B권7호
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    • pp.76-90
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    • 1994
  • In this paper, an efficient algorithm is proposed which recognizes the mixed document consisting of the printed Korean/alphanumeric texts and graphic images. In the preprocessing step an input document is aligned if necessary by rotating it. We obtain the rotation angle using the Hough transform and align the input document horizontally. Then we separate graphic image parts from text parts by considering chain codes of connected components. We further separate each character using vertical and horizontal projections. In the recognition step Korean and alphanumeric characters are classified and each of them is recognized hierarchically using several features. In summary an efficient recognition algorithm for mixed documents is proposed and its performance is demonstrated via computer simulations.

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Volatile Flavor Compounds of Saussurea lappa C.B. Clarke Root Oil by Hydro Distillation-GC and $GC/MS^+$

  • Chang, Kyung-Mi;Kim, Gun-Hee
    • Food Quality and Culture
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    • 제1권1호
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    • pp.13-17
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    • 2007
  • The volatile flavor compounds of Saussurea lappa C.B. Clarke, a perennial, aromatic and medicinal herbaceous plant of the Asteraceae family, were isolated by the hydro distillation extraction method using a Clevenger-type apparatus, and analyzed by gas chromatography (GC) and gas chromatography-mass spectrometry (GC/MS). The plant yielded a light yellow colored oil (0.02%, v/w). From S. lappa C.B. Clarke root oil, sixty-three volatile flavor compounds were tentatively identified, among which sesquiterpene was predominant (21.70%). The identified compounds of the root oil constituted 87.47% of the total peak area. From the constituents making up more than 5% of the volatile flavor components, a long-chain aldehyde, (7Z, 10Z, 13Z)-7, 10, 13-hexadecatrienal, was the most abundant volatile flavor compound (21.20%), followed by dehydrocostuslactone (10.30%) belonging to sesquiterpene lactone, valerenol (5.30%) and vulgarol B (5.06%).

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Gas Chromatography/Mass Spectrometry를 이용한 팔강약침액 성분에 대한 연구 (The Study on the Composition in Pharmacopunctures of Eight Principles by Gas Chromatography/Mass Spectrometry)

  • 김협;안병수
    • 대한약침학회지
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    • 제11권3호
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    • pp.79-91
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    • 2008
  • Objective: The purpose of this study was to investigate the composition for pharmacopunctures of eight principles hydrodistillation layer. Methods: The study was determined the hydrodistillation layer for pharmacopunctures of eight principles by hydrodistillation method. The effective components in hydrodistillation layer for pharmacopunctures of eight principles were extracted with ethyl ether or dichloromethane, and then analyzed by Gas Chromatography/Mass Spectrometry(GC/MS). Results: 1. Analyzed pharmacopunctures of eight principles by GC/MS, a lot of differences according to extraction solvent by each pharmacopunctures of eight principles and specific peak patterns were seen. 2. The main compound in pharmacopunctures of eight principles was a kind of hexaoxacyclohydrocarbon that has long hydrocarbon chain.

인테리어용 인조가죽을 위한 용출형 극세사와 저온 융착사의 제조 (Manufacture of Soluble Micro-fiber and Low Melting Polymer for Interior Synthetic Leather)

  • 안영무
    • 한국생활과학회지
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    • 제12권4호
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    • pp.529-537
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    • 2003
  • This study was conducted to manufacture the soluble micro-fiber and to synthesize low melting polymer for the interior fabric not to use the polyurethane resin causing some problems. Low melting polyester for weft yarn was introduced by adding 30-40 mol% ratio of isophthalic acid to a main chain of polyethylene terephthalate to decrease the melting temperature up to heat setting temperature. Micro-fiber for warp yarn consisted of both soluble and insoluble components with multi-layered structure. When the soluble micro-fiber was treated by alkaline hydrolysis with 3-5% concentration of NaOH, it showed the turning point at 28% weight loss since soluble polyester was hydrolyzed approximate five times faster than regular polyester.

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Cloning and Characterization of Ribosome-associated Membrane Protein 4 (RAMP4) gene in silkworm Bombyx mori

  • Yao Qin;Hu Zhigang;Xu Jiaping;Chen Keping
    • International Journal of Industrial Entomology and Biomaterials
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    • 제10권2호
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    • pp.125-129
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    • 2005
  • Ribosome-associated membrane protein 4 (RAMP4) is a membrane protein that exposes its N-terminal hydrophilic portion on the cytoplasmic side and spans the membrane close to the C-terminal end. RAMP4 has previously been reported to belong to the set of proteins that remains associated with membrane-bound ribosomes, and controls the glycosylation of major histocompatbility complex class II-associated invariant chain. RAMP4 also may be relative to the stabilization of membrane proteins in response to stress, with other components of translocon, and molecular chaperons in ER. Application of 5'-RACE technique with specially designed primer, we cloned a 715 bp cDNA fragment which contains a 195 bp ORF, termed RAMP4. The deduced protein has 64 amino acid residues and contains a putative transmembrane-spanning domain at the COOH terminus.