• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.449-458
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• 2006

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.540-548
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• 2002

The purpose of this study is to analyze the application of oyster shells (OS) as aggregates for concrete. For this purpose, five reference mixes with W/C ratios of 0.4 ∼0.6 at intervals of 0.05 were used. The replacement proportion of OS was varied with ratios of 0, 10, 30, 50 and 100％ by volume of fine or coarse aggregate in the reference mixes. OS was washed and crushed for using as aggregates. New chemical reaction between crushed OS aggregate and cement paste was tested through XRD and SEM analysis. Two strength properties (compressive and flexural) were considered. Strength tests were carried out at the ages of 1, 3, 7, 14 and 28 days. The variations of workability, air content and density, drying shrinkage of the specimens with different proportions of OS were also studied. Finally, the hollow concrete block using OS as a substitute material for fine aggregate was made for testing the application of OS. Experimental results showed that my new chemical reaction did not occur due to mixing OS in concrete. The workability and strengths decreased with increase in proportion of OS. The same trend was observed in density and unit weight, but air content increased due to the inherent pores in OS, which showed a possibility to produce light weight concrete with low strength by using OS as coarse aggregates for concrete. Tests on hollow concrete block showed that the compressive strength and absorption ratio were satisfied with quality requirements when the fine aggregate was substituted with OS up to 50％ in volume.

• Journal of the Korean GEO-environmental Society
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• v.12 no.1
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• pp.13-26
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• 2011

Because the allowable current loading of buried electrical transmission cables is frequently limited by the maximum permissible temperature of the cable or of the surrounding ground, there is a need for cable backfill materials to be maintained at a low thermal resistivity during the service period. Temperatures greater than $50^{\circ}C$ to $60^{\circ}C$ may lead to breakdown of cable insulation and thermal runaway if the surrounding backfill material is unable to dissipate the heat as rapidly as it is generated. This paper describes the results of studies aimed at the development of backfill material to reduce the thermal resistivity. A large number of different additive materials were tested to determine their applicability as a substitute material. The results of Dong-rim river sand (relatively uniform) show that as water content level increases, thermal resistivity tends to decrease, whereas the thermal resistivity on dry condition is very high value($260^{\circ}C-cm/watt$). In addition, other materials(such as Jinsan granite screenings, A-2(sand and gravel mixture), E-1(rubble and granite screenings mixture) and SGFC(sand, gravel, fly-ash and cement mixture)) are well-graded materials with low thermal resistivity($100^{\circ}C-cm/watt$ when dry). Based on this research, 4 types of improved materials were suggested as the environmentally friendly backfill materials with low thermal resistivity.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.37 no.1
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• pp.33-40
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• 2024

The volume of shells, a prominent form of marine waste, is steadily increasing each year. However, a significant portion of these shells is either discarded or left near coastlines, posing environmental and social concerns. Utilizing shells as a substitute for traditional aggregates presents a potential solution, especially considering the diminishing availability of natural aggregates. This approach could effectively reduce transportation logistics costs, thereby promoting resource recycling. In this study, we explore the feasibility of employing wasted shell aggregates in 3D concrete printing technology for marine structures. Despite the advantages, it is observed that 3D printing concrete with wasted shells as aggregates results in lower strength compared to ordinary concrete, attributed to pores at the interface of shells and cement paste. Microstructure characterization becomes essential for evaluating mechanical properties. We conduct an analysis of the mechanical properties and microstructure of 3D printing concrete specimens incorporating wasted shells. Additionally, a mix design is proposed, taking into account flowability, extrudability, and buildability. To assess mechanical properties, compression and bonding strength specimens are fabricated using a 3D printer, and subsequent strength tests are conducted. Microstructure characteristics are analyzed through scanning electron microscope tests, providing high-resolution images. A histogram-based segmentation method is applied to segment pores, and porosity is compared based on the type of wasted shell. Pore characteristics are quantified using a probability function, establishing a correlation between the mechanical properties and microstructure characteristics of the specimens according to the type of wasted shell.

• Journal of the Korea Institute of Building Construction
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• v.24 no.5
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• pp.553-563
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• 2024

In this research, the thermal properties of limestone fine powder at high temperatures were examined, followed by an analysis of its residual compressive strength when incorporated into concrete under various thermal conditions, to determine its impact on concrete subjected to high heat. The study revealed that at 900℃, limestone micropowder undergoes a decarbonization reaction, where calcium carbonate(CaCO₃) decomposes into calcium oxide(CaO), accompanied by an expansion of the limestone powder as temperature increases. This expansion leads to material cracking or crushing starting at temperatures above 500℃. Further analysis on concrete mixed with limestone powder showed that heating up to 300℃ could promote the reaction of hydrates within the concrete, thereby enhancing its strength. However, exposure to temperatures beyond 500℃ causes the limestone powder within the concrete to crack or fracture, significantly reducing the concrete's strength properties. This study highlights the dual role of limestone fine powder in influencing concrete's behavior under high-temperature scenarios, demonstrating an initial strengthening effect followed by a detrimental impact at higher temperatures.