• 한국세라믹학회지
• /
• 제35권9호
• /
• pp.899-904
• /
• 1998

Interface reaction between LSMC and YSZ is discussed with chemical composition of LSMC. The reac-tivity between LSMC and YSZ increased with increasing Co amount and A-site deficient perovskite is very effective on reducing reactivity. The (La0.8Sr0.2)xMn0.8Co0.2O3 (X=0.9-1) composition is not reactive with YSZ in experimental range. The electrode reaction reaction resistance increases due to reaction product.

• 한국세라믹학회지
• /
• 제21권3호
• /
• pp.271-277
• /
• 1984

To study interface between crystals grown and molten state in the crusible. Pulling and rotating rate of the shaft were varied in LiF crystal growth by Czochralski method. Lower speed of the pulling and rotating rate increased the degree of convexity in solid-liquid interface and higher speed of the pulling and rotating rate decreased it. Optimum condition of LiF crystal growth obtained as pulling rate was 6.5cm/h when it rotated as 46rpm.

• 한국세라믹학회지
• /
• 제40권8호
• /
• pp.784-790
• /
• 2003

본 논문은 세라믹재료가 강화재로써 보강된 복합재료가 횡방향의 단축인장하중을 받는 경우, 복합재료의 변형, 재료내 발생되는 손상의 특징, 및 응력-변형률 특성에 관한 컴퓨터 해석결과이다. 해석은 SiC/Ti 시스템을 대상으로 하였으며, 특성은 강화재의 배열형태, 강화재/기지 계면에서의 결합유무, 강화재의 부피분율변화에 대하여 각기 해석되었다. 계면에서 강한 결합이 있는 복합재와는 달리, 약한 결합의 복합재는 인장하중에 의하여 세라믹/기지 계면에서 분리가 발생되었다. 이 분리는 전체 복합재의 강성을 감소시키며, 세라믹 강화재의 부피분율이 증가할수록 탄성계수 및 횡방향 평균응력의 최종크기를 나타내는 한계응력의 크기감소로 나타났다. 계면결합이 강한 경우는 세라믹 부피분율이 증가할수록 사각형 배열보다는 육각형배열의 복합재에서 다소 큰 증가율로 나타났다. 그러나, 계면결합이 약한 경우는 세라믹 부피분율이 증가할수록 사각형 배열보다는 육각형배열의 복합재에서 상대적으로 큰 감소율로 해석되었다. 본 연구의 해석결과는 알려진 문헌의 결과와 잘 일치하였다.

• 한국세라믹학회지
• /
• 제43권7호
• /
• pp.415-420
• /
• 2006

The residual stresses in the interface region of the Thermal Barrier Coating (TBC)/Thermally Grown Oxide (TGO)/Bond Coat (BC) were calculated on the TBC-coated superalloy samples using a Finite Element Method (FEM). It was found that the stress distribution of the interface boundary was dependent upon mainly the geometrical shape or its aspect ratio and the thickness of TGO layer, which was formed by growth and swelling behavior of oxide layer. Maximum compressive residual stress in the TBC/TGO interface is higher than that of the TGO/bond coat interface, and the tensile stress had nothing to do with change of an aspect ratio. The compressive residual stresses in the TBC/TGO and TGO/bond coat interface region increased gradually with the TGO growth.

• 한국공작기계학회:학술대회논문집
• /
• 한국공작기계학회 1997년도 춘계학술대회 논문집
• /
• pp.156-163
• /
• 1997

Recently, attempts have been made to be join ceramics to metals in order to make up for the brittleness of ceramics. The difference in the coefficients of linear expansion of the two materials joined at high temperature will cause residual stress, which has a strong influence on the strength of the bonded joints. In this paper, the residual stress distribution and stress intensity factors of the ceramic/metal bonded joints were analyzed by 2-dimensional elastic boundary element method. Fracture toughness tests of ceramic/metal bonded joints with an interface crack were carried out. So the advanced method of quantitative strength evaluation for ceramic/metal bonded joints is to be suggested. Fracture surface and crack propagation path were observed using scanning electron microscope.

• 한국세라믹학회지
• /
• 제33권6호
• /
• pp.718-724
• /
• 1996

Deformation mechanism map of Langdon-Mohammed type for YBa2Cu3O7-x superconducting ceramic was constructed by considering mechanisms of Nabarro-Herring Coble and powder-law creep and grain boundary sliding (GBS) with an accommodation by grain boundary diffusion. The map was found consistent with experi-mental results not only of the creep the also of the superplastic deformation. It showed the transition from interface reaction-controlled to the grain boundary diffusion-controlled GBS mechanism at about 1 ${\mu}{\textrm}{m}$ grain size and 100 MPa flow stress in agreement with the experimental results.

• The Korean Journal of Ceramics
• /
• 제4권4호
• /
• pp.340-344
• /
• 1998

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2001년도 추계학술발표대회 논문집
• /
• pp.144-148
• /
• 2001

A proper estimation of the mechanical properties for composites has been required for better design/selection of constituents for composite materials. Present investigation shows the simulation results for ceramic reinforced metal matrix composite under uniaxial transverse tensile loading. The resulting transverse mean stress with the transverse mean strain was described for composites as a function of the volume fraction with two different types of interfacial bonding: (1)strongly bonded interface, and (2)no bonded interface. A two-dimensional finite element modeling and analysis were conducted based on the unit-cell concept with an assumption of a regular square arrangement of the reinforcement within the composite. The mean stress was generally increased with the ceramic volume fraction for composite with strong interface bonding. The micromechanics concept combined with finite element modeling for composite can be used in order to predict the transverse properties of composites with a priori known properties of constituents.

• 대한치과기공학회지
• /
• 제33권4호
• /
• pp.349-357
• /
• 2011

Purpose: In this study, for the reasons of observing the changes when using bonding agent with Ni-Cr alloy and Co-Cr alloy and using VM13 and Vintage MP ceramic which have the disparity in coefficient of thermal expansion, it is carried out to evaluate the characteristics of the bonding agent through the analysis of the interface between metal and ceramic and the analysis of bond strength by variable. Methods: The surface treatment was performed on the two kinds of alloy(Ni-Cr alloy and Co-Cr alloy) specimens, which were sandblasted and were treated with bonder application. The metal-ceramic interfaces were analyzed with EPMA in order to ionic diffusion, and the shear test was performed. Results: As a result of observation of metal-ceramic interfacial properties, it was observed that Cr atoms were spread from the alloy body to the ceramic floor in the specimen of Group B. It was also seen that Cr, W atoms were spread from the alloy body to the ceramic floor in the specimen of Group S. In consequence of observing Shear bond strength, it was calculated that the specimen of BSV was 27.75(${\pm}11.21$)MPa, BSM was 27.02(${\pm}5.23$)MPa, BCV was 30.20(${\pm}5.99$)MPa, BCM was 27.94(${\pm}10.76$)MPa, SSV was 20.83(${\pm}2.58$)MPa, SSM was 23.98(${\pm}3.94$)MPa, SCV was 32.32(${\pm}4.68$)MPa, and SCM was 34.54(${\pm}10.63$)MPa. Conclusion: In the metal-ceramic interface of Bellabond plus sample group, diffusion of Cr atoms was incurred and diffusion of C Cr atoms and W atoms in the sample group of $Starloy{(R)}\;C$ was observed. Using bonding agent showed the higher bond strength than using the sand blasting treatment. In the Bellabond plus alloys, the specimen group with the use of binding materials showed higher shear bond strength, but didn't show statistically significant differences (p>0.05). In the $Starloy{(R)}\;C$ alloys, the specimen group with the use of binding materials showed higher shear bond strength and statistically significant differences(p<0.05). In terms of VM13 ceramic, it was in the Bellabond plus alloys that the high shear bond strength was showed, but there's no statistically significant differences(p>0.05). In terms of Vintage MP ceramic, it was in the $Starloy{(R)}\;C$ alloys that the high shear bond strength was showed and statistically significant differences(p<0.05). Metal-ceramic to fracture of the shear strength measurements and an analysis of all aspects of military usage fracture of the composite, respectively.

• 비파괴검사학회지
• /
• 제14권1호
• /
• pp.7-15
• /
• 1994

동을 중간재로 하는 $Si_3N_4/SUS304$ 접합재의 접합계면 근방의 잔류응력 분포를 유한요소법과 X선 응력측정법을 이용하여 해석을 하였다. 그 결과, 접합재의 세라믹부 계면 근방의 잔류응력 분포를 정량적으로 밝혀낼 수 있었다. 세라믹부에 발생되는 접합 잔류응력은 접합계면 근방에서 대단히 크게 나타났으며, 특히 최대인장 잔류응력 ${\sigma}_x$는 단부에서 발생하였다. 한편, ${\sigma}_x$는 접합계면 근방에서 3차원분포를 하고 있기 때문에 2차원 유한요소 해석결과와는 대단히 다른 값을 나타내고 있으며, 특히 시험편 중앙부의 계면 근방에서는 X선 실측결과가 인장 잔류응력임에 반하여 2차원 유한요소 해석결과는 압축 잔류응력으로 계산되어짐을 알았다. 따라서, 이와같은 3차원 분포를 하고 있는 접합계면 근방의 잔류응력 ${\sigma}_x$보다 간편하고 정확하게 예측할 수 있는 유한요소 해석모델에 대하여 서로 검토하였다.